Organic Synthesis and Reagents Flashcards

learn which reagents are used in which synthesis reactions

1
Q

Alcohol ( Primary ) ——> Aldehyde

A

K2Cr2O7 + H2SO4 + Heat

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2
Q

Alcohol ( Secondary ) ——> Ketone

A

K2Cr207 + H2SO4 + Reflux

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3
Q

Alcohol ( Primary ) ——> Carboxylic Acid

A

K2Cr207 + H2SO4 + Reflux

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4
Q

Alcohol ——> Alkene

A

Conc H2SO4 Catalyst

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5
Q

Aldehyde ——> Alcohol

A

NaBH4 in Water + Methanol

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6
Q

Aldehyde/Ketone ——> Carboxylic Acid

A

K2Cr2O7 + H2SO4 + Reflux

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7
Q

Aldehyde/Ketone ——> Hydroxynitrile

A

Acidified KCN / HCN + 298k

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8
Q

Alkene ——> Alcohol

A

H3PO4 Catalyst + Steam + 573k + 60atm

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9
Q

Alkene ——> Halogenoalkane

A

HX (X is a halogen) + 298k

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10
Q

Alkene ——> Dibromoalkane

A

Br2 + 298k

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11
Q

Carboxylic Acid ——> Ester

A

Alcohol + Conc H2SO4 Catalyst + Reflux

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12
Q

Alkane ——> Halogenoalkane

A

UV light + X2 (X is a halogen)

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13
Q

Halogenoalkane ——> Alkene

A

NaOH/KOH + Warm Ethanol + Reflux

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14
Q

Halogenoalkane ——> Alcohol

A

Warm NaOH/KOH + Reflux

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15
Q

Halogenoalkane ——> Nitrile

A

KCN + Dry Ether + Dilute H2 + Nickel Catalyst

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16
Q

Halogenoalkane ——> Primary Amine

A

Excess NH3 + Heat

17
Q

Ester ——> Carboxylic Acid

A

Dilute Acid/H2SO4 Catalyst + H2O + Reflux // Dilute NaOH

18
Q

Primary Amine ——> Amine (Secondary/Tertiary)

A

Further Substitution with Halogenoalkanes

19
Q

Nitrile ——> Primary Amine

A

LiAlH4 + Dry Ether + Dilute H2 + Nickel Catalyst

20
Q

Acyl Chloride ——> Carboxylic Acid

A

Water + 298k

21
Q

Acyl Chloride ——> Ester

A

Alcohol + 298k

22
Q

Acyl Chloride ——> Primary Amine

A

NH3 + 298K

23
Q

Acyl Chloride ——> Amide

A

Amine + 298k