Midterm 3 Content Flashcards

(86 cards)

1
Q

MAJOR nutrient ions in seawater & are they limited?

A

major ions include:
Sodium (Na), Potassium (K), Magnesium (Mg), Calcium (Ca), Sulfur (S)
- These are UNLIMITED in seawater

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2
Q

MINOR nutrient ions in seawater & are they limited?

A

minor ions include:
Nitrogen (N), Phosphorus (P), Silica (Si)
- These are LIMITED in seawater and deemed as macronutrients for phytoplankton

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3
Q

Trace Metal ions in seawater & are they limited?

A

Trace metals include:
Iron (Fe), Zinc (Zn), Copper (Cu), Manganese (Mn), etc.
- These are quite LIMITED and are considered micronutrients

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4
Q

Macronutrient: Nitrogen
used for…?

A

N is used mainly for amino acids and protein building, and DNA and RNA formation
“soft parts”

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5
Q

Macronutrient: Phosphorus
used for…?

A

P is used mainly for DNA, RNA and ATP (energy transport)
“soft parts”

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6
Q

Macronutrient: Silicon
used for…?

A

Si is used only by some organisms to make skeletal structures made of Silica (like Diatoms)
“hard parts”

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7
Q

most common form of Phosphorus in the ocean

A

HPO4 ^(-2) = Hydrogen Phosphate makes up ~90% of phosphate in the ocean

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8
Q

where does phosphorus enter the Phosphorus Cycle?

A

Typically, phosphorus enters the phosphorus cycle through weathering of rocks and leeching from soil, which released dissolved reactive phosphorus into the hydrological cycle.

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9
Q

how long does dissolved phosphate cycle within the terrestrial ecosystem for?

A

Residence Time = around 10,000 years

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10
Q

how long does dissolved phosphate cycle within the ocean ecosystem for?

A

Residence Time = ~50,000 years

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11
Q

how is phosphorus removed from the phosphorus cycle in the ocean?

A

a very small amount of Organic P (that’s been taken up by phytoplankton) gets buried in the sediments at the bottom of the ocean, removing it from the cycle.
- Sedimentation is an output process from the ocean.

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12
Q

When Input > Output, reservoir inventory…

A

INCREASES
- can only increase inventory by either increasing input or decreasing output.

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13
Q

When Input < Output, reservoir inventory…

A

DECREASES
- Output rate is proportional to the inventory of the reservoir because removal rate depends on concentration

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14
Q

Most abundant form of FIXED Nitrogen?

A

Nitrate (NO3-)

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15
Q

Most abundant form of Nitrogen (overall)?

A

Molecular Nitrogen gas (N2)

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16
Q

define Nitrification

A

process of reduced forms of N, like Ammonium (NH4+), being oxidized into Nitrate (NO3-), which are organic forms that can be used by more organisms.

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17
Q

Most abundant form of Silicon in the ocean?

A

Silicon exists only as orthosilicic acid (or “silicic acid”) (H4SiO4) –a very weak acid.

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18
Q

How is silicon released?

A
  • by dissolution of silica (mixing it with water)
  • from chemical weathering of continental rocks (aluminosilicates)
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19
Q

Source of silicon to the ocean

A

Silicon comes from rivers (input) due to the hydrological cycle

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20
Q

Sink of silicon from the ocean

A

Silicon sinks through sedimentation (burial of biogenic silica)

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21
Q

How do biolimiting nutrients appear in the water column?

A

Surface (photic zone): low concentration due to uptake by phytoplankton (where photosynthesis > respiration)
Deep: high concentration due to regeneration by bacteria (and there’s respiration only)

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22
Q

2 layer box model - Surface vs Deep depth

A

surface depth = ~100 m
deep depth = ~3900 m

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23
Q

what is “water exchange” between the 2 ocean layers?

A

water exchange include upwelling, downwelling, and mixing.

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24
Q

define River Flux R (in 2 box model)

A

River Flux (mols/year) = input from rivers = River flow rate X River Concentration

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25
define Water Exchange Vm (in 2 box model)
Vm (mols/year) = Mu (mixing up) + Md (mixing down) Mu = Volume flux rate up X Concentration of Deep Md = Volume flux rate down X Concentration of Surface
26
define Flux F (in 2 box model)
F (g/year) = flux of particles X Concentration of particles
27
define Burial Flux B (in 2 box model)
Rate of burial of elements through sedimentation (final output) B = sediment mass accumulation rate (grams/yr) X concentration in sediment (moles/gram)
28
Surface Box Mass Balance Formula
R + Mu = Md + F River Input + Mixing Up = Mixing Down + Flux
29
Deep Box Mass Balance Formula
Md + F = B + Mu Mixing Down + Flux = Burial Flux + Mixing Up
30
water exchange between the surface layer and deep layer results in...
a net addition of nutrients to the surface water because volume up must EQUAL volume down, and the volume coming up innately has MORE nutrients in it because it's coming from the deep.
31
define Steady State Balance in 2 box model
at steady state, all inputs = outputs for each box and for the entire system. * make this assumption when doing calculations unless otherwise stated
32
define Nitrogen fixation
Forms of N involved: N2 (molecular N gas) Type of environment: ocean surface (where there is light), occurs where there is low nutrient concentration Organisms involved: Cyanobacteria Role of process: fixes N into organic form so it's available for other organisms to use
33
define Nitrate Assimilation
Forms of N involved: NO3- (nitrate) Type of environment: Anoxic/suboxic zones in deep ocean Organisms involved: Heterotrophs that eat phytoplankton Role of process: provides food & nutrient source for heterotrophs
34
define Ammonium Assimilation
oxidation of ammonium to organic N Forms of N involved: NH4+ (ammonium) Type of environment: Deep ocean (Aphotic zone) Organisms involved: taken up by phytoplankton Role of process: ammonium is taken up and formed into organic N (organisms).
35
define Ammonification
reduction of organic N to ammonium Forms of N involved: NH4+ (ammonium) Type of environment: Deep ocean (Aphotic zone) Organisms involved: heterotrophs that consumed phytoplankton Role of process: happens from respiration by bacteria, breaking down organic material
36
define Nitrification
conversion of ammonium to nitrate Forms of N involved: NH4+ to NH3 to NO2- to NO3- Type of environment: oxic and suboxic environments Organisms involved: nitrifying bacteria (genus Nitrosomonas and Nitrobacter) Role of process: supplies organic nitrogen to organisms for uptake and nutrients
37
define Denitrification
reduction of nitrate to dinitrogen gas Forms of N involved: NO3- (nitrate) & N2 (nitrogen gas) Type of environment: suboxic/anoxic zone Organisms involved: bacteria Role of process: formation of N2 gas from nitrates and nitrites
38
define Anammox
Loss of fixed N to N2 gas in in the ocean Forms of N involved: NH4+ and NO2- Type of environment: Suboxic zone Organisms involved: bacteria that use NH4+ and NO2- and form N2 that gets released Role of process: can limit oceanic primary productivity if too much fixed N is lost to N2 gas without being converted back.
39
is Nitrogen fixation inhibited if nitrate is present in seawater?
Yes, because N2 fixation requires a lot of energy, so if there's already nitrite supply it doesn't make sense to expend energy fixing more N when there's already an organic form available.
40
define Suboxic environment
a region of very low O2 concentration - tends to be in the deep ocean in the Aphotic zone
41
define Anoxic environment
a region of zero O2 concentration, so no oxygen is available. - in the deepest parts of the ocean where there is no light.
42
what is a limiting nutrient in seawater?
the nutrient that is completely utilized first (concentration goes to ~0).
43
define Redfield Ratio & it's values
the Average elemental composition of phytoplankton for optimally growing, nutrient-replete cells. 106 mol C: 16 mol N: (15 mol Si): 1 mol P - C ratio is usually negligible because it is so abundant in the ocean.
44
why is the Redfield Ratio useful?
it is an important and useful tool for assessing what the limiting nutrients are in an ecosystem
45
what is the global N & P concentration ratio in the water column?
N:P molar ration = 16 N: 1 P. In general, N & P concentration increases with depth. So the lowest N:P concentrations will be at the surface waters.
46
in the general ocean, what will you run out of first, N or P?
N will run out first because when graphed, N reaches zero when P still has a non-zero intercept.
47
define Remineralization
Remineralization includes all the processes that breakdown and return organic matter into their simpler, dissolved, inorganic forms (i.e. respiration, decomposition, nitrification, etc.)
48
what happens when phytoplankton die and sink to the ocean floor?
the phytoplankton organic matter is remineralized at depth and in Redfield Ratio proportions
49
how does nutrient concentrations change throughout the water column?
surface waters have LOW nutrient concentrations due to uptake by phytoplankton. As you move deeper, concentrations increase to be HIGH once in the deep where phytoplankton aren't growing and there is nutrient regeneration by bacteria.
50
what prevents the constant supply of unused nutrient to the surface from the deep?
stratification of the ocean layers! - when the vertical gradient in the ocean is sharp, there is strong stratification which makes it difficult for the mixing of deep water into the surface waters.
51
how do seasons affect the thermocline in temperate regions?
in winter months, there is no thermocline because the ocean is well-mixed due to cold temperatures and strong winds. As spring warms in temperature, the thermocline steepens and results in very stratified water column by the summer months and LITTLE MIXING.
52
what brings nutrients up into the Euphotic layer (surface)?
1. Turbulent diffusion - wind mixing 2. Advection - upwelling from the deep
53
what causes a Fall bloom in temperate regions?
Fall blooms are not as large as the spring bloom. - Caused by the increased mixing as winds pick up and temperatures drop after the summer months when there was high stratification. More nutrients get brought up from the deep, causing an increase in phytoplankton biomass.
54
define N*
N* is essentially the slope on a graph of nitrate vs phosphate concentration in the ocean. N* = [NO3-] - 16[PO4] - At the Redfield Ratio, N* = 0 ( when N = 16P), which is when there's normal photosynthesis and remineralization occurring.
55
when N* > 0...
indicates that there is extra N supply or P loss (steeper slope)
56
when N* < 0...
indicates that there is N loss. (less steep slope)
57
Denitrification causes N* to...
Decrease so N* < 0 Lowers only N value, not P
58
Anammox causes N* to...
Decrease so N* < 0 Lowers both N and P value
59
define OMZ (Oxygen Minimum Zone)
the suboxic zone of the ocean, right below the photic zone. where denitrification tends to happen high nutrient concentration! (even with relative N "deficit" to P)
60
what is N* is the OMZ?
N* is very (-) in the OMZ N* < 0
61
Vertical N* Distribution: Surface (oxic)
N* = 0 (normal nutrient conditions) N* > 0 (if N-fixation is occurring) N* < 0 (if strong upwelling region from OMZ)
62
Vertical N* Distribution: OMZ (suboxic)
N* < 0 (denitrification and/or anammox)
63
Vertical N* Distribution: Deep (anoxic)
N* = 0 (remineralization) N* > 0 (N2 fixation regions)
64
wind blowing over water causes...
- stress on the water, creating waves that cause turbulence and mixing. - puts surface waters into motion creating wind-driven circulation
65
how do you calculate the amount of stress on the water that comes from the wind?
Tw = paCW^2 where pa = air density C = drag coefficient (normally 2 x 10^-3) W = speed of the wind Tw given in units of N/m^2 (force/unit area)
66
what causes winds?
winds are caused by the differential heating at varying latitudes that lead to differences in air temperature between the equator and poles. Creates regions of high and low density, resulting in movement of the air.
67
define Hadley Cell
a thermally driven circulation pattern caused by the rising of warm air near the equator & moving toward the poles and sinking of cold air near the poles & moving toward the equator. - typically found near the equator due to the rotation of the earth.
68
3 air-circulation cells per hemisphere are:
1. Hadley Cell - next to the equator 2. Polar Cell - at the poles 3. Ferrel Cell - around the temperate regions between the other two cells, where the circulation goes the opposite direction
69
how does the Coriolis force effect winds?
In the northern hemisphere, winds are deflected to the right. in the southern hemisphere, winds are deflected to the left. So, the flow is never directed straight from the poles to the equator.
70
define "westerlies"
winds that come from the west and are directed to the east.
71
define "easterlies"
winds that come from the east and are directed to the west.
72
regions where the air is descending (sinking) are...
high pressure regions
73
regions where the air is ascending (rising) are...
low pressure regions
74
geostrophic flow direction is related to pressure in the way that...
in the Northern hemisphere, high pressure will be kept to the right of flow. In the Southern hemisphere, high pressure will be kept to the left of flow.
75
what do continents do to the wind cell pattern?
continents tend to break up the wind cell pattern into more 3D patterns that are less regular, but they still maintain the latitudinal bands of high and low pressure and the westerly/easterly flows.
76
high pressure = good weather because ...
high pressure is from sinking, warm air. warm air can hold more water vapour so the descending air becomes relatively drier
77
low pressure = rainy weather because ...
low pressure is from rising, cold air. cool air holds less water vapour. so the water vapour leaves the air as rain.
78
what latitudes tend to have more vs less precipitation?
high precipitation occurs near the equator and near 45-60 degree latitudes. low precipitation occurs between these near 30 degree latitudes and at the poles.
79
describe the basic Ekman dynamics when wind blows on the surface of the ocean
- wind causes stress/net force on the ocean surface, causing the water to accelerate in the direction of the applied stress - the water gets deflected to the right due to Coriolis effect - this causes stress on the water below due to friction forces - water below gets dragged and continuously shifted to the right until the energy dissipates at depth of the "Ekman layer"
80
define Ekman Spiral
how the velocity vectors spiral and decrease exponentially with depth (after wind force is applied to the surface waters) = Ekman Spiral due to Coriolis effect, the surface current flow is moving 45 degrees to the right of the wind direction (N hemisphere)
81
define Ekman Transport
the depth average (net) flow of water in the direction of 90 degrees to the right of wind direction also known as geostrophic velocity/flow
82
define Ekman Volume Flux
volume of water transported given by units ___ Ekman Volume flux = Tw/pf * do not need to know Ekman layer depth for this.
83
Ekman convergences happen when ...
there is clockwise circulating winds (N hemisphere) and vice versa in the S hemisphere i.e. high pressure in the centre
84
Ekman divergences happen when ...
there is counter-clockwise circulating winds (N hemisphere) and vice versa in the S hemisphere i.e. low pressure in the centre
85
Ekman spiral assumptions:
1. the 'eddy velocity' is constant with depth 2. the ocean is homogenous (not stratified) but NET FLUX IS ALWAYS 90 DEG TO THE WIND (not an assumption)
86
define Ekman layer
the vertical region near the ocean surface that is affected by wind forces on the surface of the ocean. i.e. goes to the depth where the Ekman spirals would end Ekman layer IS NOT the mixed layer though.