Organic Chemistry Flashcards

(62 cards)

1
Q

Crude oil

A
  • formed over millions of years from the fossiles remains of plankton
  • found in porous rocks in earths crust
  • non renewable
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2
Q

Most compounds in crude oil are

A

Hydrocarbons

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3
Q

The larger the hydrocarbon:

A
  • more viscous
  • higher boiling point
  • less volatile
  • less easily it ignites
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4
Q

Crude oil can be separated by

A

Fractional distillation

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5
Q

A fraction is

A

A set of hydrocarbon molecules

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6
Q

The bigger the fraction

A

The bigger the boiling point

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7
Q

Fractional distillation steps

A
  1. Crude oil is heated to make a vapour
  2. Vapour rises up the column
  3. The column is hot at the bottom and cooler at the top
  4. Hydrocarbons condense at different temperatures depending on the boiling point
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8
Q

Alkenes are

A

Unsaturated hydrocarbons

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9
Q

Alkene + hydrogen —>

A

Alkane

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10
Q

The complete combustion of an alkane results in

A

The production of CO2 gas

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11
Q

Alkane are defined as

A

Saturated hydrocarbon

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12
Q

Alkane are

A
  • fairly un reactive

- burn well

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13
Q

What are used to make polymers

A

Alkenes

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14
Q

What’s a monomer

A

Small molecule with a double bond

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15
Q

How to represent polymerisation

A

Text book pg70

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16
Q

In addition polymerisation reactions

A
  • The repeating units and the monomer units contain the same atoms
  • the percentage atom economy is 100%
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17
Q

The properties of a polymer metal depend on

A
  • What it is made from(what monomer)

- The conditions under which it was made(catalyst/ temperature)

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18
Q

What is low density polythene used for

A

Carrier bags

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19
Q

What is high-density Polythene useful

A

Plastic bottles

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20
Q

Condensation polymerisation

A

Monomer molecules joined together To form large polymer molecules and lose small molecules such as water

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21
Q

Meth

A

1

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22
Q

Eth

A

2

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23
Q

Prop

A

3

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24
Q

But

A

4

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25
Pent
5
26
Hex
6
27
Most fuels arevcompounds of
Hydrogen and carbon Many also contain sulfur
28
During the combustion of hydrocarbon fuels
- both carbon and hydrogen are oxidised - energy is released - waste products are released into the atmosphere
29
Carbon monoxide is
Colourless Odourless Toxic gas
30
Cracking is where
Longer- chain hydrocarbon can be broken down into shorter more useful hydrocarbon
31
During thermal cracking
- hydrocarbons heated until thu vaporise - valour passsed over a hat catalyst - thermal decomposition reaction takes place
32
During steam cracking
Hydrocarbons are mixed with steam and heated to a high temperature 500
33
Alkenes have a
Double bond
34
Are alkenes or alkenes more reactive?
Alkenes because if the double carbon bond
35
Alkenes burn with a
Smokey flame
36
Alkene+ hydrogen —>
Alkane
37
Alkene+steam—>
Alcohol
38
Alkene turns bromine water
Colourless
39
Aqueous solution of ethanol can by produced by
Fermentation of sugar
40
During fermentation | Sugar—>
Ethanol+carbon dioxide
41
Temperature during fermentation Why
25-50 Celsius Too low yeast inactive Too high yeast denatured
42
Alcoholic functional group
Hydroxyl -OH
43
Alcohols:
- Dissolve in water to form neutral solutions - React with sodium to produce hydrogen - Burn in air to produce carbon dioxide and water - Are used as fuels and solvents
44
Alcoholic drinks contain
Ethanol
45
Carboxylic acid functional group
Carboxyl | COOH
46
Carboxylic acids:
- Dissolve in water to form acidic solutions - React with carbonates to produce carbon dioxide - React with alcohol to form esters - Do not ionise fully in water so they are called weak acids
47
If combustion is not complete
Then carbon monoxide, unburnt fuels and solid particles containing soot(carbon) may be released
48
Particulates can cause | Solid particulates in the air
Global dimming by reducing the amount of sunlight reaching the earths surface and cause damage to people’s lung
49
Due to the high temperatures reached when fuels burn
Nitrogen in the air can react with oxygen to form nitrogen oxides These gases can cause respiratory problems and can react with rain water to form acid rain
50
Alkane Turns bromine water
Orange brown solution
51
Ethene reacted with bromine forms
Dibromoethane
52
Ethanol can be produced by
Fermentation of sugar
53
Sugar—>
Ethanol + carbon dioxide
54
The main acid and vinegar
Ethanoic acid
55
Ethanol can be oxidised to ethanoic acid by
chemical oxidising agents or bacteria from the air
56
Esters form from
Alcohol and carboxylic acids
57
Esters fictional group
COO
58
Ethanol + ethanoic acid
Ethyl ethanoate Ester
59
Esters are
Volatile compounds Low boiling point Distinctive smells perfumes
60
Amino acids functional groups
Amine group NH2 Carboxyl group COOH
61
DNA
Two polymer chains constructed from four different nucleotides Cytosine Guanine Adenine Thymine
62
Starch and cellulose
Polymers of sugar Made by plants Starch sugar and cellulose are all carbohydrates