Partition function 1 Flashcards

(13 cards)

1
Q

What is the single particle partition function?

A

Z = Σe-βEi

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2
Q

How do we solve a problem in SM?

A
  1. Write down Z
  2. Find the relevant functions of state
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3
Q

What is the equation for the internal energy?

A

U = -dln(z)/dβ

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4
Q

What is the equation for the entropy?

A

S = kB(βU+lnz)

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5
Q

What is the equation for Helmholtz free energy?

A

F = U-TS
F = U-kBT(βU+lnz)

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6
Q

How does the Helmholtz free energy and entropy and pressure relate?

A

(dF/dT)V = -S
(dF/dV)T = -p

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7
Q

What is the equation for Enthalpy?

A

H = U+pV

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8
Q

What is the equation for Gibbs free energy?

A

G = H-TS

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9
Q

How does entropy relate to U and F?

A

S=(U-F)/T

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10
Q

What is the Schottky Anomaly?

A

kBT/Δ~0.42

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11
Q

What is degeneracy?

A

When two or more states have the same energy

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12
Q

What is the equation for spin angular momentum?

A

S=ℏ sqrt(s(s+1))
Spin is quantised

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13
Q

What is the equation for a component of spin angular momentum?

A

SZ=ℏmS

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