Organic Reactions Flashcards

1
Q

Haloalkane + NH3 (concentrated)

A

Conditions: ethanol + heat + in a sealed tube
Reaction type: Substitution
Products: Amine + NH4X

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2
Q

Haloalkane + Halogen (X2)

A

Conditions: UV light
Reaction type: Substitution
Products: Di-haloalkane + HX

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3
Q

Haloalkane + NaX
(Halide ion has to be below the halogen atom in the periodic table for this substitution to occur)

A

Conditions: ethanol + stir
Reaction type: Substitution
Products: Haloalkane + NaX
(New halide ion replaces the halide ion in the alkane)

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4
Q

Haloalkane + KCN

A

Conditions: ethanol + heat using reflux
Reaction type: Substitution
Products: Nitrile + KX
(Carbon chain has increased in length)

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5
Q

Haloalkane + NaOH (dilute)

A

Conditions: lower temperature (100°C)
Reaction type: Substitution
Products: Alcohol + NaX

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6
Q

Haloalkane + NaOH (concentrated)

A

Conditions: Higher temperature
Reaction type: Elimination
Products: Alkene + NaX + H2O
(A hydrogen has to come off from a carbon that is a neighbor of the carbon with the halogen)

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7
Q

Alkene + Alkene

A

Conditions: Catalyst + high pressure + high temperature
Reaction type: Addition
Products: Polymer
(Double bond carbons become single and chain is ongoing)

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8
Q

Alkene + X2

A

Conditions: NONE
Reaction type: Addition
Products: Haloalkane
(Double bond becomes single and the two halogens join)

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9
Q

Alkene + H2

A

Conditions: (Ni or Pt or Pd) + heat
Reaction type: Addition and Reduction
Products: Alkane
(Double bond becomes single and the two hydrogens join)

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10
Q

Alkene + H2O

A

Conditions: H3PO4 + heat
Reaction type: Addition and Hydration
Products: Alcohol

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11
Q

Alkene + HX

A

Conditions: NONE
Reaction type: Addition
Products: Haloalkane

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12
Q

Alkene + O2

A

Conditions: NONE
Reaction type: Combustion and Oxidation
Products: H2O + CO2 + energy

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13
Q

1° Alcohol + Cr2O72-

A

Conditions: 1° Alcohol
Reaction type: Oxidation
Products: Aldehyde

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14
Q

2° Alcohol + MnO4-

A

Conditions: 2° Alcohol
Reaction type: Oxidation
Products: Ketone

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15
Q

3° Alcohol + MnO4-

A

Conditions: 3° Alcohol
Reaction type: NO oxidation
Products: NO REACTION

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16
Q

1° Alcohol + carboxylic acid

A

Conditions: 1° Alcohol
Reaction type: Condensation
Products: Ester

17
Q

1° Alcohol + O2

A

Conditions: 1° Alcohol
Reaction type: Combustion and Oxidation
Products: H2O + CO2

18
Q

Aldehyde + Cr2O72-

A

Conditions: Aldehyde
Reaction type: Oxidation
Products: Carboxylic acid

19
Q

Carboxylic acid + base

A

Conditions: NONE
Reaction type: Acid/base
Products: salt + water

20
Q

Carboxylic acid + carbonate

A

Conditions: NONE
Reaction type: Acid/base
Products: salt + water + carbon dioxide

21
Q

Carboxylic acid + metal

A

Conditions: NONE
Reaction type: Acid/base
Products: salt + hydrogen

22
Q

Carboxylic acid + oxygen

A

Conditions: NONE
Reaction type: Combustion and Oxidation
Products: water + carbon dioxide

23
Q

Amine + carboxylic acid

A

Conditions: NONE
Reaction type: Condensation
Products: Amide

24
Q

Nitrile + H2

A

Conditions: Catalyst, heat, high pressure
Reaction type: Addition
Products: Amine