Partition function 1 Flashcards
(13 cards)
What is the single particle partition function?
Z = Σe-βEi
How do we solve a problem in SM?
- Write down Z
- Find the relevant functions of state
What is the equation for the internal energy?
U = -dln(z)/dβ
What is the equation for the entropy?
S = kB(βU+lnz)
What is the equation for Helmholtz free energy?
F = U-TS
F = U-kBT(βU+lnz)
How does the Helmholtz free energy and entropy and pressure relate?
(dF/dT)V = -S
(dF/dV)T = -p
What is the equation for Enthalpy?
H = U+pV
What is the equation for Gibbs free energy?
G = H-TS
How does entropy relate to U and F?
S=(U-F)/T
What is the Schottky Anomaly?
kBT/Δ~0.42
What is degeneracy?
When two or more states have the same energy
What is the equation for spin angular momentum?
S=ℏ sqrt(s(s+1))
Spin is quantised
What is the equation for a component of spin angular momentum?
SZ=ℏmS