Part 2: Thermodynamics Flashcards
(14 cards)
What is the energy required to start a reaction called?
Activation energy
What does ΔG mean?
Gibbs free energy.
What type of reaction has ΔG
Exergonic reaction - release of energy
What type of reaction has ΔG > 0?
Endergonic reaction - requires energy
What value of ΔG is favourable for organisms in the environment, and what conditions are required for this?
ΔG
Why must reaction products be removed from the environment?
ΔG must be
What are the three mechanisms by which reaction products can be removed from the environment?
1) The product is used as a substrate for another reaction within the organism.
2) The product is used as a substrate for another organism.
3) The product is chemically or physically removed (e.g. precipitation of sulphide as FeS.
Which group of organisms can operate under the lowest Threshold Partial Pressure? (TC)
Nitrogen reducers - TC =
Why are methanogens low in energy? (EXAM)
They are only able to degrade low-energy compounds including H2, CO2, acetate
In what way are anaerobic environments more complex than aerobic? (EXAM)
In anaerobic environments, many organisms are required to work as a system to degrade substrates, whereas in oxic environments, only one organism is needed per substrate (e.g. cellulose).
Give examples of environments where the anaerobic carbon cycle is important.
The gut, plant systems.
What are the two known methods of energy conservation?
1) Substrate-level phosphorylation
2) Chemiosmotic energy conservation
Describe the energy-conserving method of “substrate level phosphylation”.
An inorganic phopshate (Pi) is converted to an organic phosphate that is then transferred to ADP. e.g. pyruvate decarboxylation.
Describe the energy-conserving method of “chemiosmotic energy conservation”.
Electrons are carried along the respiratory chain (sequence of proteins with increasing redox potential)
- energy is released on each electron transfer and is used to pump protons across the electrochemical and concentration gradients.
- the energy of the proton gradient is used for ATP production
- the amount of ATP formed depends on the organism’s environment since this affects the strength of the protein gradient.