Midterm 1 Flashcards
Describe earth as a system
- earth is a system within which there are many substances
- energy enters and leaves
- matter is here to stay but cycles through subsystems
What are the layers of the earth’s atmosphere? Where do we experience weather and climate?
- troposphere: weather and climate, planes fly + tropospheric ozone
- stratosphere : atmospheric ozone
- mesosphere
- thermosphere
- exosphere
What are the temperatures of each layer of the atmosphere?
- troposphere: warm to cold
- stratosphere : cold to warm
- mesosphere: warm to cold
- thermosphere : cold to warm
- exosphere
What are the two forms of ozone? Where are they found?
- stratospheric ozone is ‘good ozone’
- tropospheric ozone: ‘bad ozone’
Describe the electromagnetic spectrum?
- different forms of radiation define the temperature of the object
- the sun emits mostly visible and near infrared light (it is 5500 C / 5800K)
- solar radiation comes in various EMR wavelengths
- 43% visible, 49% near infrared, 7% UV
Is all the energy from the sun the same EMR wavelength?
- no! Energy from the sun comes in various wavelengths: UV, near infrared, visible
Describe the peak forms of EMR energy from the earth and the sun + what is the earth’s effective temperature? What does this mean?
- the sun’s surface temperature is 5500 C, and its peak radiation is in visible wavelengths of light
- the earth’s effective temperature (it’s temp without an atmosphere) is -20 C, and its peak radiation is in thermal infrared wavelengths
Which has shorter wavelengths : the sun or the earth?
- the sun has far shorter wavelengths! - earth reflects longer, less energetic wavelengths back to space
Describe the normal ozone breakdown and formation?
- the shorter the wavelengths he more harmful UV radiation is to living organisms
- ozone naturally forms and breaks down as they absorb UV radiation
- typically ~10% of UV-B radiation gets to earth’s surface
Why is UV radiation harmful?
- UV harms the DNA molecules of living things in different ways
- one common form: UV causes the nucleotides to bind with each other rather than across the chain : causes a bulge and the DNA molecule doesn’t function properly
- UV is also damaging to shallow water marine organisms: urchin embryo has bulge
What other processes in the biosphere are impacted by UV radiation?
- photosynthesis: plants and phytoplankton
Describe the process of ozone formation and breakdown in the atmosphere?
- Oxygen + UV-C breaks down into two Oxygen molecules
–> Oxygen and Oxygen molecule forms Ozone O3 - hit with UV-B and breaks down into O and O2 - O + O3 forms 2 new oxygen molecules
What is the trend seen between CFCs and ozone?
- increase CFCS = decrease ozone
What are CFCs?
- chlorofluorocarbons: CF2Cl2
- ‘freon’ first synthesized in 1930’s
- used as coolants in fridges and air conditioners, used as propellants for spray cans, used to make foam cups and plates, non-toxic, combustible, volatile
How do CFCs break down?
- in CFC driven ozone breakdown:
- CFCs are released into the atmosphere
- UV-B breaks down and releases chlorine atom
- chlorine breaks down ozone into ClO and O2
- without ozone in stratosphere, more UV-B radiation reaches surface of the earth
Where is the largest area of ozone depletion in the atmosphere? Why?
- above Antarctica in the spine (September/October)
- 3 conditions met:
- cold: polar vortex and polar stratospheric clouds
- Chlorine in the atmosphere (due to CFCs)
- increased sunlight from springtime
What unit of measurement is used for ozone?
- the density of ozone is measured in Dobson units
What about polar stratospheric clouds is ideal for ozone breakdown?
- the frozen crystals making up polar stratospheric clouds provide a surface for the reactions that free chlorine atoms into the antarctic atmosphere
What molecule indicates ozone depletion?
the presence of CLO’s is a good indicator: is it a product of the breakdown of CFCs and ozone and is not formed naturally
How do PSCs impact the breakdown of CFCs?
- typically the breakdown of CFCs would occur very slowly and release more stable compounds
- the presence of PSCs allows for heterogenous reactions to occur: gaseous molecules stick to the solid particles (frozen water) and accelerates the rate of ozone depletion
- in the polar spring increase UV breaks down ozone
What is the key takeaway considering PSCs and heterogenous reactions
- heterogeneous reactions are critical to polar stratospheric chemistry
- allows slow/impossible reactions to occur efficiently and drives seasonal ozone depletion
What are the different ways to measure ozone?
- light sensors: uses Dobson spectrophotometer to measure how much light comes in from space
- satellites: measures ozone levels from space based on how much light is reflected
- ozonesondes: a sensor that provides ozone profile by sending it via weather balloon into different levels of the atmosphere: sensor has a source of potassium iodide which acts with ozone and provides a proportional amount of electricity
What is the Montreal protocol?
- addressed ozone depletion: 1987 180 countries agreed to reduce their CFC production by half
- depended cuts, addressed other prove,s, advanced time tables: by 2009 it was ratified by all countries of the world
- today production has decreased by 95%
- ozone is healing; set to mend by 2050
challenges: CFCs remain in atmosphere a long time, replacements are potent greenhouse gases that are now also being phased out
What did the MP do correctly to help it be so successful?
- used cautionary Principle
- policy makers and industry worked together to develop replacement chemicals
- used adaptive management as new s scientific data was procured