Organic Pathways Flashcards

(36 cards)

1
Q

Alkane to Halogenoalkane

A

X2 (halogen)
UV light

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2
Q

Alkene to alkane

A

H2
Nickel catalyst
150 degrees

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3
Q

Alkene to Halogenoalkane

A

HX (hydrogen halide)
20 degrees

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4
Q

Halogenoalkane to Alkene

A

KOH
Ethanol
Reflux

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5
Q

Alkene to dihalogenoalkane

A

X2
20 degrees

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6
Q

Alkene to diol

A

Acidified KMnO4
20 degrees

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7
Q

Alkene to alcohol

A

Steam
H3PO4 catalyst
300 degrees
60-70 atm

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8
Q

Alcohol to Alkene

A

Conc H3PO4
170 degrees

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9
Q

Alcohol to Halogenoalkane (chloroalkane)

A

PCl5
20 degrees

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10
Q

Alcohol to Halogenoalkane (bromoalkane)

A

KBr
50% conc H2SO4
20 degrees

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11
Q

Halogenoalkane to alcohol

A

Warm aqueous KOH
Reflux

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12
Q

Alcohol to Halogenoalkane (Iodoalkane)

A

Rep phosphorus I2
Reflux

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13
Q

Alcohol to aldehyde/ketone

A

K2Cr2O7
Heat

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14
Q

Aldehyde/Ketone to Alcohol

A

LiAlH4

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15
Q

Aldehyde/Ketone to Carboxylic Acid

A

K2Cr2O7
Reflux

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16
Q

Carboxylic Acid to Alcohol

17
Q

Halogenoalkane to Nitrile

A

KCN
Ethanol
Reflux

18
Q

Halogenoalkane to Carboxylic Acid

A

Mg
Dry ether
Followed by CO2
Dilute acid

19
Q

Halogenoalkane to primary amine

A

Excess Ethanolic ammonia
Heat

20
Q

Nitrile to primary amine

A

LiAlH4
Followed by Dilute acid

21
Q

Nitrile to Carboxylic Acid

A

Dilute HCl
Reflux

22
Q

Acyl chloride to amide

A

NH3
20 degrees

23
Q

Alcohol to ester

A

Carboxylic acid/acyl chloride,
acid catalyst
heat

24
Q

Ester to alcohol

A

Dilute acid/alkali
Reflux

25
Carboxylic acid to ester
Alcohol Acid catalyst Heat
26
Ester to carboxylic acid
Dilute acid/alkali Reflux
27
Acyl chloride to Ester
Alcohol 20 degrees
28
Carboxylic acid to acyl chloride
PCl5 20 degrees
29
Acyl Chloride to carboxylic acid
Cold H2O
30
Benzene to bromobenzene
Br2 Halogen carrier catalyst RTP
31
Benzene to chlorobenzene
Cl2 Halogen carrier catalyst RTP
32
Benzene to nitrobenzene
Conc nitric acid Conc sulphuric acid Less than 55 degrees
33
Nitrobenzene to C6H5NH2
Tin Conc HCl Reflux
34
Benzene to C6H5COR
RCOCl Halogen carrier catalyst
35
Benzene to C6H5R
RCl Halogen carrier catalyst Reflux
36
Benzene to C6HSO2OH
Conc H2SO4 SO3 Reflux