Organic Conditions Flashcards

(35 cards)

1
Q

What are the reagent for:

Nitrile to Amine

A

LiAlH4 or H2/Ni

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2
Q

What is the type of reaction for:

Nitrile to Amine

A

Reduction

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3
Q

What are the reagents and conditions for:

Haloalkane to Alkene

A

  • NaOH in ethanol*
  • Heat under reflux*
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4
Q

What are the type of reaction for:

Haloalkane to Alkene

A

Elimination

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5
Q

What are the reagents for:

Haloalkane to Nitrile

A

KCN

alcholic solution/reflux

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6
Q

What is the type of reaction for:

Haloalkane to Nitrile

A

Nucleophilic substitution

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7
Q

What are the conditions for:

Haloalkane to Primary Aimine

A

NH3 (excess)

alcholic solution/reflux

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8
Q

What is the type of reaction for:

Haloalkane to Primary Aimine

A

Nucleophilic substitution

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9
Q

What are the reagents/conditions for:

Ketone to Secondary Alcohol

A

NaBH4

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10
Q

What is the type of reaction for:

Ketone to Secondary Alcohol

A

Nucleophillic addition/Reduction

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11
Q

What are the reagents/conditions for:

Aldehyde to Primary Alcohol

A

NaBH4

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12
Q

What is the type of reaction for:

Aldehyde to Primary Alcohol

A

Nucleophillic addition/Reduction

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13
Q

What are the reagents/conditions reaction for:

Ester to Carboxylic Acid & Alcohol

A

H2O

Dilute H+ Catalyst/Reflux

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14
Q

What is the type of reaction for:

Ester to Carboxylic Acid & Alcohol

A

Hydrolysis

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15
Q

What are the conditions and type of reaction for:

Carboxylic Acid to Ester

A
  • Alcohol/Conc. H2SO4 catayst*
  • Reflux*

Esterification
Nucleophillic
Addition/Elimination

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16
Q

What are the Reagents of reaction for:

Aldehyde to Carboxylic Acid

A

  • H+/K2Cr2O7*
  • or Tollen’s*
  • or Fehlings*
17
Q

What is the type of the reaction:

Aldehyde to Carboxylic Acid

A

Oxidation

(via H+/K2Cr2O7, Tollen’s or Fehlings)

18
Q

What are the reagents of reaction for:

Secondary Alcohol to Ketone

19
Q

What is the type of reaction for:

Secondary Alcohol to Ketone

20
Q

What are the reagents and conditions of reaction for:

Primary Alcohol to Aldehyde

A
  • H+/K2Cr2O7*
  • Distillation*
21
Q

What is the type of reaction for:

Primary Alcohol to Aldehyde

A

Oxidation

(via H+/K2Cr2O7)

22
Q

What are the reagents and conditions of reaction for:

Alcohol to Alkene

A
  • conc. H2SO4*
  • reflux*
23
Q

What is the type of reaction for:

Alcohol to Alkene

24
Q

What are the reagents and conditions of the reaction for:

Haloalkane to Alcohol

A
  • NaOH(aq)*
  • Warm/under reflux*
25
What is the type of reaction for: Haloalkane to Alcohol
*Nucleophilic substitution*
26
What are the reagents and conditions of reaction for: Alkene to Haloalkane
## Footnote * HBr* * Room temperature*
27
What is the type of reaction for: Alkene to Haloalkane
## Footnote *Electrophilic addition*
28
What are the conditions of reaction for: Alkene to Polymer
* High temp* * High pressure* * Catalyst*
29
What is the type of the reaction for: Alkene to Polymer
*Addition polymerisation*
30
What is the type of reaction for: Alkene to Alcohol
Hydration
31
What are the reagents and conditions of reaction for: Alkene to Alcohol
* Conc. H2SO4* * Steam: 300 oC* Pressure: 60atm
32
What are the reagents and conditions of reaction for: Alkene to Dihaloalkane
## Footnote * Halide (e.g. BR2)* * Room temperature*
33
What is the type of reaction for: Alkene to Dihaloalkane
*Electrophilic addition*
34
What are the reagents and conditions of reaction for: Alkane to Haloalkane
* Halide (e.g. Cl2)* * UV light & 1:1 ratio* * free radical substitution*
35
What is the type of reaction for: Alkane to Haloalkane
*free radical substitution*