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A Level Chemistry Ocr > Module 4 Chapter 13 > Flashcards

Module 4 Chapter 13 Flashcards

1
Q

what are aliphatic molecules

A

Containing carbon atoms joined together in unbranched (straight) or branched chains and are not aromatic

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2
Q

What is the general formula of alkenes

A

CnH2n

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3
Q

What can alkenes be

A

They can be branched and contain more than one c=c double bond or be cyclic

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4
Q

What do cyclic alkenes and alkenes with more than one c=c bond do

A

Cyclic alkenes and alkenes with more than one c=c don’t follow the general rule

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5
Q

What can each carbon form

A

They can make 4 covalent bonds as they have 4 electrons present

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6
Q

What are 3 of the electrons used in and where are the bonds found

A

3 of the electrons are used in 3 sigma bonds
Where:
1 is to the other carbon in the double bond
2 are to two other atoms (c or h)

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7
Q

What is 1 electron in the carbon - carbon double not involved in and what orbital is it in

A

1 electron on each carbon atom of the double bond is not involved in sigma bonding
This electron is in a p orbital

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8
Q

What is a pi bond

A

It is formed by the sideways overlap of two orbitals, one from each carbon in the double bond

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9
Q

What does each carbon involved int eh double bond do

A

It contributes one electron to the electron pair in the pi bond.

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10
Q

Where is the electron density in the pi bond concentrated

A

Above and below the sigma bond.

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11
Q

What does the pi bond do (rotation)

A

It locks the 2 carbons of the C=C in position and thus, prevents them from rotating around the double bond

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12
Q

What is the shape of the molecule around the carbon atoms in the double bond

A

It is trigonometric planar as there are 3 regions of electron density. They repel as far apart as possible - so the bond angle is around 120*.

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13
Q

What are alkenes used in

A

The production of plastics - polymers
Some alkenes regulate fruit ripening - ethene
Pharmaceutical synthesis
Used as fuels - found in diesel
Used to make detergents and can be converted to alcohols.

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14
Q

What are the possible reactions of alkenes

A

Combustion

Electrophilic addition includes
Hydrogen
Bromine
Hydrogen bromides
Steam

Additional polymerisation (free radicals)

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15
Q

What is the reactivity of alkenes

A

They are more reactive than alkanes due to the pi bond

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16
Q

Why are alkenes more reactive than alkanes due

A

C=C bond is made up of a sigma bonding and a pi bond

The pi bond electron density is concentrated above and below the plane of the sigma bond

The pi electrons are more exposed

Therefore the pi bond more readily breaks and alkenes undergo addition reactions relatively easily

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17
Q

What occurs in Electrophilic addition

A

A small molecule is added across the double bond, the pi bond breaks and new bonds form

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18
Q

What is the word equation for the hydrogenation of alkenes

A

Alkene + hydrogen (+ nickel catalyst) —> Alkane

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19
Q

What are the conditions and catalyst required for the hydrogenation of alkenes and what occurs in the reaction

A

423K and a nickel catalyst
Hydrogen is added across the double bond = addition = hydrogenation

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20
Q

What is the halogenation of alkenes

A

it is where chlorine or bromine at room temperature is added across the c=c bond to form a haloalkane

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21
Q

How can halogenation be used to differentiate between alkenes and alkanes

A

Add orange bromide water drop wise to a sample of an alkene, the bromine is added across the double bond and the colour disappears. This tells us a c=c bond is present. Whereas if it was done for an alkane there would be no change in colour.

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22
Q

What is the reaction conditions of the addition addition of hydrogen halides to alkenes

A

Alkenes react with gaseous halides at room temperature forming haloalkanes. They are both gases when you mix them together.

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23
Q

How are the hydrogen halides added if the alkene is a liquid

A

Then the hydrogen halide is bubbled through

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24
Q

What do alkenes also react with (acid)

A

They also react with concentrated HCl or HBr (hydrobromic acid)

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25
What is a characteristic of the reaction (hydrogen halides + alkenes) (product)
A variety of different products are formed (unsymmetrical or symmetrical)
26
What is the word equation of the hydration of alkenes
Alkene + water (g) + (phosphoric acid catalyst) —> alcohol
27
What does the steam do in the reaction and what is it used for in industry
It adds across the double bond - an addition reaction widely used in industry to make ethanol.
28
What is an isomer
The same structural formula but a different arrangement of the atoms in space
29
When does E/Z isomerism occur
It only occurs when a c=c double bond is present
30
Why does E/Z isomerism occur
It occurs when the rotation around the double bond is restricted So groups attached to either side are fixed relative to each other If a molecule has both a c=c bond and different groups attached to each carbon atom of the double bond then E/Z isomerism will occur.
31
When is it a Z isomer
It is a Z isomerism when the groups that have the biggest atomic number on the carbon are on the same side
32
What is Cis-Trans isomerisation
It is a special case of E/Z isomerism, where one of the attached groups on each C=C must be hydrogen
33
When is it a cis isomer and when is it a trans isomer
Hydrogen atoms on the same side (z/cis) Hydrogen atoms on diagonally opposite sides (e/trans)
34
What is Electrophilic addition
When alkenes undergo addition reactions to form a saturated compound
35
What does the double bond represent and do
The double bond in an alkene represents a region of high electron density because of the pi electrons. This highly electron density attracts electrophiles.
36
What is an electrophile
An atom or group of atoms that is attracted to an electron rich centre and accepts an electron pair. Usually they are a positive ion or a molecule with a partially positive charge.
37
Draw the mechanism for the Electrophilic addition of hydrogen bromide to an alkene (general)
38
What are carbocations
They are positive ions, with the positive charge on the carbon ion.
39
Why are carbocations unstable
Because they contain a positively charged carbon atom which creates an electron deficiency
40
Draw the mechanism for the Electrophilic addition of bromine to an alkene (general)
41
What does Markownikoff’s rule show
How to predict which of two possible isomers is the major product
42
What are the three different types of carbocations
Primary carbocations, secondary carbocation, tertiary carbocation
43
What is the most stable carbocation and why
The most stable carbocation is the tertiary carbocation as they have the most carbon chains attached to them, so there are more electrons present to stabilise the carbocation.
44
What will the major product be using markowniff’s rule
The major product will be the reaction with the carbocation that is the most stable
45
Draw the mechanism for the Electrophilic addition of an acid
DRAW IT
46
Draw the mechanism for the Electrophilic addition of water
DRAW IT
47
What are polymers made up from
Monomer repeat units
48
What do monomers undergo to form a polymer
A polymerisation reaction
49
What are the properties of condensation polymers
They can be made up of repeating monomers or different monomers, and an additional molecule is produced. The monomer units also form links.
50
What are addition polymers
They are composed of a repeating pattern of a single monomer, no other products are produced in the reaction.
51
What type of molecule undergoes addition polymerisation
Unsaturated alkenes
52
What does addition polymerisation produce
Long saturated chains
53
What are addition polymerisation reactions conditions
High temperatures and high pressures using catalysts.
54
What does the reaction produce (addition polymerisation)
Long saturated chains
55
How are polymers names
After the original monomer usually with poly as the prefix. For example poly (ethene)
56
What is the repeat unit
It is the specific arrangement of atoms in the polymer
57
How is the repeat unit represented
It is always written in squared brackets, and after the bracket a letter n is written to show that there are a large number of repeats.
58
What are the steps to draw repeat units from monomers
Remove the double bond Add brackets Draw the single bond to the left and the right of the repeating unit N to show that we don’t know how many are joined up.
59
What can high density polymer chains do
Linear polymer chains can pack tightly together, increasing the number of particles in a given amount. There will also be more surface contact between the high density polymer molecules meaning Greater London forces and overall strength.
60
What are low density polymer chains
They have lots of branched chains preventing molecules from packing too close together
61
What are high density polymer chains
They are linear with few branched chains allowing molecules to pack very close together
62
What are the differences in formation strength and uses of high density polymers compared to low density polymers
Formation- LD (high pressure and trace oxygen), HD (low pressure and catalyst at 50*C) Strength - LD (weak and lower melting point), HD (strong higher melting point) Uses - LD - Clingfilm, plastic bands, HD - bottles, storage tubs
63
What are uses of poly (ethene), and its monomer and the same for poly(tetrafluoroethene)
Plastic bands, plastic Monomer - ethene Coating for non stick pans, permeable membrane for clothing and shoes Monomer - tetrafluoroethene
64
What is the monomer of poly (chloroethene) and its uses and the same for poly(styrene)
Monomer - chloroethene Uses - pipes, films, Monomer - Styrene/phenylethene Uses - cups, food trays,
65
Why are polymers commonly used but bad for the environment
They are easily available, cheap and convenient. They are not very reactive which is good for food and chemical storage, however not so great for degradation So have serious environmental effect including land fills and threats to land and marine life
66
How does recycling reduce environmental impacts and limitations
It conserves fossil fuels and decreases the amount of waste in landfill However you can’t mix polymers and they need to be separated in order to effectively recycle. PVC: is hazardous as it has a high chlorine content and additive present so it can’t be buried or burnt (as it will release HCL - a corrosive gas)
67
How can PVC be recycled
Solvents dissolve polymers, so high grade PVC can be recovered by precipitation form solvent and the solvent is used again.
68
How can waste polymers be used as a fuel
Some are derived from petroleum or natural gas —> high stored energy value Can be incinerated to produce heat —> steam —> drive a turbine —> electricity
69
What is feedstock recycling
It involves both chemical and thermal processes Reclaims monomers, gases or oil Products produced resemble those from crude oil refineries. So it can be used as raw materials from production of new polymers
70
What are Bioplastics
They are plastics produced from plant starch, cellulose, plant oils and proteins. They are renewable and sustainable conserving oil reserves and protecting the environment.
71
What does biodegrade-able mean
It can be broken down by microorganisms into water, CO2 and biological compounds. And compostable polymers leave no visible toxic residues.
72
What does photodegradable mean
Photodegradable oil based polymers have been developed They contain bonds that are weakened by absorbing light to start the degradation Light absorbing additives are used.

A Level Chemistry Ocr (20 decks)

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