Petroleum Flashcards
(45 cards)
What are the three main hazards of petroleum and how do they pose a risk to the ship?
Flammability (fires/explosions)
Density (gives off gasses heavier than air)
Toxicity ( harmful to humans)
What conditions are required for petroleum gasses to burn?
Petroleum gasses only burn when they are mixed with air in the right proportion. The gasses are flammable when the proportion of gasses to air is between the lower and upper flammable limits. ( usually around 1 and 10%)
What is the flashpoint?
When liquid petroleum products are heated the concentration of gas increases. The temperature at which the concentration reaches the lower flammable limit is the flashpoint.
What is a volatile liquid?
A liquid with a flashpoint of less than 60 degrees Celsius
What is a non-volatile liquid?
A liquid with a flashpoint of 60 degrees Celsius or above.
What is the LFL?
Lower flammable limit. Below this limit there is insufficient hydrocarbon gas in the mixture to support combustion. The mixture is lean.
What is the UFL?
Upper flammable limit. Above this limit the is insufficient oxygen in the mixture to support combustion. The mixture is too rich.
What is the flammable range?
The range of mixtures of hydrocarbon gas that will support combustion. Between the LFL and UFL.
What are some possible causes of explosion/combustion?
- Direct heat
- Mechanical sparks
- Chemical energy
- Electrical energy
What are some sources of direct heat on a ship?
Hot work
Smoking
Funnel sparks
What are some things on a ship that might cause mechanical sparks?
Dropped tools
Chipping
Badly secured anodes
Cigarette lighters
What are some sources of chemical energy on a ship?
Metallic smears
Spontaneous combustion
Auto ignition
Polyphoric iron sulphide - produced when H2S is present with rust.
What are some sources of electrical energy on a ship?
Electrical sparks
Electrical arching
Lightning
Static discharge
How can static charges be created on a ship?
- The flow of liquids
- The flow of fuels through fine filters
- The movement of contaminants through a liquid (slop tanks)
- Gas bubbles rising through a liquid
- Static accumulator oils (insufficient conductivity to dissipate a charge)
- The splashing of a liquid against a solid surface
- Water droplets or oil being ejected from a nozzle during tank cleaning
- Synthetic ropes rubbing on PVC gloves
- Wet steam condensing
What are some objects that may need to be insulated to prevent static discharges?
- Ship/shore couplings and flanges if more than one non-conductive pipe or hose in a string
- Portable tank cleaning machines
- Manual ullaging and sampling equipment
- A metal object such as a sampling can, floating in a static accumulating liquid.
- A loose metal object while it is falling in a tank.
What is a static accumulating liquid?
A liquid with a conductivity less that 50 pico siemens per metre
What is earthing?
A connection to the main structure of the ship
What is bonding?
Connecting two metal parts together to ensure electrical continuity.
What are some safety precautions that need to be taken aboard petroleum cargo vessels?
- No smoking on deck
- No hot work on deck
- Use intrinsically safe equipment at all times
- Limit the initial loading rate
- Ensure there are no hot surfaces near cargo tanks
- Anti-static additive
- Ensure electrical continuity of hoses
- Only use earthed and bonded equipment in cargo tanks.
- Be careful of ullaging and sampling equipment
- Ensure there are no loose conductive objects in cargo tanks
- Avoid splash filling by using a filling line that terminates close to the bottom of the tank.
What is toxicity?
Toxicity is a substances ability to harm humans. Toxic substances can cause damage through ingestion, inhalation, absorption and injection
What is TLV?
Threshold Limit Value. The maximum concentration of cargo vapours in air which personnel can be exposed to without adverse effects. Measured in parts per million of volume of gas in air.
What is TLV-TWA
Threshold limit value - time weighted average. The maximum concentration of cargo vapours in air that a person can be exposed to for a regular 8hr day/40hr week.
What is TLV-STEL?
Threshold limit value - short term exposure limit. The max concentration of cargo vapours in air that personnel may be exposed to for 15 minutes. Max 4 times per day with an hour between each time.
What is the TLV-C?
Threshold limit value - ceiling. The concentration of cargo vapours in air that must not be exceeded.