Module 6 Flashcards

1
Q

Strong Acids

A

Fully ionise
Strong electrolyte conductors
–>

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2
Q

Names of strong acids

A

HCl
HBr
HI
H2SO4
HNO3
HCLO4,3
SO I Have NO Clean Clothes

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3
Q

Weak Acids

A

Partially ionises
-><-

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4
Q

Strong Bases

A

Fully ionises

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5
Q

Names of Strong Bases

A

NaOh, KOH, Ca(OH)2, Ba(OH)2
NO KO CO BO

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6
Q

Weak Bases

A

Partially
To show their basic behaviour first show the dissolution of the base irreversible
1.) Na2CO3 –> 2Na+ + CO2-3
2.) Co2-3 + H2O -><- HCO-3 +OH -

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7
Q

Ka

A

Equilibrium constant for ionisation of acid into a hydrogen ion
If triprotic, then mutiple ka’s for each disassociation

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8
Q

How do indicators work?

A

Weak acids and bases

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9
Q

Methyl Orange

A

Low pH (acidic) red
High pH (basic) yellow
Range: 3.1-4.4

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10
Q

Litmus

A

4.5-8.3

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11
Q

Bromothymol Blue

A

Low pH (acidic) Yellow
High pH (basic) Blue
Range: 6.0-7.6

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12
Q

Phenolphthalein

A

Low pH (acidic) colourless
High pH (basic) pink
Range: 8.2-10.0

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13
Q

Why use BaSO4?

A

White solid
Neutral white background to see colour change seeping through soil

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14
Q

Metal hydroxide and acid reaction

A

BASH2O

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15
Q

Acid and Metal Carbonate

A

CASH2OCO2

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16
Q

Acid and Ammonia

A

Special case: does not contain oxygen but is an acidic, and instead will only produce ammonium salt

17
Q

Enthalpy of neutralisation

A

negative - exothermic

18
Q

Lavoisier

A

1st
Acids contain oxygen

19
Q

Davy

A

2nd
Acids contain. hydrogen
Doesn’t explain why e.g. ch4 is not acidic

20
Q

Liebig

A

3rd
Acids contain hydrogen which is replaced by a metal

21
Q

Arrhenius

A

4th
Acid: ionises in water to produce hydrogen ions
Base: ionises in water to produce hydroxide ions

22
Q

Limitations of Arrehenius

23
Q

Brønsted-Lowry

A

Acid: proton donor
Basez: proton acceptor

24
Q

Limitations of Brønsted-Lowry

A

Cannot explain reactions with acidic oxides or basic oxides e.g. CaSO4

25
Conjugate base of weak acid
strong conjugate base
26
Will a solution of KF be acidic or basic?
1. KF --> K+ F- 2. F- + H2O --><-- OH- + HF So basic
27
Degree of Ionisation
%ionised: [H+] eqm/[HA]ini *100
28
pH after dilutions for strong acid/bases
c1v1=c2v2
29
pH of solutions after mixing (Strong acid and Strong acid or base/base)
Total moles of h+ or OH- is the sum *don't forget volume)
30
pH after neutralisation
Subtract acid and base * keep in mind which is xs * keep in mind volume
31
Buffer
Resist changes in pH when small amounts of a/b are added Exists in equilibrium
32
How are buffers made?
Mixing a weak acid and its conjugate base of weak base and conjugate acid
33
Blood Buffer
H2CO3/HCO-3