Polymers Flashcards

1
Q

Best polymer properties (3)

A

Cheap, Lightweight, corrosion resistance

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2
Q

Difference between Engineering polymers and common

A

Improved strength and temp performance

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3
Q

What are polymers?

A

Repeat units of a molecular unit

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4
Q

2 Ways of creating polymers

A

Addition polymerisation, condensation polymerisation

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5
Q

Addition polymerisation what

A

Monomers are joined together with no extra product created

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6
Q

Condensation Polymerisation

A

To molecules are added together

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7
Q

Does condensation polymerisation result in an additional product

A

yes a condensate (water, methane)

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8
Q

How to measure polymer size(2)

A

Molecular weight or degree of polymerisation

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9
Q

How to calculate degree of polymerisation?

A

number of monomers

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10
Q

Polymer chains- Linear

A

just straight

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11
Q

Polymer chains- branched, properties

A

like tree, lower density and strength

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12
Q

Polymer Chains- crosslinked (properties)

A

covalent bonds- increases strength and stiffness

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13
Q

What is a copolymer?

A

2 or more types of polymer

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14
Q

grafted copolymer what

A

linear with one monomer and branches of the other sticking out

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15
Q

Block copolymers what

A

many of one monomer and then many of the other

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16
Q

Thermoplastics- structure

A

linear/ branched

17
Q

Thermoplastics- tensile properties (4) and why?

A

plastic and ductile, not strong low density cause chains can be pulled apart from each other

18
Q

Thermoplastics- heat?

A

Soften and melt

19
Q

Thermoplastics- crystal

A

mix of amorphous and crystalline

20
Q

Thermoplastics- examples

A

Polyester, polycarbonate, polyethylene

21
Q

Thermoplastics - stress strain curve why weird

A

Stress reduces after elastic region

22
Q

Why does stress strain curve weird

A

Cause the chains slide rotate disentangle and become aligned with stress direction

23
Q

Thermoplastics temperature dependence

A

Can be glassy leathery or viscous depending on temp

24
Q

Thermoplastics- creep- describe

A

under constant load sample gradually gets longer

25
Thermoplastics - relaxation describe
under constant strain leads to stress reaction- exponential- depending on temp
26
Thermosetting- chains?
Cross-linked
27
Thermosetting- heat?
do no soften
28
Thermosetting- properties (3)
Harder, more brittle and more stable
29
Elastomers- chains
Crosslinked but specially
30
Elastomers- deformation
no plastic deformation but still has viscoelastic relaxation
31
Thermoplastics - blow moulding
using air to get into shape
32
Thermoplastics- calendaring
Like making pasta
33
Thermoplastics- thermoprocessing
using a vacuum to suck it to the right bits
34
Thermoplastics-injection moulding
Injecting plastics into mould
35
Thermosets- processing general
must be processed and a liquid before cross-linking
36
Thermosets- compression moulding
using hot dies to shape and start crosslinking
37
Thermosets- transfer moulding
put in mould and then it will polymerize through heat
38
Are thermoplastics recyclable
yes but not easy as have to be pure and get rid of extras
39
Are thermosets recyclable
no