Periodic Trends Flashcards

1
Q

coulombic attraction

A

“electrostatic force”:
the force of attraction or repulsion between charged particles

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2
Q

what affects coulombic attraction?

A
  1. the signs of the particles
  2. the distance between the particles
  3. their charge’s magnitude
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3
Q

if the charge of a particle increases…

A

the magnitude of electrostatic forces also increases

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4
Q

if the distance between particles increases…

A

the magnitude of electrostatic force quickly decreases

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5
Q

coulomb’s law

A

the electrostatic force between two charged particles:
F oc (q1 x q2)/ r^2
(f is the force, q charge of particle)

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6
Q

what is coulomb’s law?

A

a proportionality

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7
Q

how to find nucleus and e- attraction?

A

F oc (q nuc x q2)/ r^2

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8
Q

what happens if both charges are the same, or different in coulomb’s law?

A

same: repulsive force
different: attractive force

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9
Q

shielding is…

A

when when outer electrons are repulsed by inner electrons, and therefore feel lesser pull towards the nucleus

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10
Q

shielding across and down:

A

across a period: shielding doesn’t increase a lot (same outer shell)
down a group: shielding increases a lot (extra outer shells, so more inner e-)

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11
Q

effective nuclear charge (zeff)

A

the amount of charge an electron actually feels from the nucleus
zeff = z - s

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12
Q

Fe

A

Another aka of electrostatic force / coulombic attraction

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13
Q

across a period

A

zeff increases, attraction btwn nuc and e-s increases, as shielding up, but nuc charge upup

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14
Q

down a group

A

zeff increases, distance INCREASES, so attraction decreases (shielding and charge increase, but distance even more)

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15
Q

ionization energy

A

the E needed to remove 1 e-

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16
Q

e- affinity

A

the E released when 1 e- is gained

17
Q

electronegativity

A

an atom’s tendency to attract e- density in a bond (lower it is, the more it shares e-s)

18
Q

across a period trends

A

radius down
IE up
EA up
ENEG up

19
Q

down a group trends

A

radius up
IE down
EA down
ENEG down

20
Q

why is distance more powerful than charge in coulomb’s law?

A

b/ distance is SQUARED and in the denom (:

21
Q

IE trends

A

up in a period b/ it takes more energy to take an e- from more charge, down in a group b/ opposite

jumps for each IE, jumps a LOT if losing a shell

22
Q

radius trends

A

down in a period b/ the more p+s, the more the e-s are pulled in, up in a group b/ opposite

23
Q

EA trends

A

up in a group b/

24
Q

electronegativity trends

A

up in a period b/ more charge means the less it wants to share and down in a group b/ the less charge, the easier it is to share

25
Q

IE exceptions

A
  1. lower when 1 e- is on a higher sublevel (like p vs s) b/ it takes less energy to pull off a single e- in a dif sublevel
  2. lower when 1 pair of e-s is in one orbital b/ more e- - e- repulsion, and easier to remove