Oxygen Family Flashcards

(40 cards)

1
Q

What are the elements in the oxygen family?

A

O, S, Se, Te, Po

Also known as chalcogens

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2
Q

What is the most abundant element in the oxygen family?

A

Oxygen

Comprises 21% by volume of the atmosphere, primarily produced by photosynthesis

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3
Q

What is the general electronic configuration of elements in the oxygen family?

A

ns² np⁴

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4
Q

What is the trend in electronegativity in the oxygen family?

A

O > S > Se > Te > Po

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5
Q

What is the trend in metallic character in the oxygen family?

A

O < S < Se < Te < Po

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6
Q

What is the trend in ionization energy in the oxygen family?

A

O > S > Se > Te > Po

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7
Q

What is the trend in electron gain enthalpy in the oxygen family?

A

S > Se > Te > Po > O
Reason: O is small therefore electron repulsion

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8
Q

Trend of ionic radii and atomic radii change in the oxygen family?

A

O < S < Se < Te < Po

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9
Q

Which element has a higher catenation property, oxygen or sulfur?

A

Sulfur
Reason: O has interelectronic repulsion

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10
Q

What type of compounds does oxygen mainly form?

A

Peroxides

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11
Q

What type of compounds does sulfur mainly form?

A

S8 rather than S2

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12
Q

Galena?

A

PbS

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13
Q

What is the decay product of uranium and thorium minerals?

A

Polonium (Po)

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14
Q

What is the chemical formula for gypsum?

A

CaSO4 · 2H2O

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15
Q

epsum?

A

MgSO4 · 7H2O

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16
Q

bauxite?

A

Al2O3

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17
Q

hematite?

18
Q

pyrolusite?

19
Q

True or False: As you move down the group in the oxygen family, the catenation property increases.

A

False

Catention decreases top to bottom

20
Q

Zinc blende?

21
Q

Fool’s gold

22
Q

Chalcopyrite

23
Q

Who best forms multiple bonds

A

Oxygen
Reason: 2p π 2p π overlap

24
Q

Trend of melting point and boiling point

A

O«< S< Se< Te< Po
Large diff in O and S bcz of their atomicity. O forms O2 and S forms S8

Surface area more = more mp bp

25
Oxygen allotropes
O2 and O3 Stability O2 > O3
26
Allotropes of sulphur
- rhombic α - monoclinic β - plastic - colloidal - chair form
27
α and β sulphur coexist in
Dynamic equilibrium Below 95 C α Above 95 C β
28
Yellow coloured sulphur allotrope, insoluble in h2o but soluble in CS2
RHOMBIC
29
colourless sulphur allotrope, needle shaped crystals and insoluble in CS2
MONOCLINIC
30
Chair form exists as
S6
31
Allotrope formed when red hot sulphur is suddenly placed in cold water
PLASTIC
32
Colloidal sulphur
SO2 + 2H2S —> 3S + 2H20
33
At very high temp sulphur exists as
S2 (vapour state)
34
When does sulphur show paramagnetic nature
S2 (vapour state)
35
Why is H2O liquid but H2S gas
O is more EN than S Hbonding occurs in h20 and not h2s
36
In the group -2 Oxid state is preferred by
Oxygen
37
+6 oxidn state is preferred by
Middlemost elements
38
+4 oxidn state is preferred by
Lowermost elements
39
Covalent charecter
More in bigger grp 16 elements
40
Thermal stability is more when
Ionic charecter is more