pollution 4 Flashcards

nanomaterials, chemical cocktails and the future (13 cards)

1
Q

nanoparticles

A
  • particle less than 100 nanometres in one dimension
  • engineered nanomaterials e.g. for large surface area, antibacterial properties electrical properties, magnetic properties
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2
Q

Engineered NM environmental impacts

A
  • use and disposal of NMs then enter environment
  • enhanced properties cause them to interact with environment causing abiotic reactions: can produce chemicals more toxic than nanomaterials itself
  • can also impact on an ecosystem scale due to chemical effects, contaminant interactions with other compounds and bioaccumulation (largely unknown)
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3
Q

Toxicity of silver nanoparticles

A
  • many consumer products uses silver nanoparticles (AgNPs)
  • comes through home and industries
  • impact of AgNPs on pacu (P. mesopotamicus )
  • even at low exposure nanoparticles in brain, liver and gills
  • this increased antioxidant stress and evidence of DNA damage even at low concentrations
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4
Q

Ag NP on community structure

A
  • fungi and bacteria help decompose leaf litter
  • silver nanoparticles and silver nitrate impacted community structure of bacteria in both short term (5 days) and long term exposure
  • fungi took longer to response to exposure (only showed impact after 25 days)
  • in bacteria the community becomes more tolerant and rapidly response to exposure
  • fungi cant response as well, changes are more physiological, taxa lost
  • impact on ecosystem function: significant reduction in leaf mass consumed by bacteria and fungi biomass and production is reduced – impacts on community and ecosystem scale
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5
Q

Pollutant cocktail

A
  • pollutants interact with each other and the ecosystem
  • additive effect: add together and combined effect is the effect of individual exposures added
  • synergistic effect: combined effect of two contaminants is greater than additive effect
  • antagonistic effect: combined effect of contaminants is lower than additive effect
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6
Q

Pollutant cocktails: pharmaceuticals

A
  • Vasquez et al 2014
  • few studies on pollutant cocktails
  • most studies on algae, zoo plankton, daphnia etc not on larger organism
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7
Q

Impact of diphenhydramine and nanoplastics on zebrafish

A
  • Barreto et al 2023
  • combined exposure greater than induvial exposures (synergistic)
  • reduction in survivorship, increase in defects in combined exposure
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8
Q

Pesticide cocktail impacts on tadpole of toad

A
  • pesticides are commonly used multiple at a time
  • looked at mortality, genotoxicity, cardiotoxicity
  • examined combined effect of pesticide cocktails and saline stress
  • interactive effect: mortality greater when pesticide mixture crossed with NaCl
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9
Q

Pollutant cocktail interaction with plastics

A
  • 4 risks factors of plastics: shape, polymer type, size of particle and environmental chemistry
  • method of categorising environmental risk of plastic pollution types
  • however requires large number of information how these variables interact with environmental chemistry/other additives to understand risk
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10
Q

future research on ECs

A
  • characterise the effect of EC mixtures at environmentally relevant concentrations
  • understand the impact of ECs on other environment stresses, in particular future climate stressors due to climate change. How this influences, breakdown mobility and transport
  • Identify influence on aquatic ecosystem functioning and non-target organisms
  • determine interactions of ECs with other pollutants
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11
Q

future monitoring of ECs

A
  • regular monitoring of ECs required as national assessment of aquatic health
  • increase data collection from the Global South to understand emerging contaminants at a global scale
  • cost-effective, reliable. Standardised methods for monitoring ECs to increase monitoring capacity
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12
Q

The future interventions

A
  • investment in treatment methodologies and technologies for EC removal of wastewaters
  • regulation of pharmaceutical and other EC use and disposal
  • creation of open reference data bases – similar to pesticides
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13
Q
A
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