Module I Flashcards

(39 cards)

1
Q

Extensive property

A

A property that depends on how much matter you have

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2
Q

Intensive property

A

A property that does not depend on its quantity

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3
Q

Absolute error =

A

Measured value - True value

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4
Q

Relative error =

A

Absolute error / True value

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5
Q

What is absolute error?

A

The difference between a measured value and a true value

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6
Q

What is relative error?

A

The proportion of the absolute error relative to the measured value

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7
Q

Standard state of metals

A

Solid (except for mercury, a liquid)

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8
Q

Standard state of nonmetals

A

Solid

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9
Q

Standard state of diatomic nonmetals

A

Gas

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10
Q

Exceptions to diatomic nonmetal standard states

A

Iodine (solid) and Bromine (liquid)

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11
Q

Standard state of phosphorus

A

P4(s)

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12
Q

Standard state of sulfur

A

S8(s)

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13
Q

Definition of precision

A

How closely clustered together the measurements are

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14
Q

Definition of accuracy

A

How close to the true value the measurement is

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15
Q

When will charge items not interact?

A

When they are infinitely far apart

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16
Q

Quantum number n

A

Principle quantum number, shell number

Roughly describes the distance from the nucleus

Fully describes energy in single electron systems

17
Q

Quantum number L

A

Shape of orbitals
s, p d, f
s = 0 … f = 3
Max value = n-1

18
Q

Quantum number m(L)

A

Magnetic quantum number

Orientation of orbital

-L <= m(L) <= L

19
Q

Quantum number m(S)

A

Spin quantum number

Property of the electron itself, not its orbital

Either +1/2 or -1/2

20
Q

Which electrons are best at screening?

A

The electrons closest to the nucleus are best at screening the nucleus’s charge from outer electrons

21
Q

Why is there no 1p orbital?

A

Because p indicates that L=1, therefore n must equal 2

22
Q

Effective nuclear charge

A

The pull exerted on a specific electron by the nucleus, notated as Z(eff)

23
Q

What makes a group of atoms and/or ions isoelctronic?

A

Sharing the same electron configuration

24
Q

Ionization energy

A

The amount of energy required to remove the most loosely bound electron (cation formation)

25
Electron affinity
The energy change for the process of adding an electron to form an anion. Can be endothermic or exothermic.
26
A compound made of nonmetals only is usually...
Molecular
27
A compound made of metals and nonmetals is usually...
Ionic
28
Determinate error
Causes the mean of a data set to differ from the accepted value
29
Indeterminate error
Causes data to be scattered roughly symmetrically around a mean value (also called random error)
30
Dalton's atomic theory
1. Elements consist of indivisible small particles 2. All atoms of the same elements are identical 3. Atoms can neither be created nor destroyed
31
What subshells do electons fill first?
The ones with the lowest available energy
32
You calculate that two of an atoms electrons share the same set of four quantum numbers. Is this correct?
No. The Pauli Principle states that no two electrons in an atom can have an identical set of four quantum numbers. You likely made a mistake somewhere.
33
Hund's rule
All orbits will be singly occupied before any is doubly occupied
34
Empirical formula
Simplest whole number ratio of atoms found in a compound/molecule
35
Simplest whole number ratio of atoms found in a compound/molecule
Empirical formula
36
How to calculate the total number of orbital nodes:
n - 1 n being the first quantum number, referring to an electron's shell (think Bohr model)
37
How to calculate the total number of angular/planar nodes:
L L being the second quantum number, corresponding to the s p d f orbital shapes
38
How to calculate the total number of radial/spherical nodes:
n - 1 - L For the smartasses, just subtract the number of angular/planar nodes from the total number of orbital nodes
39
What is light's/photons ability to excite and eject an electron dependent on?
The frequency of the photon wave, NOT its intensity! This is because energy is quantized (smallest divisible particle is a photon). It's not continuous