Metabolic Pathways Flashcards
(26 cards)
Oxidation
Strips an electron from an atom in a compound
Reduction
The addition of an electron to a compound
ATP
(Adenosine triphosphate) small molecule that is used to power reactions in the cell
Substrate-level phosphorylation
A phosphate group is transferred from a pathway intermediate straight to ADP
Electron Transport Chain
Group of proteins in the inner membrane of the mitochondrion
Oxidative phosphorylation
Energy released in ETC captured as proton gradient, which powers production of ATP by membrane protein (ATP synthase)
Aerobic respiration
Oxygen requiring process
Anaerobic respiration
Non-oxygen requiring process
Oxidized
One of the reacting molecules loses electrons
Reduced
Another reacting molecule gains electrons
Reducing agent
Atom or molecule that donates electrons
Oxidizing agent
Atom or molecule that accepts electrons
When is a carbon-containing molecule likely reduced?
If it gains hydrogen atoms or loses oxygen atoms
When is a carbon-containing molecule likely oxidized?
If it loses hydrogen atoms or gains oxygen atoms
Oxidation as defined by a Biologist
Losing hydrogen atoms
Reduction as defined by a Biologist
Gaining hydrogen atoms
Spontaneous reactions
Redox reactions that move electrons or electron density from a less to a more electronegative atom, and release energy
Non-spontaneous reactions
move the system from a lower to a higher energy state and require energy
What are the two ways glucose is oxidized in a gradual way?
1) electrons are stripped off of glucose in pairs during cellular respiration, rather than at the same time. Electrons are then transferred to electron carriers
2) electron carriers deposit electrons in ETC, electrons are passed in energy-releasing steps so that energy is captured in the form of an electrochemical gradient
Why is the transfer of electrons important in cellular respiration?
Most energy stored in atoms and used to fuel cell functions is in the form of high-energy electrons. This allow cells to transfer and use energy in increments.
Electron carriers
Small organic molecules that readily cycle between oxidized and reduced forms and are used to transport electrons during metabolic reactions.
NAD+
(nicotinamide adenine dinucleotide) the primary electron carrier during cellular respiration that accepts 2 electrons and 1 hydrogen ion to become NADH
FAD
(flavin adenine dinucleotide) an electron carrier that only participates in 1-2 reactions during cellular respiration and accepts 2 electrons and 2 hydrogen ions to become FADH2
Coenzyme
Organic molecules that serve as helpers during enzyme-catalyzed reactions, and they receive electrons and protons as part of these reactions