Organic chem Flashcards

(24 cards)

1
Q

How do you go from primary alcohol to Aldehyde(=O at end)?

A

K₂Cr₂O₇ oxidises it - distillation

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2
Q

How do you go from 1y alcohol to carboxylic acid?

A

K₂Cr₂O₇ oxidises it - reflux

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3
Q

How do you go from aldehyde to 1y alcohol?

A

NaBH4/LiAlH4/ether - reduces it

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4
Q

How do you go from 2y alcohol to keytone(mid=O)?

A

K2Cr2O7/H2SO4 - oxidises it

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5
Q

How do you go from ketone to 2y alcohol?

A

NaBH4/LiAlH4 - reduces it

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6
Q

How do you go from alcohol to halagenoalkane?

A

KBr+H₂SO₄ -OR- PCl₅/HCl

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7
Q

How do you go from halogenoalkane to alcohol?

A

Warm KOH reflux

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8
Q

How do you go from alcohol to ester?

A

carboxylic acid/conc. H2SO4 + heat

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9
Q

How do you go from ester to alcohol?

A

Dilute acid(HCl)/Alkaline(NaOH)- Reflux

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10
Q

How do you go from ester to carboxylic acid?

A

Dilute acid(HCl)/Alkaline(NaOH)- Reflux

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11
Q

How do you go from carboxylic acid to ester?

A

Alcohol + acid (H₂SO₄)

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12
Q

How do you go from Alcohol to Alkene?

A

H₃PO₄ + Heat

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13
Q

How do you go from Alkene to Alcohol? It’s this one

A

H20(steam) + H₃PO₄

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14
Q

How do you go from Alkene to Alkane? Sheldon cooper

A

H2 + Nickle

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15
Q

How to go form Alkene to Halogenoalkane?

A

+hydrogen halide (HBr,HCl,HI)
(electrophilic addition)

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16
Q

How to go from Halogenoalkane to Alkene?

A

+ KOH and Ethanol
- Heat reflux

17
Q

How to go form Alkane to Halogenoalkane?

A

Halogen(Cl2/Br2) + UV
Free radical sub

18
Q

How to go from Alkene to Diol?

A

acidified KMnO₄

19
Q

How to go from carboxylic acid to Acyl chloride? Not the cl u think

A

PCl5 room temp

20
Q

How to go from Acyl Chloride to carboxylic acid?

21
Q

How to go from Acyl Chloride to Amide?

A

NH3 Nucleophilic sub

22
Q

How to go from halogenoalkane to Amine? A bit more

A

Excess ethanolic ammonia

23
Q

How to go from halogenoalkane to nitrile?

A

KCN + Ethanol Heat reflux

24
Q

How to go from nitrile to carboxylic acid?