organic chemistry part 1 Flashcards

remember (51 cards)

1
Q

alkane formula and suffix

A

CnH2n+2
example:end in ane
propane
methane
hexane
octane

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2
Q

alkene formula and suffix

A
  • CnH2n
  • ene
  • double bond
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3
Q

alkyne formula and suffix

A
  • CNH2n-2
  • yne
    -triple bond
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4
Q

Alkene example explain

A

you remove ane part of alkane then you state where the double bond occurs then u add the prefix of alkene.

For example: But-2-ene

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5
Q

Alkyne example explain

A

you remove ane part of alkane then you state where the triple bond is then you add the prefix of alkyne

For example: Pent-2-yne

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6
Q

halogenoalkanes when to know when to use and how to state and example

A

when you either see F,CL,Br or I off the Carbon.
-you start by saying the number first and on which carbon it is located, then you right which halogen it is but you chop of the ine and and o then u state the alkane

example:2-Chlorobutane

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7
Q

alcohol when to know when to use and how to state and example

A

OH replaces an H and is seen in parenthesis when in formula.
- suffix is ol

when creating the example only remove the E from the alkane then write where the oh is placed then add the suffix ol

example: Butan-2-ol

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8
Q

aldehydes functional group

A

C double bond to O and single bond to H
has to be at end of the chain

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9
Q

aldehyde suffix and how to word

A

-al
- remove the e from the alkane and add al

example: pentanal

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10
Q

ketone functional group

A

similar to aldehyde but the double bond of O is in the middle or not at the end

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11
Q

ketone suffix and how to word

A

one

remove the e from the alkane then state where the O is located then write the suffix

example: pentan-2-one

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12
Q

carboxylic acids functional group

A

C is connect to a double bond of O and a single bond of OH instead of H’s

always at the end of a chain

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13
Q

Carboxylic acid suffix and how to word

A

change the e of the parent alkane to oic

example:pentanoic acid

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14
Q

esters functional group

A

C bonded to a double bond O(replacing the H) and that same C bonded to a single bond O that replaces an original C

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15
Q

Esters suffix and how to write

A

replace the e from the alkane with oate(use the chain attached to the C double bonded to O

place the name of the alkyl group in the front(use the chain attached to the single bonded O)

example: ethyl Propanoate

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16
Q

Ethers

A

O is separating the carbon atoms

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17
Q

naming symmetrical ethers

A

doesnt matter which side name alkyl group and add oxy then follow it by name of the alkane that the O is bonded to

example: Ethoxy Ethane

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18
Q

Naming Asymmetrical ethers

A

The shorter chain gets the Oxy ending while the longer chain keeps entire name

example: ethoxy Butane

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19
Q

Unsaturated Carbons

A

Akenes
alkynes

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20
Q

Saturated carbons

A

Alkane

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21
Q

Functional group for ketone?

22
Q

Functional group for Alcohol

A

Hydroxyl group

23
Q

Primary Alcohol?

A

The Carbon holding the OH is bonded directly to one other carbon

24
Q

Secondary Alcohol

A

The Carbon holding the OH is bonded directly to two other carbons

25
Tertiary alcohols
No reaction occurs
26
Combustion of Alkanes
Hydrocarbon(pentane etc) + O2 ---> CO2 + H2O
27
how many products does combustion of alkanes have
2
28
Substitution always has how many products
2
29
Incomplete combustion for alkane
Hydrocarbon + O2 ---> CO + H2O incomplete combustion always forms CO
30
Substitution reaction of alkanes Alkane + Halogen ---->
Alkane + Halogen ----> Halogenalkane + acid example: CH4+ Cl2 -----> CH3Cl + HCL
31
How can Alkanes react with Halogens
UV light
32
Free radical
Atom or molecule that contains an unpaired electron and so is VERY reactive
33
Initiation in Reaction mechanism
Cl bonded to another Cl ---> Cl + Cl not bonded to each-other but with an unpaired electron as the 7th valence electron. These are known as free radical
34
Propagation in Reaction mechanism
When the Chlorine free radicals come into contact with a methane molecule, they combine with a hydrogen atom to produce hydrogen chloride, and a methyl radical The methyl free radical reacts with a chlorine molecule to form a halogenalkane and regenerate another chlorine radical
35
Termination in reaction mechanism
Thus occurs when 3 radicals react together Cl + Cl= Cl2 CH3+ CH3= ethane
36
Alkene+ Halogen(diatomic) ----> forms what
Alkene+ Halogen(diatomic) ----> Dihalogenalkanes ex: Prop-1-ene + bromine ---> 1,2dibromopropane
37
Hydrogen halides
Halogens(Br,F,I,Cl when they combine with hydrogen
38
Addition of Hydrogen halides (Alkene+ hydrogen halide ---->)
Alkene+ hydrogen halide ----> halogenoalkane
39
addition has how many products
1
40
Addition of hydrogen
When you see a alkene or alkyne + H2 Alkene+ hydrogen ---> alkane Alkyne + hydrogen ---> alkene
41
Addition of water Alkene + H2O ---> forms what
Alkene + H2O ---> Alcohol Example: ethene + water ----> ethan- 1 - ol
42
repeating unit
A group of atoms that appears repeatedly along a polymer chain
43
properties of polymers
- High melting and boiling points - low thermal and electrical conductivity.
44
Addition Polymerization
Monomer ---> Polymer -monomers with double bonds combine together to form polymers
45
Nucleophilic Substitution of Halogenoalkanes (halogenoalkane + hydroxide ---> what does this form, and example
----> alcohol + salt ex: Chloromethane + sodium hydroixde ---> COH(hydrogen bonds attach to C) + nacl
46
Combustion of Alcohols
Alcohol + O2 ---> CO2 + H2O ex: C2H5OH + O2 ---> CO2 + H2O
47
Oxidation with primary Alcohols
Primary alc --> aldehyde ---> carboxylic acid
48
Oxidation with secondary Alcohols
Secondary alc ---> ketone
49
Homologous series
Same general formula or functional group differs from one another by one CH2
50
how does bp go with carbon atoms
the more Carbon atoms the higher bp the less carbon atoms the lower the Bp
51
Isomers
same molecular formula but different structural formulas.