midterm Flashcards

1
Q

how to calculate formal charge

A

valence electrons-(free electrons+bonds)

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2
Q

How can an excited atom return to a lower energy level?

A

by emitting light energy

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3
Q

How can an atom be excited into a higher energy level

A

by absorbing light energy

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4
Q

how is wavelength and frequency related

A

they are inversely proportional

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5
Q

where is alkali metals

A

elememts of group 1 (column)

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6
Q

where are alkali earth metals

A

elements of group 2

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7
Q

where are the halogens

A

elements in group 17

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8
Q

where are the inert noble gasses

A

elements in group 18

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9
Q

where are the transition metals

A

elements in groups 4-12

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10
Q

where are the non metals

A

the “stairs from group 13-18

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11
Q

what are the first three quantom numbers

A

they identify the position of an electron in orbit

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12
Q

what does the last quantum number represent

A

the spin of the electron around its axis

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13
Q

which quantum number helps explain an atom’s magnetic properties

A

the last one (ms) : the spin of the electron around its axis

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14
Q

In quantum numbers, what does N represent?

A

the energy of an electron; the smaller the N, the lower the energy. also coincides with the distance the orbit is from the nucleus

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15
Q

what is the angular momentum quantum number

A

L, defines the different orbitals possible within an energy level.

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16
Q

the number of shapes possible of an orbital is dependent on what.

A

L is dependent on the size of the major energy level (N)

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17
Q

What are the possible values of L

A

N-1=L (any number lower than N)

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18
Q

What is the magnetic quantum number

A

ML; indicates how many orbitals there are that have the same N value and the same L value, but a different orientation (same distance from nucleus, same path, different orientation)

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19
Q

If L=2, what are the possible ML

A

2,1,0,-1,-2 (five different orientations

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20
Q

What is the spin quantum number

A

MS; Used to describe the possible directions of the spin of an electron.

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21
Q

what are the possible values of MS

A

-1/2, 1/2

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22
Q

What makes an atom have magnetic properties?

A

unpaired electrons

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23
Q

define diamagnetic

A

when an atom has all paired electrons

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24
Q

equation to determine maximum number of electrons in a major energy level

A

2N^2

eg. in the 4th energy level: 2(4)^2=32electrons

25
what is Hunds rule
when filling sub shells of the same major level, every Subshell gets one before any get 2
26
how to calculate how much attraction is from the electron to the nucleus
electrons/protons
27
Describe the periodic properties of atomic and ionic radii
as you go to the right, radii decreases. as you move down, radii increases
28
what is ionization energy
energy required to remove an electron from a gaseous atom
29
describe the periodic trends of ionization energy
as you go to the right, it increases. as you go down, it decreases
30
what is electron affinity (EA)
amount of energy it will give in order to gain an electron (energy released when a gaseous atom gains an electron)
31
describe the periodic trends of electron affinity
increases to the right, decreases going down
32
what is electronegativity
measure of the tendency of an atom to gain electrons (how badly an atom wants an electron)
33
describe the trends of electronegativity
increases to the right, decreases down
34
what is a pi bond
double bond looking thing
35
what property must an atom have in order to have a PI bond
a P orbital
36
properties of PI binds
atoms must have a P orbital not as string as theta bonds they indirectly overlap (meaning the electrons are basically jumping to and from bond) easy to break
37
2 electron pairs =
sp,linear,180
38
3 electron pairs =
sp2,trigonal planar,120
39
4 electron pairs=
sp3, tetrahedral, 109.5
40
5 electron pairs=
trigonal bypiramid, 90,120,180
41
6 electron pairs=
sp4d2,octahedral, 90,180
42
sp
linear, 180
43
sp2
trigonal planar, 120
44
sp3
tetrahedral, 109.5
45
sp3d
trigonal bypyramid, 90,180,120
46
sp3d2
octahedral, 90,180
47
Ab3 shape
trigonal planar,120
48
AB2 shape
linear,180
49
AB4 shape
tetrahedral, 109.5
50
AB3E
Trigonal pyramidal
51
AB2E2
bent/angular
52
AB5
trigonal bypyramidal
53
AB4E
seesaw
54
AB3E2
T-shaped
55
AB2E3
Linear
56
AB6
octahedral
57
AB5E
Square pyramidal
58
AB4E2
square planar