Organic Introductions Flashcards

(48 cards)

1
Q

Saturated

A

Contain single carbon-carbon bonds only.

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2
Q

Unsaturated

A

Contains c=c double bond

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3
Q

Molecular formula

A

Formula which shows the actual number of each type of atom

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4
Q

Empirical formula

A

Simplest whole number ratio of each atom in a compound

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5
Q

General formula

A

Algebraic formula for a homozygous series

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6
Q

Structural formula

A

Minimal detail that shows the arrangement of atoms in a molecule

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7
Q

Displayed formula

A

Shows all covalent bonds and atoms present in a molecule

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8
Q

Skeletal formula

A

Simplified organic formula shown by removing hydrogen atoms from alkyl chains leaving just a skeletal skeleton and associated functional groups

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9
Q

Homozygous series

A

Families of organic compounds with the same general formula

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10
Q

Homozygous series features are:

A

Show gradual change in physical properties
Each member differs by one CH2 from the last
Same chemical properties

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11
Q

Alkane functional group and suffix

A

C-C

Ane

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12
Q

Alkene functional group and suffix

A

C=C ene

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13
Q

Alcohol functional group and suffixes

A

Ol-ending
Hydroxy-beginning
C-OH

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14
Q

Halogen alkane functional group and suffix

A

Chlorine-chloro
Bromine-bromo
Iodine-iodo
C-halogen

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15
Q

Aldehydes functional group and suffix

A

O=C-H
Al-ending
Formyl-beginning

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16
Q

Ketones functional group and suffix

A

O=C
One-ending
Oxo-beginning

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17
Q

Carboxylic acid functional group and suffix

A

O=C-H

Oic acid

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18
Q

Esthers functional group and suffix

A

O=C-O

Yl oate

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19
Q

1 carbon

A

Meth

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20
Q

2 carbons

21
Q

3 carbons

22
Q

4 carbons

23
Q

5 carbons

24
Q

6 carbons

25
7 carbons
Hept
26
8 carbons
Oct
27
9 carbons
Non
28
10 carbons
Dec
29
How do you tell the positions of functional groups?
Count how many carbons go from lowest to highest
30
Which come first functional groups or branched carbon chains
Functional groups
31
What happens if there are multiple of the functional group
Di tri tetra penta hexa
32
General rules for naming carbon chains
Count longest chain Find any branched and how many carbons they contain Add appropriate suffixes
33
Hydrocarbon
Compound made of carbon and hydrogen only
34
Homolytic fission define
Each atom gets one electron the covalent bond | Half curly arrow
35
How many radicals does homolytic fission produce?
Two
36
Free radicals are:
``` Free radicals (•) don't have charge Reactive species which possess an unpaired electron ```
37
Heterolytic fission
One atom gets two electrons | ↩️
38
Structural isomers
Same molecular formula different structures (structural formulae)
39
What can structural isomerism come from?
Chain isomerism Position isomerism Functional group isomerisms
40
Chain isomers are?
Compounds with same molecular formula but different structures carbon skeleton
41
Position isomerism
Compounds with same molecular formula but different structures due to different positions of the same functional group in the carbon skeleton.
42
Functional group isomerisms
Compounds with same molecular formula but different functional group
43
Stereoisomers
Same structural formula but different spatial arrangement of atoms
44
What isomerisms can alkenes exhibit?
E-Z isomerism
45
When do E-Z isomerism arise?
Restricted rotation around c=c double bond | Two different groups/atoms attached to both ends of the double bond
46
Why do E-Z isomers exist?
Restricted rotation about c=c bonds
47
Do e-z isomerism happen in single bond
No because they can easily rotate
48
How do determine whether a molecules is E or Z?
Find highest Ar If largest are on the same side then Z If largest on both sides then E