Polymers and Life - Isomerism and Carboxylic Acids Flashcards

(37 cards)

1
Q

what is a saturated compound?

A

hydrocarbons that contain the maximum amount of hydrogens possible with no double or triple bonds

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2
Q

what is an aromatic compound?

A

a compound that contains one or more benzene rings

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3
Q

what is an aliphatic compound?

A

compounds that do not contain any benzene rings

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4
Q

what is a homologous series?

A

a series of compounds that all contain the same functional group

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5
Q

what is a functional group?

A

modifers that are responsible for the characteristic chemical reactions of molecules

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6
Q

what is the structure of phenol?

A

an OH group attached to a benzene ring

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7
Q

what is an isomer?

A

compounds with the same molecular formula but have different arrangements of atoms

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8
Q

what is structural isomerism?

A

when the atoms are bonded together in a different order

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9
Q

what is stereo isomerism?

A

order of bonding of atoms is the same but the arrangement of atoms in space is different

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10
Q

what are the types of structural isomerism?

A

chain isomerism

position isomerism

functional group isomerism

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11
Q

what is chain isomerism?

A

when the arrangement of carbon chains and side chains is different

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12
Q

what is position isomerism?

A

when the functional group is in a different position in the molecule

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13
Q

what is functional group isomerism?

A

when there are different functional groups in the molecule

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14
Q

what are the types of stereoisomerism?

A

geometric isomerism

optical isomerism

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15
Q

what is a carbonyl compound?

A

C = O

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16
Q

what is an acyl compound?

18
Q

what is the functional group for aldehydes?

19
Q

what is the functional group for ketones?

22
Q

how are molecules with two carboxyl groups named?

A

ending -dioic

23
Q

what is the structure of benzoic acids?

25
Q

how are esters named, using ethyl ethanoate as an example

A

named after the alcohol and acid that it is formed from

acid part ends it -oate

ethyl ethanoate is formed from ethanol and ethanoic acid

26
Q

what is the equation for carboxylic acid dissociation?

A

R-COOH ⇔ R-COO- + H+

27
Q

what is the strength of carboxylic acid?

A

it is a weak acid

28
why is carboxylic acid a weak acid?
only a small proportion of the carboxylic acid molecules will dissociate
29
what is produced when a carboxylic acid reacts with a carbonate?
carbon dioxide, water and an ethanoate salt
30
what happens when an alcohol or a phenol reacts with a carbonate compared to carboxylic acids?
carboxylic acids - solution will fizz alcohol and phenol - will not fizz
31
what happens when ethanoic acid reacts with universal indicator?
it will turn the universal indicator orange
32
what happens when ethanoic acid reacts with magnesium?
magnesium ethanoate produced hydrogen given off
33
what happens when ethanoic acid reacts with sodium hydroxide?
sodium ethanoate is produced as well as CO2 and H20
34
what happens when ethanoic acid reacts with sodium carbonate?
sodium acetate, carbon dioxide and water produced
35
what happens when ethanoic acid reacts with sodium hydrogen carbonate?
calcium ethanoate solution produced carbon dioxide released
36
what happens when carboxylic acids react with metals?
redox reaction produces a salt and hydrogen gas
37
what happens when carboxylic acids react with alkalis?
acid-base neutralisation reaction produces salt + water
38
what happens when carboxylic acids react with carbonates?
acid-base reaction produces salt, water and carbon dioxide
39
how are esters formed?
condensation reaction between a carboxylic acid and an alcohol reversible reaction, usually under reflux and with a catalyst
40
what is the reverse reaction of esterfication?
hydrolysis of an ester into a carboxylic acid and an alcohol