Organic: Tests for Compounds Flashcards
(14 cards)
Alkane
NO POSITIVE TEST
Alkene
Add Br2
If present: colour change from orange/brown–>colourless
Halogenoalkane
Heat + NaOH(aq), excess HNO3(aq), then add AgNO3
If present: white, cream or pale yellow precipitate forms.
Alcohol
Heat + H+/Cr2O72-
If primary or secondary present: Orange—>Green
If tertiary present: NVR
Nitrile
NO POSITIVE TEST
Primary Amine
NO POSITIVE TEST
Secondary Amide
NO POSITIVE TEST
Carboxylic Acid
+Na2CO3(aq) or (s)
If present: effervescence
Acyl Chloride
+H2O(l)
If present: Misty fumes of HCl(g)
Primary Amide
NO POSITIVE TEST
Ester
+H2O(l)
If present: misty fumes of HCl(g)
Ketone
NO POSITIVE TEST
Aldehyde
Heat + Tollen’s Reagent (silver mirror)
Heat + Fehling’s (red precipitate)
Hydroxynitrile
NO POSITIVE TEST