ORGANIC CHEM:Molecule types Flashcards

(32 cards)

1
Q

What are alkanes

A

single covalent bonds between carbon atoms
fully saturated
sp3 hybridized

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2
Q

Formula for noncyclic alkanes

A

C(n)H(2n+2)

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3
Q

1-10 prefixes for carbon atoms

A
meth-
eth- 
prop-
but-
pent-
hex-
hept- 
oct-
non-
dec-
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4
Q

Isomers?

A

2+ molecules with the same formula but different shapes

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5
Q

Naming alkanes

A

prefix-base-family

Ex) 2,4-dimethylhexane

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6
Q

For ringed structures:

A

cyclo-(base)ane

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7
Q

Alkane reactivity

A

used as non-polar solvents

fuel b/c combustion reactions are exothermic

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8
Q

What are alkenes?

A

unsaturated hydrocarbons that contain C&H atoms and at least one c-c double bond
(fewer than max H’s)
C on double bond is Sp2 hybridized

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9
Q

Can alkenes rotate freely around the double bond?

A

No

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10
Q

Naming alkenes

A

same as alkanes but with -ene

and a prefix before family to indicate location of double bond

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11
Q

Why is structure important

A

determines physical properties

IE boiling points

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12
Q

Cis vs trans

A

Cis-same side

trans- opposite sides

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13
Q

What are alkynes?

A

unsaturated hydrocarbons that contain at least one c-c triple bond
Carbons on triple bond are Sp hybridized and linear

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14
Q

Naming of alkynes?

A

same as alkenes but with -yne

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15
Q

what are Aromatic hydrocarbons

A

highly unsaturated but unreactive

NO ADDITION REACTIONS

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16
Q

why are aromatic hydrocarbons unreactive?

A

delocalized pi electrons confer special stability

17
Q

common names for aromatic hydrocarbons?

A

benzene, naphthalene (2 Benz), anthracene (3 benz),

18
Q

possible isomers for aromatic hydrocarbons?

A

Ortho- substituents adjacent
para- substituents opposite
meta- I carbon in-between substantiates

19
Q

What is an alcohol?

A

an oxygen inserted between H &O

20
Q

To name alcohols

A

ending in -ol

number to indicate where O is attached

21
Q

what is an Ether?

A

oxygen atom between 2 carbon atoms

22
Q

to name ethers?

A

the 2 carbon groups on either side of O are subsitents followed by ether.
H3C-CH2-O-CH2-CH3
Ex) diethyl ether

23
Q

Reactivity of ethers

A

relatively unreactive

used as solvents

24
Q

What do aldehydes, ketones, carboxylic acids and esters have in common?

A

carbonyl group C=O

the 2 other substientunts determine family of compound

25
What is a aldehyde?
when the carbonyl group has at least one hydrogen atom -CHO named with -al
26
What is a ketone?
When both groups on the carbonyl group are carbon -CO- named with-one
27
what are carboxylic acids?
carbonyl group with an -OH attached suffix -oic acid -COOH
28
What are esters?
prepared by condensation reaction between carboxylic acid and alcohol- product being ester and water R-COOR'
29
What does R and R' stand for
substituents
30
To name esters?
1) name of alcohol | 2) then acid
31
What are amines?
organic bases with general formula R3N (where R=H of hydrocarbon group) suffix amine
32
what are Amides?
contain a combination of carbonyl and amine suffix: amide Produced through condensation reaction between carboxylic acids and amines