NACE Chp 3 Coatings Flashcards

(58 cards)

1
Q

What is the definition of a “coating?

A

A film forming material that protects the surface it’s applied to from the effects of the environment

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2
Q

What are the 2 classifications of coatings

A

Organic(made from living things) and Inorganic(uses an inorganic binder)

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3
Q

Give 2 examples of ORGANIC coatings

A

tung, oil, castor oil, linseed oil, fish. All contain CARBON

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4
Q

Give 2 examples of INORGANIC coatings

A

SILICATES: sodium silicate, calcium silicate, lithium silicate, ethyl silicate(organic)

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5
Q

What are the 2 components of coating?

A

Pigment and Vehicle

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6
Q

What are 2 qualities of pigment

A
  1. pigment is a discrete particulate solid used for protection and decoration
  2. they do not dissolve, they remain in particles
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7
Q

What else does pigment describe?

A

Pigment can also describe inert fillers like chalk, talc, mica added for bulk

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8
Q

What part of the coating is the vehicle?

A

Vehicle is the liquid base of the coating.

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9
Q

What 3 things does vehicle consist of?

A
  1. Solvent
  2. Binder (resin i.e the film-forming portion)most coatings are named after the resin binder
  3. Liquid additives
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10
Q

What 2 components make up the dried coating film?

A

The binder and pigment

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11
Q

What are the 5 functions of pigments? (In total there are 6 main functions and 6 other functions)

A
1.it’s rust inhibiting
2 makes film less permeable
3 hides the surface	
4  color
5  protects from UV rays and weather
6  reinforces the film
7  self-cleaning and controlled chalking
8  helps with coat binder drying
9    Helps with paint storage
10  increases body so thicker films can be applied
11  allows sacrificial protection
12 provides finishes…metallic or glosses
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12
Q

What are the 3 different pigment shapes and what is each used for?

A
  1. Nodular- LUMP SHAPED-generally adds COLOR or are SACRIFICIAL
  2. Acicular- NEEDLE-SHAPED- e.g. zinc oxide- adds COLOR and REINFORCES
  3. Lamellar- PLATELIKE-e.g. mica, glass flake-makes MORE IMPERMEABLE to moisture
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13
Q

What does vehicle consist of?

A
  1. Solvents
  2. Binders (resins)
  3. Additives
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14
Q

What are the 2 component groups of vehicle?

A
  1. Nonvolatile, film-forming (binder)

2. Volatile solvents

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15
Q

How are coating materials generally named? Give 2 examples

A

Coating materials are generally named for their PRINCIPAL RESIN
Examples epoxy, vinyl etc.

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16
Q

What do most resins require to aid in their application?

A

Solvent

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17
Q

What must binders convert from and into to create a protective coating?

A

The binder resins must convert from PLIANT LIQUID FORM to COHESIVE SOLID FORM

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18
Q

What properties should a binder have to be a suitable corrosion resistant coating?
(there are 6 in total)

A

1 Have good WETTING and ADHESION properties
2 resist water and oxygen transmission
3 Tolerate different application processes
4 Resist chemical and physical change
5 dry in reasonable time to avoid any contamination
6 form a stable film but still be flexible and strong

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19
Q

What is seen as the most critical choice in coating selection?

A

Choice of BINDER

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20
Q

What are the 3 classifications of solvents and their properties

A
  1. Primary (active): dissolves the resin that allows its use as a coating vehicle
  2. Latent: used with the primary solvent to:
  3. make the coating easier to apply
  4. control the evaporation rate
  5. improve quality of the final film.
  6. Diluent: e.g.water used with active solvents to dilute the coating in the container. Diluents DO NOT dissolve the resin.
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21
Q

What are the 2 characteristics of solvents?

A
  1. Solvency power: the ability to dissolve other chemical compounds (e.g. resins)
  2. Volatility: largely governs the evaporation rate
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22
Q

In reducing the coating for application, what is the ONLY solvent that should be used?

A

ONLY the SOLVENT SPECIFIED in the coating specificatrion

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23
Q

Name 5 things that EVAPORATION RATE influences

A
  1. leveling
  2. flowing
  3. sagging
  4. wet-edge time
  5. gloss
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24
Q

Evaporation rates are usually expressed relative to what?

A

the n-butyl acetate, which has a flsh point of 38 degrees and is assigned a value of one.

25
What are the 7 different solvent types
1. Aliphatic Hydrocarbon Solvents 2. Aromatic Hydrocarbon Solvents 3. Ketone Solvents 4. Ester Solvents 5. Alcohol Solvents 6. Ether/Glycol Ethers 7. Miscellaneous Solvents
26
Paraffin is what kind of hydrocarbon solvent is it an open or closed chain?
Aliphatic solvents and they are OPEN chain or straight chain
27
Give 2 other examples of aliphatic hydrocarbon solvents?
1. mineral spirits | 2. V.M. and P (Varnish Makers and Painters) naphtha
28
What kind of boiling point does mineral spiriits have?
It has a HIGH boiling point and is used to dissolve oils, asphalts and alkyds
29
Benzol is an example of what kind of hydrocarbon solvent? Are they open or closed chain
Aromatic, they are CLOSED chain hydrocarbons
30
What is the six carbon ring called?
The benzene-ring structure.
31
What is the simplest chemical in this aromatic family of hydrocarbons?
Benzene; the family also includes TOLUENE, XYLENE, and some higher boiling point HOMOLOGS.
32
What solvents are oxygenated hydrocarbons of the acetone family?
Ketone solvents
33
Ketone solvents are the most effective for what materials
Vinyls. They are also often used in epoxies
34
a)What solvents have a banana-like odor? b) What kind of resins are they good solvents for?
a) Ester solvents. | b) Synthetic resins
35
What is the trade name of the best slow-evaporating solvent for thermoplastic acrylics?
Cellosolve
36
a) What solvents are good for highly polar binders such as phenolics? b) Give 2 examples of these solvents
a) Alcohol solvents | b) Methyl alcohol, ethyl alcohol, propyl alcohol, butyl alcohol or isopropyl alcohol
37
Why are ether solvents not usually used for synthetic resins?
They are very flammable
38
Cellosolve is used in many lacquers to improve what two things?
Flow out and gloss
39
Tetra hydrafuran is what kind of ether?
It is a cyclic ether with strong solvent characteristics for resinous materials e.g.rubbers, epoxies and acrylates
40
What is solution kick out?
The point at which the resin precipitates when a solvent is added to it in increasing amounts. Also known as the DILUTION LIMIT
41
What is the dilution limit an indication of?
The degree to which the resin and solvent are COMPATIBLE
42
What does VOC stand for?
Volatoile Organic Compounds
43
To make the calculation of the maximum allowable thinning that is VOC compliant, and inspector muct know what 4 things?
1. Allowable VOC level 2. VOC of activated/mixed coating 3. VOC of thinner 4. to calculate in ounces per gallon
44
SOLVENT SAFETY | What 2 kinds of hazards is solvent safety concerned with?
Fire and health
45
How is the flash point of a solvent defined?
AS the lowest temperature at which enough vapor will be present above the liquid to be IGNITED by an ignition source such as a flame.
46
The lower the flash has what effect on the vapor released and the risk of vapor ignition?
The GREATER the amount of vapor which will be released and the GREATER the risk of vapor ignition
47
The lower the flashpoint of a solvent makes that solvent more or less flammable?
The lower the flashpoint the MORE HIGHLY FLAMMABLE that solvent is
48
What is th lower explosive limit (LEL)?
It is the lowest concentration of solvent vapor in air that can be ignited
49
What is the upper explosive level (UEL)
It is the HIGHEST concentration of solvent in air that can be ignited.
50
What is the name of the Safety organization that deals with solvents?
The National Institute of Occupational Safety and Health (NIOSH)
51
What 2 things do they recommend inspectors use at all time when dealing with solvents?
Breathing apparatus and protectiv clothing
52
What does TLV stand for and what does it mean?
Threshold limit value: a concentration of airborne can be inhaled for a period of time by workers according to OSHA
53
What does TWA/TLV stand for and what does it mean?
Time weighted average/threshold limit value: time weighted average concentration for a stated work period e.g. 8 hour day or 40 hour week.
54
What does STEL/TLV stand for and what does it mean?
Short-term exposure limit/threshold limit value: The maximum concentration to which workers can be exposed regardless of the period of time.
55
What regulations should solvent storage follow?
Local and federal regulations
56
An inspector should notify the safety supervisor immediately if they have doubts about what 3 things?
1. Any on-site solvent or coating handling practice 2. Protective clothing 3. Breathing apparatus
57
ADDITIVES: | What are 8 reasons additives are added to coatings?
1. Adjust consistency 2. Improve film build 3. Make conductive (for use on concrete) 4. Reduce settling 5. Improve flexibility 6. Retard mildew 7. Provide anti-static properties to coating 8. Provide abrasion and skid resistance
58
Additives are part of what portion of the coating?
The vehicle portion of the coating