multiple choice 2 Flashcards

1
Q

CO2(g)+ H2O(g) ⇋ H2CO3(aq) + Heat
According to Le Chatelier’s Principle, what two conditions can be applied to dissolve more
carbon dioxide?
a) Increase pressure and decrease temperature
b) Decrease pressure and increase temperature
c) Increase pressure and increase temperature
d) Decrease pressure and decrease temperature

A
A - Increase pressure will drive towards right 
as less gas moles on this side
 Decrease temp as this reaction is 
exothermic and this will push towards 
right hand side
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is the concentration of silver ions in a saturated solution of silver iodide?

a) 4.26 x 10-9 mol L-1
b) 9.23 x 10-9 mol L-1
c) 8.52 x 10-17 mol L-1
d) 9.23 x 10-18 mol L-1

A

B - AgI  Ag+ + I-
Ksp = [Ag+] [I-]
Ksp = 8.52 x 10-17 (from formula sheet) = x2
x = square root of 8.52 x 10-17 = 9.233 x 10-9

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Which of the following has the homologous series in order of increasing polarity?

a) Alcohols, alkanes, carboxylic acids
b) Alcohols, carboxylic acids, alkanes
c) Alkanes, alcohols, carboxylic acids
d) Alkanes, carboxylic acids, alcohols

A

C -
Alkanes = non-polar
Alcohols = polar due to presence of hydroxyl
at end
Carboxylic acids = more polar due to carbonyl
group and hydroxyl group

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

The table below shows the boiling points of a number of alcohols:
Alcohol Boiling Point (°C)
Methanol 65
Ethanol 78
Propan-1-ol 97
Butan-1-ol 117
What is the cause of the trend observed in the boiling points?
a) Increasing chain length results in stronger dispersion forces
b) Increasing chain length results in stronger hydrogen bonding
c) Hydrogen bonding between hydroxyl groups is stronger in larger molecules
d) Hydrogen bonding between hydroxyl groups is stronger in smaller molecules

A

A - Only change between molecules is increasing
length of carbon chain = increase dispersion
forces

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

25.00 mL of 0.02 M potassium hydroxide solution in a conical flask is neutralized by the gradual addition of 33.20 mL of nitric acid.
What is the concentration of the nitric acid?
A. 0.015 mol L-1
B. 0.0265 mol L-1
C. 5 x 10-4 mol L-1
D. 1.66 x 10-5 mol L-1

A

A
KOH(aq) + HNO3(aq) —- KNO3 (aq) + H2O(l)
n(KOH)= 0.02M x 0.025L = 0.0005 = n(HNO3)
c(HNO3) = n /v = 0.0005 / 0.03320 = 0.015M

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q
What is the concentration of H3O+ in a solution with a pH of 2.38?
A. 0.38 mol L-1 
B. 11.62 mol L-1 
C. 4.17 x 10-3 mol L-1 
D. 2.40 x 10-12 mol L-1
A

C
[H+] = 10-2.38
[H+] = 4.17 x 10-3

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Consider the following reaction pathway:
Primary alcohol  Oxidation  Compound A  Oxidation  Compound B
Which combination correctly identified Compound A and Compound B?
Compound A Compound B
a) Aldehyde Ketone
b) Ketone Aldehyde
c) Aldehyde Carboxylic Acid
d) Ketone Carboxylic Acid

A

C - Primary Alcohols oxides first to a aldehyde then to a carboxylic acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

A student analysed the sodium chloride present in a 40.0 g sample of noodle soup. The
chloride ion was precipitated by adding an excess of silver nitrate solution. The silver
chloride was extracted, washed and dried. The mass of silver chloride was 0.752 g.
What percentage of sodium chloride was present in the soup?
A) 0.217%
B) 0.465%
C) 0.767%
D) 1.89%

A

C
Mass silver chloride = 0.752g
n(AgCl) = m/MM = 0.752g / 143.32gmol-1 =
0.00525mol
n(AgCl) = n(Cl-) = n(NaCl)= 0.00525mol
m(NaCl) = n x MM = 0.00525 x 58.443 =0.307g
%(NaCl) = (0.307/40.0g) x 100 = 0.767%

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Native Australian fruits vary from sweet to sour taste. Fruits like Davidson plum and quandong
have a sour or tart taste. This sour taste is attributed to:
a) Sugars like fructose, glucose and sucrose
b) Sugars like fructose, ascorbic acid and sucrose
c) Acids like citric acid, glucose and sucrose
d) Acids like citric acid, tartaric acid and ascorbic acid

A

D - Acids like citric acid, tartaric acid and

ascorbic acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Which product would form if water and dilute phosphoric acid where added to pent-1-ene?

a) Pentane
b) Pentan-1-ol
c) 1-Chloropentane
d) Glucose

A

B - Hydration of an alkene produces an alcohol in

acidic environments.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly