pH, Acids & Bases Flashcards

1
Q

What do acids and bases, respectively, have a tendency to do?

A

Acids have a tendency to lose a proton and bases have a tendency to accept a proton.

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2
Q

What is the equilibrium equation for acids and bases?

A

AH + B A- + BH+

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3
Q

What do the following, from the equilibrium equation, represent?

  1. AH
  2. B
  3. A-
  4. BH+
A
  1. an acid
  2. a base
  3. the acid’s conjugate base
  4. the base’s conjugate acid
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4
Q

When water behaves as a base what happens?

A

It accepts H+ and forms a hydronium ion (H3O+).

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5
Q

When water behaves as an acid what happens?

A

It loses a proton and forms a hydroxide ion (OH-).

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6
Q

What is pH?

A

It’s a measure of the acidity of a solution.

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7
Q

The pH of a solution depends on what two things?

A
  1. the concentration of the acid/base in the solution

2. the type of the acid/base in the solution

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8
Q

What does the pKa value tell us?

A

It tells us how acidic (or not) a given hydrogen atom in a molecule is i.e. how likely it is that a hydrogen atom is released.

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9
Q

What is pKa?

A

It is the pH at which a group has lost half of its hydrogens.

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10
Q

True or False: an acid is a substance that increases the concentration of hydronium ions (H3O+) in a solution.

A

True

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11
Q

How far do strong acids dissociate in water?

A

Strong acids completely dissociate in water.

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12
Q

How far do weak acids dissociate in water?

A

Weak acids only partially dissociate in water.

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13
Q

True or False: a weak acid dissociates as the pH increases.

A

True

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14
Q

What is the status of the acid if the pH is 2 units or more below the pKa?

A

The acid is approximately 100% undissociated i.e. < 1% dissociated.

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15
Q

What is the status of the acid when the pH = pKa?

A

The acid is 50% dissociated.

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16
Q

What is the status of the acid if the pH is 2 units or more above the pKa?

A

The acid is almost fully dissociated i.e. >99% dissociated.

17
Q

INSERT CARD HERE ABOUT BUFFERRING!

A

SLIDE 15

18
Q

What is meant when it’s said that Phosphoric acid has three dissociable protons?

A

It means that the acid has three hydrogens to donate.

19
Q

What happens to an acid when it dissociates?

A

The acid either loses or gains a charge.