Organic Chemistry Flashcards

(31 cards)

1
Q

What do isomers have in common?

A

They have the same molecular formula but different arrangements.

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2
Q

What are the two types of isomers?

A

Structural isomers and stereoisomers.

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3
Q

How many types of structural isomers are there?

A

Three types: position, functional, and chain.

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4
Q

What are stereoisomers?

A

Isomers that differ in the spatial arrangement of atoms.

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5
Q

What is a chiral carbon?

A

A carbon atom bonded to four different groups.

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6
Q

What types of isomers include cis and trans isomers?

A

Stereoisomers.

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7
Q

What is the shape of an s orbital?

A

Spherical

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8
Q

How many types of hybridized orbitals are there?

A

sp2 and sp3 hybridized orbitals

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9
Q

What forms a sigma bond?

A

sp3 hybridized orbitals

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10
Q

What forms a pi bond?

A

The vacant electron left in the p orbital of sp2 hybridized orbitals

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11
Q

What is the characteristic of C-C single bonds?

A

They have sigma bonds only

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12
Q

How many bonds do C=C double bonds have?

A

1 sigma bond and 1 pi bond

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13
Q

How many bonds do C≡C triple bonds have?

A

1 sigma bond and 2 pi bonds

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14
Q

Which type of bonds are formed by sp3 and sp2 hybridized orbitals respectively?

A

Sigma and pi bonds

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15
Q

Fill in the blank: The unhybridized p orbital of a pi bond is involved in ______.

A

resonance

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16
Q

True or False: Sigma bonds can exist without pi bonds.

17
Q

What does the presence of pi bonds indicate about the bond type?

A

Double or triple bonds

18
Q

What type of reaction is butene with hydrobromic acid?

A

Electrophilic addition

Electrophilic addition involves the reaction of an electrophile (like HBr) with a nucleophile (like butene).

19
Q

What are Qcds classified as in chemical reactions?

A

Electrophiles

Electrophiles are species that accept electrons in a chemical reaction.

20
Q

What are bases classified as in chemical reactions?

A

Nucleophiles

Nucleophiles are species that donate electrons in a chemical reaction.

21
Q

What is the role of NaBH4 in chemical reactions?

A

It acts as a reducing agent

Sodium borohydride (NaBH4) is commonly used to reduce carbonyl compounds.

22
Q

What type of addition does cyclopentanone undergo with sodium borohydride?

A

Nucleophilic addition

Nucleophilic addition occurs when a nucleophile attacks a carbon atom in a carbonyl compound.

23
Q

Fill in the blank: NaBH4 is a _______ and bases are _______.

A

[reducing agent], [nucleophiles]

24
Q

What is the outcome of the addition of water to an alkene?

A

Hydration reaction

Hydration reactions typically lead to the formation of alcohols from alkenes.

25
True or False: Electrophiles donate electrons in a reaction.
False ## Footnote Electrophiles accept electrons, while nucleophiles donate them.
26
What is Mass Spectrometry?
A technique used to identify the composition of a sample by measuring the mass of its ions ## Footnote Mass spectrometry can analyze complex mixtures and identify chemical compounds.
27
How does Mass Spectrometry work?
It ionizes chemical species and sorts the ions based on their mass-to-charge ratio ## Footnote The process typically involves ionization, acceleration, deflection, and detection.
28
What is the significance of infrared absorption in Mass Spectrometry?
It helps in identifying bonds in a molecule ## Footnote Different bonds absorb infrared light at different frequencies, providing structural information.
29
True or False: Mass Spectrometry can only analyze pure substances.
False ## Footnote Mass Spectrometry is particularly useful for analyzing complex mixtures.
30
What is the importance of the mass spectrum?
It provides a visual representation of the mass-to-charge ratios of ions ## Footnote This spectrum helps in determining the composition and structure of the sample.
31
List the main steps in the Mass Spectrometry process.
* Ionization * Acceleration * Deflection * Detection ## Footnote Each step plays a crucial role in analyzing the sample.