Module 4 Flashcards
(22 cards)
It is the equilibrium constant for the equilibrium that exists between a solid ionic solute and its ions in a saturated aqueous solution
Ksp
The solubility of an ionic precipitate decreases when a soluble compound containing one of the ions of the precipitate is added to the solution. This behavior is called
common-ion effect
is a technique often used to analyze substances in our daily lives even if we are unaware of it.
Gravimetric Analysis
the analyte is separated from
a solution of the sample as a precipitate and
is converted to a compound of known
composition that can be weighed.
precipitation
the analyte is separated from
other constituents of a sample by
conversion to a gas of known chemical
composition. The weight of this gas then
serves as a measure of the analyte
concentration.
volatilization
the analyte is separated by
deposition on an electrode by an electrical
current. The mass of this product then
provides a measure of the analyte
concentration.
electrogravimetry
the mass of the reagent, of
known concentration, required to react
completely with the analyte provides the
information needed to determine the analyte
concentration.
gravimetric titremitry
uses a mass spectrometer to
separate gaseous ions formed from the
elements making up a sample of matter. The
concentration of the resulting ions is then
determined by measuring the electrical
current produced when they fall on the
surface of an ion detector.
mass spectrometry
Experimental variables that affect the particle size of precipitates:
- Solubility
- Temperature
- Reactant concentrations
- Rate at which reactants are mixed
solution is an unstable
solution that contains a higher solute
concentration than a saturated solution. With
time, this solution is relieved by precipitation of
the excess solute.
supersaturated
is a process in which a minimum
number of atoms, ions or molecules join
together to give a stable solid.
nucleation
is a process in which a
substance (gas, solid or liquid) is held on the
surface of a solid.
adsorption
involves retention of a substance within the pores of a solid.
suspension
are tiny particles are invisible to the naked eye
and show no tendency to settle from solution,
nor are they easily filtered.
colloidal suspension
temporary dispersion of particles in a liquid phase; particles tend to settle sponstaneously and are readily filtered.
crystalline suspension
made up of fine particles that have not grown together to form an extensive lattice structure.
curdy suspension
much larger in number and of much smaller dimension than those of crystalline precipitate where a large quantity of water is adsorbed
gelatinous precipitate
is a process by which a coagulated colloid returns to its dispersed state.
peptization
is a process in which a precipitate is heated for an hour or more in the solution from which it was formed (the mother liquor).
digestion
is the solution from which precipitate was formed.
mother liquor
is a process in which normally soluble compounds are carried out of solution by a precipitate
Coprecipitation