Metals & Alloys Flashcards

(74 cards)

1
Q

what is the symbol for an edge dislocation?

A

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2
Q

what is the symbol for a screw dislocation?

A

curved arrow

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3
Q

how do two like dislocations interact?

A

can repel each other

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4
Q

how do two unlike dislocations interact?

A

attract and annihilate each other

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5
Q

what does the ability of metal to plastically deform depend on?

A
  • depends on the ability of dislocations to move

- to strength a material we try to restrict or hinder dislocation movement

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6
Q

what are the 4 main mechanisms for restricting dislocation movement to strengthen a material?

A
  • solid-solution strengthening
  • strain hardening or cold working
  • reducing grain size
  • precipitation strengthening
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7
Q

how does grain size reduction work?

A

reducing the gain sizes increases the number of grain boundaries - dislocations need more energy to pass through a grain boundary so it impedes dislocation movement, rolling with a polycrystalline metal can also induce this

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8
Q

are fine or large grained materials harder?

A

fine grained materials are stronger and harder because the yield strength is increased because there is a larger no. of grain boundaries

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9
Q

what is the Hall-Petch equation? what does it relate to?

A

σyield = σo + ky x d^-0.5
where…
σyield = yield stress
σo = starting stress for dislocation movement (constant)
Ky = strengthening coefficient
d = average grain diameter
(it relates to the effect of grain boundaries on the yield stress)

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10
Q

what is solid-solution strengthening?

A
  • when you deliberately alloy metals with impurity atoms
  • impurity atoms distort the lattice and generate stress
  • stress can produce a barrier to dislocation motion
  • can be done with substiituonal solid solution or interstitial solid solution strengthening
  • more energy is required as a dislocation wants to move it has to to tear itself from the impurity atoms
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11
Q

what is an example of solid-solution strengthening?

A

Cu-Ni alloys, alloying increases the yield stress and tensile strength

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12
Q

in terms of solid-solution strengthening, what does the degree of strengthening depend on?

A

the relative atomic size…
for example Cu-Ni had a small difference whereas Cu-Sn has a large difference in atomic size meaning there is a larger lattice strain and will have greater strengthening by concentration

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13
Q

what is precipitation strengthening?

A
  • dislocations can’t get through precipitates easily
  • hard precipitates are difficult to shear, which takes up a lot of energy
  • for example aluminium is strengthened with precipitates formed by alloying making it ideal for use in aircrafts because it has greater strength
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14
Q

what can we change in terms of precipitation strengthening?

A

decreasing the spacing, S, and putting the precipitates close together means the dislocations bend round more which increases the material strength

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15
Q

what is cold work hardening (or strain hardening)?

A
  • hitting a metal with a hammer etc.
  • metal becomes harder and stronger as it is deformed due to strain or ‘work’ hardening - improves the mechanical properties
  • dislocations become entangled
  • the stress required to cause further plastic deformation increases
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16
Q

how does cold work hardening work?

A
  • dislocations entangle one another during cold work

- dislocation motion becomes more difficult

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17
Q

what is the equation that relates to cold work hardening ?

A

%CW = (Ao - Ad / Ao) x 100

where A is the area, use πro^2 and πrd^2 for a cylindrical rod

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18
Q

what is annealing?

A
  • heating up the metal and cooling it slowly
  • removes strengthening, as diffusion allows dislocations to rearrange and annihilate
  • annealing is a form of recovery: it allows for recrystalisation and grain growth, removes stresses
  • reduces dislocation density
  • if you increase the temp. you increase the grain size
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19
Q

where are dislocations primarily seen?

A

primarily in metals and alloys

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20
Q

what is cast iron? where is it used?

A
  • 2-4% carbon
  • lower melting point due to high carbon content
  • has pearlite and flakes of graphite
  • graphite improves wear resistance by providing lubrication and a large reduction in toughness and ductility as source of cracks
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21
Q

what is metal fabrication and what are the main types?

A

metal fabrication is the processing of metals into finished objects, these methods include:

  • casting - pouring liquid metals (low cost)
  • forming/forging (if metal is ductile)
  • machining such as cutting and grinding
  • joining
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22
Q

how are most alloys initially formed?

A

by casting - conditions during solidification are important in determining the quality of the alloy

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23
Q

what is sand casting?

A
  • low cost way of manufacturing simple shapes
  • make the required ‘pattern’ which is the needed shape
  • place the wooden pattern into moulding sand, then remove the positive mould former
  • liquid alloy is poured into the negative void and allowed to solidify
  • sand mould is broken up and casting is removed
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24
Q

what is investment casting?

A
  • process of using lost wax
  • used for high temp alloys (e.g turbine blades)
  • provides high dimensional accuracy for materials that are difficult to machine at room temp.
  • used for low volume but complex shapes
  • master mould is produced in alloy which is machinable e.g brass
  • the master is then used to create wax patterns
  • wax pattern is coated with ceramic
  • the coated wax is melted away leaving a high temp ceramic mould
  • high Tm alloy is poured into the ceramic mould and removed on solidification
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25
what is die casting?
- process of injecting liquid metal into a reusable mould under pressure - produces complex shapes - reduced porosity - little metal waste - restricted to lower Tm alloys (Cu, Zn, Mg, Al etc.)
26
what is forging?
shaping by hammer blows into an anvil 'mould' - can form complex, strong parts such as wrenches and crankshafts
27
what is rolling?
material passed through cylindrical roller to produce sheet type products and things like rails and I-beams
28
what is extrusion?
forcing metal through a shaped die to form parts with a constant cross section like tubing and rods
29
what is drawing?
pulling metal through a die usually to make metal wires, rods and tubing
30
in what conditions is plastic deformation done?
at high temp. to reduce stress required and provide ductility in the finished part
31
what are the main difference between cold working and hot working?
COLD WORKING: - more energy to deform - oxidation: good finish - higher strength - fracture resistant HOT WORKING - recrystalisation - less energy to deform - oxidation: poor finish - lower strength
32
what is an alloy?
an alloy is a metallic substance made up of more than one element
33
name some examples of alloys
- bronze (Cu-Sn) - brass (Cu-Zn) - solder (Pb-Sn) (bronze alloys are used for propellors in boats because they are corrosion resistant, also used for musical instruments)
34
why do we alloy metals?
- to improve the mechanical properties - they can have higher strengths - easier casting (controlled solidification) because lower melting point - electrical/magnetic properties - can tailor properties for a given application
35
what are the properties of metals and alloys controlled by?
- bonding - crystal structure - microstructure / defects
36
what are components in terms of alloys?
the elements or compounds which are mixed initially (e.g Al and Cu)
37
what are the phases in terms of alloys?
the physically and chemically distinct material regions that result (e.g α and β) - they have different structures
38
what is the phase boundary/solubility limit on a phase diagram?
the boundary between a liquid and saturated solution (i.e a liquid + solid) - the point at which you can't fit any more solid in
39
what are ferrous alloys?
metals that contain iron
40
what are some benefits of iron? and one con?
- abundant - extraction is economical - versatile and tailored properties - high stiffness (210GPa), good strength and ductility - CON: susceptible to corrosion
41
if we add carbon to iron what do we get?
steel
42
what type of steel is used to reinforce concrete?
low carbon steel
43
what phases are included in the iron-carbon phase diagram?
ferrite and cementite | during heat treatment it will pass through the austenite phase producing distinctive microstructures
44
what is ferrite?
pure iron, α-iron - BCC
45
what is cementite?
iron carbide Fe3C (a ceramic)
46
what does α + Fe3C mean?
pure iron (ferrite) and iron carbide (cementite) or PEARLITE
47
what is austenite?
γ-iron (higher temp phase) - FCC
48
what is the main difference between ferrite and austenite?
ferrite is body centred cubic | austenite is face centred cubic
49
at what temp does ferrite form?
room temp.
50
at what temp does austenite form?
912 - 1394 degrees C
51
at what temp does liquid iron form?
1538 degrees C
52
what happens if you increase the temp. from ferrite?
ferrite is a a soft, ductile, magnetic phase - if you increase the temp. you get austenite which is non magnetic
53
what do we have above 6.7wt% carbon?
pure cementite, Fe3C iron carbide - cementite is hard and brittle and can be used to enhance the strength of some steels
54
what is the eutectoid?
going from a solid to solid phase
55
what is the eutectic?
going from a liquid to solid phase
56
what is pearlite?
- pearlite is the laminated structure of ferrite and cementite formed during cooling by the diffusion of carbon - has alternating lamellar of ferrite and cementite - occurs at the eutectoid as the temp. decreases - it has soft, ductile ferrite as well as hard, brittle cementite making it brittle
57
what is martensite?
- formed when the steel is cooled very quickly, pearlite doesn't form because the carbon hasn't got enough time to diffuse - non equilibrium phase (don't see it on phase diagram) - martensite is very hard and brittle - BCT unit cell
58
what happens if you cool austenite very slowly?
you get pearlite (BCC) which is soft and ductile
59
what happens if you cool austenite very quickly?
you get martensite (BCT) which is hard and brittle
60
what unit cell is the structure of martensite?
BCT - body centred tetragonal
61
how can we use martensite formation to improve metal properties?
we can use quenching (heat treatment) to improve the strength and hardness of steels
62
why is welding an issue with medium to high carbon steels?
when the weld cools down martensite can form and because martensite is brittle it will result in a weaker weld - therefore you can't weld high carbon steel due to martensite formation
63
some info on low carbon steels?
- less than 0.25wt% carbon - produced in greatest quantities - unresponsive to heat treatments (difficult to form martensite) - strengthening achieved by cold working - relatively soft and weak, but excellent ductility - machinable, weldable (no martensite) - cheap, low cost to produce and manufacture with
64
what are some applications for low carbon steels?
- car body components - structural shapes (I-beams) - reinforced concrete - sheets used in pipelines and buildings
65
some info on medium carbon steels?
- 0.25-0.6wt% carbon - heat treatable to improve mechanical properties, but thin sections only - stronger but less ductile than low C steels
66
what are some applications for medium carbon steels?
- railway wheels and tracks - gear and crank shafts - high strength and wear resistance, moderate toughness
67
some info on high carbon steels?
- 0.6-1.4wt% - hardest, strongest and least ductile - heat treatable in thick sections but avoid welding - additions of Cr, V, W, form hard carbides with excellent wear resistance and hardness
68
what are some applications for high carbon steels?
- cuttings tools and blades | - drill bits
69
what is hardenability?
ease of martensite formation
70
why is martensite not observable in the iron-carbon equilibrium phase diagram?
martensite is a non-equilibrium phase formed during rapid cooling when diffusion is too slow to allow pearlite formation
71
why might you add chromium, vanadium or tungsten to a high carbon steel?
forms hard carbides which give excellent wear resistance and hardness
72
what crystal unit cell represents the structure of magnesium?
HCP
73
what method is suitable for the manufacture of a steel beam?
rolling of a billet - softening point of steel is too high so extrusion cannot be used and it's rolled
74
what does increasing carbon content do in terms of martensite production?
facilitates martensite formation