Nov 2019 Flashcards
(38 cards)
Are reversible processes frictionless? Why?
A. because the processes are driven by forces which imbalance is differential in magnitude;
B. because when reversed, retraces its forward path and restores the initial state of the system and surroundings.
C. none of these
D. because only infinitesimal changes occur;
because when reversed, retraces its forward path and restores the initial state of the system and surroundings.
If radon -222 disintegrates to a stable condition by emitting three alpha emission and two beta emission, determine the stable nucleus formed.a. 222Rn86b. 192Ir77c. 137Cs55d. 210Pb82
If radon -222 disintegrates to a stable condition by emitting three alpha emission and two beta emission, determine the stable nucleus formed.
a. 222Rn86
b. 192Ir77
c. 137Cs55
d. 210Pb82
210Pb82
The person’s senses of smell and taste depend on specific biochemic receptors present in a person’s nose and mouth. In 2004, a Nobel prize was given to the researchers who established this fact and identified the type of organic compound associated with the sense of smell and taste. The chemical identified was;
A. an alcohol
B. rhodopsin
C. an ester
D. an isomer
rhodopsin
Define gluconeogenesis?
A. Positive ions are smaller and negative ions are smaller than their corresponding atoms.
B. Positive ions are larger and negative ions are larger than their corresponding atoms.
C. Positive ions are smaller and negative ions are larger than their corresponding atoms.
D. Positive ions are larger and negative ions are smaller than their corresponding atoms.
Positive ions are smaller and negative ions are larger than their corresponding atoms.
When a thorium-230 atom undergoes alpha decay, the products of the reaction are usually;
A. Radium and an alpha particle
B. Actinium and an alpha particle
C. Actinium and a positron
D. Radium and a positron
Radium and an alpha particle
In the study of fats and lipids, determine which of the two triglycerides has a higher melting point? Substance A- containing only lauric acid and glycerol, or substance B- containing only stearic acid and glycerol?
A. Both have the same melting points
B. B
C. A
D. None of these
stearic acid and glycerol
Determine the number of neutrons of the radioactive isotope C14.
A. 14
B. 6
C. 8
D. 12
8
In the collision theory of chemical kinetics, it is suggested that reaction rate is governed by the relationship rate= Pz exp (Ea/Rt). What can an enzyme do to the activation energy of the reaction -Ea?
A. Enzymes can raise temperature to make the reaction proceed faster.
B. None of these.
C. Enzymes bind the reactants in close proximity for a longer period in order to get the reaction energy going.
D. Enzymes provide an alternative reaction pathway in lowering or increasing the energy level of the reaction.
Enzymes provide an alternative reaction pathway in lowering or increasing the energy level of the reaction.
A chemical reaction may occur;
A. When atoms of two elements undergo a loss in electrons for one element or a gain in electrons for the other;
B. When a nonmetal element steals electrons from another nonmetal element in order to achieve a stable configuration;
C. None of these
D. When covalent bonds in two elements are transformed into polar covalent bonding during an oxidation/ reduction process
When atoms of two elements undergo a loss in electrons for one element or a gain in electrons for the other
To which subatomic particle does each statement refer to a) has a positive charge; b) is found outside of the nucleus; c) has the smallest mass; d) has a negative charge
A. electron, electron, proton, proton
B. proton, electron, proton, electron
C. electron, proton, electron, proton
D. proton, electron, electron, proton
proton, electron, proton, electron
What is the significance of colligative property in physical chemistry?
A. It refers to the freezing point, depression, boiling point elevation, osmotic pressure and lowering of the vapor pressure by a nonvolatile solute;
B. It refers to the temperature, pressure and energy of fusion of volatile solutes in phase equilibrium;
C. It refers to the non existence of pressure among molecules within the solute;
D. It refers to the temperature differentials exhibited by non volatile solutes in reactions
It refers to the freezing point, depression, boiling point elevation, osmotic pressure and lowering of the vapor pressure by a nonvolatile solute
Define a salt in terms of acid and bases.
A. A salt is a compound that follows le chatelier’s principle in reactions with other compounds.
B. all of these
C. A salt is a compound formed when the nucleus of a hydrogen atom enters a quantity of water.
D. A salt is a compound other than water) produced by the reaction of an acid and a base
A salt is a compound other than water) produced by the reaction of an acid and a base
In order to describe the intensive state of a system at equilibrium, specify the degrees of freedom for a one-phase, two phase system and three phase system:
A. F=2; F=l; and F=0
B. F=1; F=2; and F=3
C. F=0; F=1; and F=2
D. F=3; F=2; and F=1
F=2; F=l; and F=0
Applying the Octet Rule, determine how many electrons each must each atom gain or lose to acquire an electron configuration identical to the noble gas nearest to it in atomic number; Sr, S and Si;
A. krypton; argon; argon and neon;
B. neon; argon and krypton; krypton;
C. none of these
D. argon; krypton; krypton and argon;
krypton; argon; argon and neon
If a labeled fatty acid with radioactive Carbon -14 is fed to an experimental animal, in what type of compounds contained in the breath of the animal would the radioactive material appear?
A. as nitrogen
B. as CO2
C. as water vapor
D. as hydrogen
(numerade answer)
as CO2
What is the “buckyball”?
A. An epoxy resin
B. C60H+++
C. A fullerene
D. Sodium benzoate
fullerene
Determine whether the following statements are TRUE (T) or FALSE (F)
about constitutional isomers:
a. They have the same molecular formula
b. They have the same physical properties
c. They have the same molecular weight
d. They have the connectivity of their atoms
A. T, F, T, F
B. F, T, F, T
C. T, F, F, T
D. F, F, T, T
T, F, T, F
The element neon was discovered in 1898 by;
A. Marks and Howell
B. Travers and Ramsey
C. Davy and Russel
D. Pontin and Berzelius
Travers and Ramsey
A gaseous system contains CO, CO2, H2, H2O and C6H6 in chemical equilibrium. Determine how many components here are, how many independent reactions and number of degrees of freedom?
A. 1;2;4
B. none of these
C. 2;3; 6
D. 3;2;4
(chatgpt answer)
3;2;4
Applying the Gibbs phase rule in the degrees of freedom, determine the number of degrees of freedom of a: liquid water in equilibrium with its vapour; b: liquid water in equilibrium with a mixture of water vapor and nitrogen; c: a liquid solution of alcohol in water in equilibrium with
its vapor.
A. F=1; F=4; F=3
B. F=2;F=3;F=3
C. F=1;F=2; F=2
D. F=2;F=3;F=2
F=1;F=2; F=2
What is the Clapeyron Equation?
A. Any of these
B. It postulates that the colligative properties, freezing point depression, boiling point, elevation, osmotic pressure and vapor pressures are all dependent on the number in a solution and any change thereof is described
C. It postulates that if two components systems consisting of solid and liquid phases are miscible in the liquid state and immiscible in the oslid state, only the pure solid systems will separate cut on cooling solutions.
D. It postulates that if the temperature and pressure are both given by the equation.
It postulates that if the temperature and pressure are both given by the equation.
Biochemical compounds are either hydrophilic, hydrophobic or ampiphatic.
Classify the following compounds; glucose, stearic acid, soaps, fatty acids.
A. Ampiphatic, ampihatic, hydrophobic, hydrophobic
B. Hydrophilic, hydrophobic, ampiphatic, hydrophobic
c: Hydrophilit, amp-pratic, ampiphatic, hydrophobic
D. Hydrophobic, hydrophilic, hydrophobic, ampiphatic
Hydrophilic, hydrophobic, ampiphatic, hydrophobic
In the collision theory of chemical kinetics, It is suggested that reaction rate is governed by the relationship rate = PZ exp (Ea/RT). What can an enzyme do to the activation energy of the reaction - Ea?
A. Enzymes can raise temperature to make the reaction proceed faster.
B. Enzymes provide an alternative reaction pathway in lowering or increasing the energy level of the reaction.
C. None of these
D. Enzymes bind the reactants in close proximity for a longer period in order to get the reaction energy going.
(chatgpt answer)
Enzymes provide an alternative reaction pathway in lowering or increasing the energy level of the reaction.
These compounds are formed by the reaction of acids with alcohols.
A. Ethers
B. Esters
C. Bases
D. Enzymes
Esters