Periodicity Flashcards

1
Q

Name the 4 types of bonding structures

A

Metallic
Monatomic
Covalent molecular
Covalent network

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2
Q

In the first 20 elements, name the elements with metallic bonding

A

Li Be Na Mg Al K Ca

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3
Q

In the first 20 elements, name the elements with monatomic bonding

A

He Ne Ar

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4
Q

In the first 20 elements, name the elements with covalent molecular

A

H2 N2 O2 F2 Cl2 P4 S8 and fullerenes

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5
Q

In the first 20 elements, name the elements with covalent networks

A

B C (diamond and graphite) Si

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6
Q

The noble gases are what type of elements

A

Monatomic

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7
Q

What kind of forces are between the atoms of noble gases

A

London dispersion forces

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8
Q

Describe London dispersion forces

A

Weak forces of attraction between atoms and molecules when temporary dipoles are formed within atoms or molecules

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9
Q

What do the halogens Hydrogen, Nitrogen, oxygen exist as?

A

Individual diatomic molecules

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10
Q

Hydrogen etc have London dispersion forces between the molecules, what are these?

A

Intermolecular forces

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11
Q

Hydrogen etc have strong covalent bonds between the atoms in a molecule, what are these known as?

A

Intramolecular forces

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12
Q

Sulfur and phosphorus have strong London dispersion forces. What state are they in at room temp?

A

Solids

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13
Q

Carbon can exist as fullerenes, describe these.

A

Large individual covalent molecules, which have molecules with 60 carbon atoms or more.

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14
Q

What shake can fullerene molecules be?

A

Ball or tube-shaped

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15
Q

Why do fullerenes have high melting points?

A

Large London dispersion forces between molecules

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16
Q

Carbon can exist as covalent networks in the form of?

A

Diamond and graphite

17
Q

The carbon atoms in diamond are bonded to …

A

4 other carbons in a large, strong, three-dimensional network. That is very hard.

18
Q

The structure of diamond results in diamond having?

A

A very high melting point

19
Q

Why is diamond a non-conductor of electricity?

A

It has no delocalised electrons

20
Q

Graphite forms a network that each carbon is bonded to? Can it conduct electricity?

A

Three other carbons, which results in graphite having delocalised electrons, and do conducts electricity.

21
Q

The carbon atoms in graphite form what kind of shape? What are they held together by?

A

Hexagonal plates which are held together by London dispersion forces

22
Q

The layers in graphite can be easily seperated, what does this result in?

A

Graphite’s not as hard as diamond

23
Q

Boring and Silicon are covalent networks, describe their properties.

A

High melting and boiling points

24
Q

What patterns exist when going down a group, or across a period?

A

Covalent radii, ionisation energy, electronegativity

25
Q

Describe the covalent radius

A

Is half the distance between the nuclei of two atoms, joined by a covalent bond

26
Q

What happens to the covalent radius going down a group and why?

A

Covalent radius increases as the number of occupied electron shells increases and shields the outer electrons from the pull of the nucleus

27
Q

What happens to the covalent radius going across a period?

A

Decreases as there is no increased shielding as the electrons are added to the same shell, stronger nuclear charge

28
Q

What is ionisation energy?

A

The energy required to remove one mole of electrons from one mole of atoms in the gaseous state

29
Q

What happens to the first ionisation energy going down a group?

A

Decreases going down a group as the outer electrons get further away from the nucleus and are shielded by from the pull of the nucleus by shells of the inner electrons

30
Q

What happens to the first ionisation energy across a period?

A

Generally increases as the outer electrons are held more tightly by the nucleus as electrons are added to the same energy level and energy he charge on the nucleus increases

31
Q

What is electronegativity?

A

A measure of the attraction an atom has for the electrons of the bond

32
Q

What happens to electronegativity going down a group?

A

Decreases as atoms get bigger and the attraction of the nucleus for bonding electrons decreases

33
Q

What happens to electronegativity going across a period?

A

Increases as the atoms get smaller, and the attraction of the nucleus for the bonding electrons increases