Periodicity Flashcards

(14 cards)

1
Q

what is periodicity

A

the study of trends within the periodic table. Often linked to elements electronic configurations

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2
Q

What is the trend in atomic radius along a period

A

atomic radius decreases

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3
Q

why does the atomic radium decrease along a period

A
  • due to an increased nuclear charge
  • same number of electron shells
  • means that the outer electrons are pulled close to the nucleus as the charge produces a greater attraction
  • atomic radius reduced
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3
Q

what is the trend in atomic radius down a group

A

increases

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4
Q

why does the trend in atomic radius increase down a group

A
  • more electron shells
  • increases distance between the outer electrons and the nucleus so weaker force of attraction
  • increase electron shielding
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5
Q

what is the trend in ionisation energy along a period

A

increases

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6
Q

why does the ionisation energy increase along a period.

A
  • atomic radius decreases
    -increase nuclear charge
  • outer electrons are held more strongly so more energy required to remove the outer electron and ionise atom.
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7
Q

What is the trend in ionisation energy going down a group

A

energy decreases

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8
Q

why does the ionisation energy decrease down a group

A
  • weaker FOA between nucleus and outer electrons
  • shielding increases
  • less energy required to remove outer electron
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9
Q

what does the melting point of period 3 elements depend on

A
  • structure of element
    -bond strength
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10
Q

what happens to melting points across period 3 between sodium and aluminium

A
  • all metals with metalliic bonding
  • increase due to greater positive charge of their ions
  • more electrons are released in the form of free electrons
  • increasing electrostatic forced
  • more energy needed to break
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11
Q

Why does the melting points increase dramtically for silicone in period 3

A
  • very storng covalent structure
  • more energy required to break the strong covalent bonds
  • high melting point
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12
Q

why does the melting point decrease in period 3 between P and Cl

A
  • all simple covalent molecules with weak VDW
  • less energy is needed to overcome these weak intermolecular forces
  • low melting points
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13
Q

why does argon have an even lower melting point than Cl

A
  • Argon is a noble gas that exists as individual atoms with a full outer shell of electrons
  • makes atom every stable
    -VDW forces very weak
  • less energy requried to overcome weak VDW forces so argon exists as a gas at room temp
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