Module 3 Flashcards
(12 cards)
Where has evidence for how the electrons are arranged in atoms come from
Ionisation energies
What is the 1st ionisation energy
Energy required to remove one electron from each atom in a mole of gaseous atoms producing one mole of 1+ ions
What is the 2nd ionisation energy
Energy required to remove only the second electrons
1st and 2nd ionisation energy of Na
1st] Na(g) —> Na+(g) + e-
2nd] Na+(g) —> Na2+(g) + e-
What three factors affect ionisation energy
Distance from the nucleus
Electron shielding
Nuclear charge
Balance for ionisation energy
Nuclear charge. Distance, shielding
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Ionisation energy as you go down a group
As you go down the group, the ionisation energy decreases and the element have more shells, as distance of outer electron from nucleus increases so does shielding
Explanation for generals increase in ionisation energy as you go across a period
The nuclear charge increases, shielding stays the same, distance decreases slightly
Exception of general increase of ionisation energy between group 2-3 explanation
2p subshell higher energy than 2s so 2p electron easier to remove
Exception of general increase of ionisation energy between group 2-3 explanation
llhighest energy in 2p, but paired in 6- electrons repel making it easier for them to be removed
When are successive ionisation energies greater
After 1st electron, remaining electrons pulled closer yo nucleus, nuclear attraction increases so more energy needed
How do successive ionisation energies allow predictions about number of electrons in the outer shell .’. Group .’. Element
If there’s a large increase is successive ionisation energies electron has been removed from shell closer to the nucleus with less shielding