Properties and structure of matter Flashcards

1
Q

Homogenous mixture

A

A mixture with indistinguisable components:
- Same consistency throughout
- All components are in (or dissolved into) a single phase/state of matter
- E.g: tea with sugar, air, tap water

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2
Q

Heterogeneous mixture

A

A mixture with physically distinguishable components:
- Differing consistency throughout
- All components don’t have to be in the same phase/state of matter
- E.g: oil and water, wet sand, bread, gravel

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3
Q

Phase

A

State of matter (gas, liquid, solid etc)

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4
Q

List some methods of separation based on physical properties

A

Decantation, centrifuge, magnetic separation, evaporation & crystallisation, filter funnels, distillation

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5
Q

Decantation

A

Immiscible liquids or mixtures with suspensions will separate according to density (with the most dense at the bottom) and form layers. The top layer can then be poured off the top.

Physical property that the separation is based on: density

There are limitations to the purity of the separated components, the the process is favourably quick.

EXAMPLE: oil and water

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6
Q

Define immiscible

A

Two liquids that will not dissolve into one another

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7
Q

Centrifuge

A

The separation of mixtures (usually fluids or fluid/solid mixtures) based on the physical property using centrifugal force. The centrifugal force pushes the more dense (heavier) objects to the out edge of the orbital movement. This leaves the denser materials at the bottom of the centrifuge tube with less dense substances sitting on top. These are then separated by decantation (pouring off top layer).

Physical property that the separation is based on: density

EXAMPLE: removing fat from milk to produce skim milk

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8
Q

Define centrifugal force

A

A force which appears to act on a mass moving in a circular path and is directed away from the centre around where the mass is moving

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9
Q

Magnetic separation

A

If a component of a solid mixture is magnetic in nature, it can be separated by placing a magnet in front/above the mixture and the magnetic component in removed due to the magnetic attraction.

Physical property that the separation is based on: Magnetic nature

Note: this process is limited to ferromagnetic elements or compounds (Fe, Ni and Co). The process is favourable as it is very inexpensive and fairly reliable. It is often common in iron ore mining.

EXAMPLE: Iron filings and sand

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10
Q

Define ferromagnetic vs ferrimagnetic

A

Ferromagnetic: elements that are naturally attracted to magnetic fields

Ferrimagnetic: compounds or minerals that are naturally attracted to magnetic fields

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11
Q

Define mixture

A

Two or more substances that are mixed together but not chemically combined and that may vary in proportion. Can be separated by physical methods and are based on physical properties.

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12
Q

Evaporation/crystallisation

A

Evaporation: allowing the solvent to vaporise from a solution in a natural environment and retain the solid solute
Crystallisation: forcing the evaporation by applying heat to rapidly drive off the solvent while retaining the solid solute

Basically: When a solution is heated, the solvent evaporates and crystals of the solute are left behind.

Physical property that the separation is based on: boiling point

Limitations include loss of the solvent and high energy output for crystallisation. Some solute can also be lost if heating is too vigorous.

EXAMPLE: salt water mixture; is heated, water is evaporated from a liquid to a gas, leving behind the salt in a solid, crystallised state.

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13
Q

Solution vs solvent vs solute

A

A solution is a homogeneous mixture consisting of a solute dissolved into a solvent. The solute is the substance that is being dissolved, while the solvent is the dissolving medium.

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14
Q

Solution vs mixture

A

A mixture is when two or more substances are mixed physically, but not chemically bonded. E.g: seawater

A solution is a type of homogeneous mixture of two or more substances that are chemically mixed. E.g: sugar water

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15
Q

How can a solution be separated

A

By applying heat and vaporising the solvent from the solution

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16
Q

Filter funnels

A

Insoluble substances can be separated from liquid mixtures through filtration. Larger/solid particles (the insluable residue) are trapped by the filter. The residue is retained in the filter (and will contain some liquid unless evaporated) while the fitrate passes through and is collected by a breaker/flask beneath.

Physical property that the separation is based on: particle size/state of matter

Sieves can be used to separate mixtured of solid particles of varying size. A limitation is that filtration can be a slow process.

EXAMPLE: sand and saltwater

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17
Q

Define filter

A

A perforated barrier that allows the rest of the mixture to travel through

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18
Q

Define residue

A

The component of the mixture that is trapped by the filter

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19
Q

Define filtrate

A

The components of the mixture that passes through the filter

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20
Q

Define boiling point

A

The temperature that a substance moves from the liquid phase to the gas phase

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21
Q

Distillation

A

Separates miscible liquids/solutes from a solution by removing the component with the lowest boiling point as a gas through heating. The lower boiling points in the liquid vaporises and enters the condenser; cool water lowers the temp. of the vapor, which then condenses back into a liquid for collection.

Physical property that the separation is based on: particle size/state of matter

It is often useful on an industrial scale when separating out crude oil.

EXAMPLE: water can be separated from salt solution by simple distillation. This method works because water has a much lower boiling point than salt. When the solution is heated, the water evaporates.

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22
Q

Define distillate

A

The component of the mixture that passes through the condenser

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23
Q

Multiple stage separations with an example

A

If a mixture has multiple components that interact with different ways one may need to use multiple stages in the separation.

EXAMPLE: sandy seawater. Sea water has salt and sands mixed with it. The salts are soluble and make a homogenous solution with the water while the sand in insoluble and makes supension with the salt water solution.
Stage 1: filter out the sand from the heterogeneous mixture - the water needs to be evaporated from the sand
Stage 2: The homogenous mixture is separated through crystallisation leaving salt in the evaporating basin

Note: this ^ will not retain the water

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24
Q

Define percentage composition

A

Indicates the relative amounts of each element/compound in a composition

25
Calculating percentage composition by weight
- The unit of mass is grams - Measure the total mass of a sample and once separated , measure the mass of the component collected Mass % = mass of component / mass of mixture x 100/1 - Mass percentage is also known as percent by weight or w/w% EXAMPLE: 100g of sea water was evaporated and 5.3g of crystallised salts were remaining in the evaporating basin. Calculate the percentage by weight of salts. mass % = 5.3g/100g x 100/1 = 0.053 x 100 = 5.3 w/w%
26
Define ionic bonding
Involves the outright transfer of electrons from one atom to another. The bonding consists of electrostatic attraction between the positive and negative ions formed.
27
Define ions
Positively (cations - metals) or negatively (anions - non-metals) charged particles
28
Empirical formulae
Formulae that give the ratio by ions (or atoms) of the elements in a compound, rather than the actual numbers of atoms in a molecule
29
Define valence/valency
The number that measure the combining power of the element when it forms compounds. It allows determination of the rations in which elements combine to form compounds. When an elements forms ionic compounds, the valence of the element is the numerical value of the charge on the ion of the element.
30
Ionic binary compounds
Named by giving the positive ion first, then the negative ion. The positive ion has the same name as the element (e.g 'sodium', 'calcium') while for the negative ion the ending of the element name is changed to -ide.
31
Define polyatomic ion
An ion formed from two or more atoms joined together
32
What can chemical substances be divided into
Organic and inorganic substances
33
Organic substances
Those based on carbon, almost always bonded to other carbon and/or hydrogen.
34
Inorganic substances
A group of chemicals that contain no carbon
35
IUPAC
The International Union of Pure and Applied Chemistry
36
Define malleable
Able to be hammered or pressed into shape without breaking or cracking
37
Define brittle
Hard but liable to break easily
38
Define alloy
A metal made by combining two or more metallic elements, especially to give greater strength or resistance to errosion
39
Define electrolysis
A process in which an electric current is passed through a substance, causing it to break down into its component parts
40
Define gravimetric
1. Relating to the measurement of weight 2. Relating to the measurement of gravity
41
Properties of alkali metals
- Most reactive group of elements - Less dense than other metals - Have one loosely bound valence electron - Highly reactive, with reactivity increasing moving down the group - Largest atomic radius of elements in their period - Low ionisation activity and low electronegativity - Malleable, ductible, good conductors of heat and electricity
42
Define atomic radius
Total distance from an atom's nucleus to the outermost orbital of an electron
43
Define ionisation energy
The amount of energy required to remove an electron from an isolated atom or molecule
44
Define electronegativity
A chemical property that describes the tendency of an atom or a function group to attract electrons towards itself
45
Properties of alkaline earth metals
- Two electrons in the valence shell - Readily form divalent cations - Low electron affinity and low electronegativity - Typically malleable and ductible (can be drawn into wires or pounded into thin sheets) - Relatively soft but strong
46
Define divalent cations
Positively charged ions that form when a neutral atom loses two electrons in the process of oxidation (combine chemically with oxygen)
47
Define electron affinity
The measure of attraction between the incoming electron and the nucleus - the stronger the attraction, the more energy released
48
Properties of transition metals
*Lanthanides and actinides are included - Low ionisation energies - Positive oxidation states. Multiple oxidation states, since there is a low energy gap between them - Very hard, shiny, ductible, malleable - High melting and boiling points - High thermal and electrical conductivity
49
What are 'lanthanides'?
Also known as rare earth metals. A group of 15 chemical elements that are silver in colour and can tarnish when exposed to oxygen in the air (part of transition metals).
50
What are 'actinides'?
Group of 15 metallic elements. Radioactive and release energy upon radioactive decay - because of unstable nucleus, they decay into other elements and other simple particles (part of transition metals).
51
Properties of basic metals
- Shiny metallic appearance - Solids at room temperature (except mercury) - High melting points - High densities - Large atomic radii - Low ionisation energies and low electronegativities - High deformation (usually) - Malleable and ductible - Thermal and electrical conductors
52
Define deformation
To spoil the usual and true shape of something
53
Properties of metalloids (semimetals)
- Electronegativity and ionisation energy are intermediate between that of metals and nonmetals - May possess metallic luster* - Variable desnity, hardness, conductivity and other properties (bascially, would have some characteristics from both metals and nonmetals) - Often good semiconductors - Reactivity depends on nature of other elements in the reaction (usually behaving as nonmetals in chemical reactions) - Ability to form alloys with metals - Usually brittle, usually solids under ordinary conditions *Luster: reflected light that resembles a polished metal surface
54
Define semiconductors
Substances with properties somewhere between them - a material that is between the conductor and insulator in ability to conduct electrical current
55
Properties of nonmetals
- High ionisation energies and high electronegativities - Poor thermal and electrical conductors - Brittle solids - Little or no metallic luster - Readily gains electrons - Dull, not metallic-shiny, but may be colourful - Lower melting and boiling points than the metals
56
Properties of halogens
- Type of nonmetal - Extremely high electronegativities - Seven valence electrons (one short of a stable octet) - High reactive, especially with alkali metals and alkaline earth metals- they are the most reactive nonmetals
57
Properties of noble gases
- Fairly nonreative - Complete outer electron/valence shell (oxidation number = 0) - High ionisation energies BUT very low electronegativies - Low boiling points (all monatomic gases at room temperature) - No colour, odor, or flavour unless under ordinary conditions (but may then form coloured liquids/solids) - Nonflammable - At low pressure, they will conduct electricity and fluoresce* *Fluoresce: to shine or glow brightly due to fluorescence
58
What ions do metals form?
Cations
59
What ions do nonmetals form?
Anions