Organic Chemistry Flashcards
(31 cards)
What do isomers have in common?
They have the same molecular formula but different arrangements.
What are the two types of isomers?
Structural isomers and stereoisomers.
How many types of structural isomers are there?
Three types: position, functional, and chain.
What are stereoisomers?
Isomers that differ in the spatial arrangement of atoms.
What is a chiral carbon?
A carbon atom bonded to four different groups.
What types of isomers include cis and trans isomers?
Stereoisomers.
What is the shape of an s orbital?
Spherical
How many types of hybridized orbitals are there?
sp2 and sp3 hybridized orbitals
What forms a sigma bond?
sp3 hybridized orbitals
What forms a pi bond?
The vacant electron left in the p orbital of sp2 hybridized orbitals
What is the characteristic of C-C single bonds?
They have sigma bonds only
How many bonds do C=C double bonds have?
1 sigma bond and 1 pi bond
How many bonds do C≡C triple bonds have?
1 sigma bond and 2 pi bonds
Which type of bonds are formed by sp3 and sp2 hybridized orbitals respectively?
Sigma and pi bonds
Fill in the blank: The unhybridized p orbital of a pi bond is involved in ______.
resonance
True or False: Sigma bonds can exist without pi bonds.
True
What does the presence of pi bonds indicate about the bond type?
Double or triple bonds
What type of reaction is butene with hydrobromic acid?
Electrophilic addition
Electrophilic addition involves the reaction of an electrophile (like HBr) with a nucleophile (like butene).
What are Qcds classified as in chemical reactions?
Electrophiles
Electrophiles are species that accept electrons in a chemical reaction.
What are bases classified as in chemical reactions?
Nucleophiles
Nucleophiles are species that donate electrons in a chemical reaction.
What is the role of NaBH4 in chemical reactions?
It acts as a reducing agent
Sodium borohydride (NaBH4) is commonly used to reduce carbonyl compounds.
What type of addition does cyclopentanone undergo with sodium borohydride?
Nucleophilic addition
Nucleophilic addition occurs when a nucleophile attacks a carbon atom in a carbonyl compound.
Fill in the blank: NaBH4 is a _______ and bases are _______.
[reducing agent], [nucleophiles]
What is the outcome of the addition of water to an alkene?
Hydration reaction
Hydration reactions typically lead to the formation of alcohols from alkenes.