Organic 1 - 4.5 Flashcards

(33 cards)

1
Q

What is crude oil made up of?

A

Crude oil is a mixture of hydrocarbons

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2
Q

What makes up a hydrocarbon?

A

a hydrocarbon compound is made up of hydrogen and carbon ONLY

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3
Q

What happens as the fractions boiling point increases?

A
  • the fractions get darker in colour
  • the fractions get more viscous
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4
Q

What are the important fractions?

A

Refinery gases
Gasoline
Kerosene
Diesel
Fuel oil
Bitumen

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5
Q

What is the use of refinery gases?

A

FUEL for home cooking

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6
Q

What is the use of gasoline?

A

FUEL for cars

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7
Q

What is the use of kerosene?

A

FUEL for aircraft

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8
Q

What is the use of diesel?

A

FUEL for trains

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9
Q

What is the use of fuel oil?

A

FUEL for ships

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10
Q

What is the use of bitumen?

A

making road

NOT FUEL

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11
Q

What happens during fractional distillation?

A

Each of the fractions is separated from crude oil by fractional distillation.
The fractional distillation of crude oil is done industrially on a large scale.
The fractionating column is hotter at the bottom and colder at the top.

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12
Q

How does fractional distillation work?

A
  1. Crude oil is heated/vapourised
  2. The vapour passes into/rises up the fractioning column
  3. Different vapours condense at different heights due to their different boiling points
  4. Similar vapours condense together as a fraction.
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13
Q

What is the general formula for alkanes?

A

CnH2n+2

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14
Q

What is meant by the term homologous series?

A

A family of molecules which have:
similar chemical reactions
trends in physical properties
the same general formula

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15
Q

What is meant by the term isomerism?

A

Isomers are molecules with the same molecular formula but different structural formulae

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16
Q

What are the products of complete combustion of hydrocarbons?

A

carbon dioxide
water

17
Q

What are the products of incomplete combustion of hydrocarbons?

A

Carbon monoxide
Soot - causes lung disease

18
Q

What type of reaction occurs with alkanes when they react with halogens - substitution or addition?

A

substitution - because it will swap
the reaction requires UV light - because the alkane is pretty unreactive

19
Q

Why is carbon monoxide poisonous?

A

a toxic gas that lowers the oxygen carrying capacity of blood

20
Q

What pollutants does the combustion of alkanes as fuels release in the atmosphere?

A

Carbon dioxide - forms directly from the combustion of the alkane fuel.
It is a greenhouse gas that traps heat in the atmosphere and causes climate change

Nitrogen oxides - form when nitrogen from the air combusts.
Usually nitrogen doesn’t combust but car engines are really, really hot.
They dissolve in rainwater to form acid rain, which corrodes structures and is harmful
to plant and aquatic life.

Sulphur dioxide - This forms when sulphur impurities in the fuel combust.
Like nitrogen oxides, it also dissolves in rainwater to form acid rain.

21
Q

Why are alkanes classified as saturated carbons?

A

because they do NOT have a double carbon bond

22
Q

What is the general formula for alkenes?

23
Q

Why are alkenes classified as unsaturated hydrocarbons?

A

They DO contain a double carbon bond

24
Q

What happens when alkenes react with bromine?

A

break the double carbon bond and add the bromine atoms in
addition reaction
works with pure bromine liquid or bromine water
mixture turns ORANGE to COLOURLESS - because the bromine is used up in the reaction

this reaction is used as a test for the double carbon bond in unsaturated compounds

25
What is an addition polymer?
an addition polymer forms when molecules with a double carbon bond add into chains
26
What are the problems with the disposal of addition polymers?
Addition polymers are inert, which means they’re chemically very unreactive. This means they don’t break down very easily take up a lot of space
27
What are the only options for disposal of an unwanted addition polymer?
Reuse it, or give it to someone else who will use it Recycle it, which allows it to be reshaped for another use. Incinerate it, and use the energy released to generate electricity. Chuck it onto landfill, and hope it goes away
28
Explain why cracking is a useful process in the oil industry
shorter chains are more useful cracking produces short chain alkanes short alkanes can be used as fuels alkenes can be used to make polymers
29
What is the description of a monomer?
a molecule used to make a polymer
30
What is meant by the term biodigrade?
breaks down by bacteria/microorganisms
31
What property of polymers prevents them from biodegrading?
inert / unreactive
32
What is meant by the term polymer?
a long chain formed when monomers join together
33
State the changes that occur in the formation of an addition polymer from its monomer.
double carbon bond becomes a single carbon bond increases in mass monomers join together to form a long chain