ochem exam 1 Flashcards

(23 cards)

1
Q

alkene to alkane hydrogenation (syn)

A
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2
Q

aromatic NO2 to aromatic NH2

A
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3
Q

1° halogen to nitrile

A
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4
Q

1° halogen to azide

A
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5
Q

1° nitrile hydrogenation to amide

A
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6
Q

1°azide hydrogenation to amine

A
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7
Q

alkenes to diol (cis)

A
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8
Q

cleaves diols into 2 aldehydes

A
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9
Q

alkene to diol to 2 aldehydes

A
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10
Q

ozonolysis: oxidation (2 carboxylic acids)

A
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11
Q

ozonolysis: reduction (aldehydes)

A
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12
Q

epoxidation of alkene

A
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13
Q

1° alcohol to aldehyde & 2° alcohol to ketone

A

PCC (CrO3Cl), DMP

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14
Q

1° alcohol to carboxylic acid

A
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15
Q

aldehyde to 1° alcohol or ketone to 2° alcohol

A
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16
Q

allylic and benzylic bromination via radical

17
Q

radical initiation mechanism

18
Q

radical initiation

19
Q

radical initiation

20
Q

radical termination (with AIBN)

21
Q

allylic bromination

22
Q

benzylic bromination›

23
Q

anti-markovnikov bromination