Midterm SEAM 4 Flashcards
(97 cards)
when a refined metal is naturally converted to a more stable form such as its oxide, hydroxide or sulphide state this leads to deterioration of the material
Corrosion
Main Factors influencing the Rate of Corrosion
Diffusion
Temperature
Conductivity
Acid
Types of Ion
Electrochemical Corrosion
the process resulting from random motion of molecules by which there is a net flow of matter from a region of high concentration to a region of low concentration
Diffusion
– the measure of hotness or coldness expressed in terms of any of several scales, including Fahrenheit and Celsius
– indicates the direction in which heat energy will spontaneously flow—i.e., from a hotter body (one at a higher temperature) to a colder body (one at a lower temperature)
Temperature
a measure of the ability of water to pass an electrical current
Conductivity
a chemical substance, usually a liquid, which contains hydrogen and can react with other substances to form salts
Acid
occurs when two dissimilar metals are present in an electrolytic medium
Electrochemical Corrosion
– a chemical compound that dissociates into ions and hence is capable of transporting electric charge - i.e.
– an electric conductor; unlike metals the flow of charge is not a flow of electrons, but is a movement
Electrolyte
electrically charged atoms
Ions
Two types of ions
Cations
Anions
positively charged ions
Cations
negatively charged ions
Anions
when metals collect this, an electrochemical reaction causes the steel to corrode
Moisture
– also known as metal oxides
– forms when oxygen reacts with metal atoms
Rust
– a coating which is the major line of defense against corrosion in ballast tanks and void spaces
– in ballast tanks, they are commonly used and there is some interest in using inert gas atmospheres
Hard Epoxy Coating
– a means of preventing electrochemical wastage is required
– a system of preventing corrosion by forcing all surfaces of a structure (e.g. hull) to be cathodes by providing external anodes
Cathodic Protection
A type of Cathodic Protection that can be accomplished by fitting aluminium, magnesium or zinc anodes in tanks or underwater portion of a ship, which waste away by galvanic action
Sacrificial Anode Cathodic Protection
A type of Cathodic Protection that can be achieved by superimposing on the hull an impressed current provided by a remote
power source through a small number of inert anodes
Impressed Current Cathodic Protection
Two Types of Cathodic Protection Method
Sacrificial Anode System
Impressed Current System (ICCP)
– metals or alloys attached to the hull that have a more anodic, i.e. less noble, potential than steel when immersed in sea water
– supply the cathodic protection current, but will be consumed in doing so and therefore require replacement for the protection to be maintained
Sacrificial Anodes
– may be safely employed
– sacrificial anodes made of zinc that are attached to a ship’s hull
– a critical component of a cathodic protection system, which is used to protect the ship’s metal structure from corrosion
– they work by corroding instead of the hull, providing protection against corrosion
Zinc Anodes
– consists of a number of anodes (lead or platinised titanium) fitted to the hull at
selected places below the waterline, and control equipment which automatically
regulates the anode current to the required value
– consists of anodes connected to a DC power source
Impressed Current Cathodic Protection (ICCP)
an electrical device used to convert alternating current (AC) into direct current (DC) by allowing a current to flow through the device in one direction only
Rectifier
The process where diodes work like one-way valves within the rectifier to maintain the flow of current
rectification