Organic Reactions Flashcards by Hamish Pratt

Q

Alkane to Haloalkane

A

Halogen, UV

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Q

Alkene to Alkane

A

H2/Ni

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Q

Alkene to Haloalkane

A

Hydrogen halide

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Q

Haloalkane to Nitrile

A

CN- / ethanol

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Q

Haloalkane to Amine

A

NH3/ethanol

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Q

Haloalkane to Alcohol

A

NaOH(aq)

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Q

Alcohol to Haloalkane

A

Sodium halide / H2SO4

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Q

Alcohol to Alkene

A

H3PO4 or H2SO4, heat

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Q

Alkene to Alcohol

A

H2O (steam) / H3PO4

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Q

1° Alcohol to Aldehyde

A

K2Cr2O7/H2SO4

Distillation

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Q

Aldehyde to 1° Alcohol

A

NaBH4

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Q

1° Alcohol to Carboxylic Acid

A

K2Cr2O7 / H2SO4

Reflux

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Q

Aldehyde to Carboxylic Acid

A

K2Cr2O7 / H2SO4

Reflux

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Q

2° Alcohol to Ketone

A

K2Cr2O7 / H2SO4

Reflux

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Q

Ketone to 2° Alcohol

A

NaBH4

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Q

Aldehyde to Hydroxynitrile

A

NaCN(aq) / H+(aq)

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Q

Ketone to Hydroxynitrile

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A

NaCN(aq) / H+(aq)

Q

Hydroxynitrile to Amine

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A

H2 / Ni

Q

Nitrile to Amine

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A

H2 / Ni

Q

Nitrile to Carboxylic Acid

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A

H2O / HCl, heat

Q

Hydroxynitrile to Carboxylic Acid

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A

H2O / HCl, heat

Q

Alcohol to Ester

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A

Carboxylic acid / conc. H2SO4 OR acid anhydride

Q

Carboxylic Acid to Ester

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A

Alcohol / conc. H2SO4

Q

Ester to Carboxylic Acid

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A

Dilute acid, heat

Ester to Carboxylate

OH-, heat

Acyl chloride to Ester

Alcohol

Carboxylic Acid to Acyl Chloride

SOCl2

Acyl Chloride to Carboxylic Acid

H2O

Acyl Chloride to 1° Amide

NH3

Acyl Chloride to 2° Amide

Primary amine

Benzene to Nitrobenzene

Conc HNO3 | Conc H2SO4

Nitrobenzene to Aminobenzene

Sn / Conc HCl

Benzene to Bromoenzene

FeBr3 / Br2

Benzene to Chlorobenzene

AlCl3 / Cl2

Benzene to Alkylbenzene

Chloroalkane / AlCl3

Benzene to Acylbenzene

Acyl Chloride / AlCl3

Acylbenzene to 1-phenyl alcohol

NaBH4

Phenol to 2,4,6-tribromophenol

Br2

Phenol to Sodium Phenoxide

NaOH (aq)

Phenol to Nitrophenol

Dilute HNO3