Portland cement Flashcards

(39 cards)

1
Q

glue that bonds aggregate together to make concrete

A

cement paste (cement + water)

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2
Q

cement paste and sand

A

mortar

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3
Q

cement + water + sand + gravel

A

concrete

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4
Q

process to make portland cement

A

crushing and grinding of raw materials, heat and melt in kiln that forms cement clinker, add gypsum to clinker and pulverize to fine powder

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5
Q

chemical composition of PC

A

tricalcium silicate, dicalcium silicate, tricalcium aluminate, and tetracalcium aluminoferrite

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6
Q

How is fineness important when making PC

A

smaller particles have more surface area to react with water, fineness controls the rate of hydration (heat and strength game)

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7
Q

measures air permeability against known standard material

A

Blaine test

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8
Q

measures sedimentation rate suspended in kerosene

A

Wagner Turbidimeter

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9
Q

specific gravity of cement (w/o air voids)

A

3.15

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10
Q

chemical reaction of cement w water

A

hydration

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11
Q

dominates early stage of hydration

A

through-solution

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12
Q

solid state reaction at cement surface

A

topochemical

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13
Q

Hydration rate: aluminates > silicates

A

needs balance

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14
Q

Hydration of C3S & C2S

A

makes paste strong

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15
Q

Primary Chemical Reaction Chemical reactions that harden cement paste

A

Fast in the beginning but is long term (decades in dams), Causes heat, which can be a problem if there’s too much

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16
Q

Voids in hydration space

A

interlayer hydration space, capillary voids, trapped voids, entrained air

17
Q

space between atomic layers, shrinkage if humidity is less than 11%

A

interlayer hydration space

18
Q

w/c too high, decrease strength and increased permeability

A

capillary voids

19
Q

large pockets caused by handling, decrease strength and increase permeability

A

trapped voids

20
Q

microscopic bubbles caused by admixtures, increased durability

A

entrained air

21
Q

change from plastic state to solid state

22
Q

premature stiffening within a few minutes

23
Q

sets that cannot be fixed

A

quick and flash sets

24
Q

Ability for concrete to retain volume after setting

25
Most important property of hydrating cement
water-cement ratio
26
w/c need for hydration
0.4
27
Pros and cons of adding extra water to cement?
improves workability but also causes voids
28
types of PC
``` I. Normal II. Moderate Sulfate Resistance III. High Early Strength IV Low Heat of Hydration V. High Sulfate Resistance ```
29
produce tiny, dispersed air bubbles into the concrete, causes cracking and internal stress, this prevents this from happening
Air Entrainers
30
Air Entrainers decrease strength by 20% but can be compensated with lower w/c ratio
true
31
Three ways to use water reducers
1. ) improve workability using same w/c ratio 2. ) increase strength using lower w/c ratio 3. ) reduce cost at same w/c ratio by reducing both water and cement
32
delay or retard initial set (increase set time), may reduce early strength, usually doesn't reduce final set time, long haul time
Retarders
33
have the ability to stop and reactivate the hydration process of concrete
Hydration Controllers
34
2 parts to hydration controllers
stabilizer and activator
35
speed up initial and final set times
Accelerators
36
What are accelerators used for?
increase rate of strength gain, reduce the amount of time before finishing operations begin, reduce curing time, plug leaks under hydraulic pressure efficiently
37
Most common accelerator
calcium chloride
38
most common supplementary cementitious Materials
Fly Ash
39
Classes of Fly Ash
N, F, and C