Proteins Flashcards

(32 cards)

1
Q

What are amino acids

A

The building blocks from which proteins are formed

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2
Q

What functional groups do amino acids contain

A

Contain the amino/amine group(-NH2)
And the carboxyl group(-COOH)

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3
Q

What are proteins

A

Condensation polymers
They are made of amino acid molecules that are linked together by condensation reactions

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4
Q

What happens to amino acids when they undergo condensation reactions

A

The amine group of 1 amino acid and the carboxyl group of another join and water is eliminated (similar to esters)

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5
Q

What is the link that forms during condensation reactions called

A

Peptide/amide link (-CONH)

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6
Q

What are essential amino acids

A

Amino acids that the body cannot make. They have to be supplied by our diet.

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7
Q

What are enzymes

A

Biological catalysts

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8
Q

What is hydrolysis

A

The process of breaking proteins into amino acids

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9
Q

Describe the structure of proteins

A

Long chain molecules that form sheets, spirals and other complex shapes. These shapes give it a specific job.

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10
Q

What happens when a protein is heated

A

Intermolecular bonds are broken allowing the protein to change shape. This is called denaturing (- stops it from being able to do its job)

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11
Q

What functional groups do aldehydes contain

A

Carbonyl functional group (C=O) on the END of the carbon chain
(Name as u would an alkane but with an -al on the end i.e. Propanal)

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12
Q

What functional groups do ketones contain

A

Carbonyl group (C=O)
In the MIDDLE of the carbon chain
For ketones names end in -one (must include carbon number of carbonyl group i.e. Propan-2-one)

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13
Q

What are oxidation reactions

A

An carbon compounds it involves an increase in an increase in oxygen to hydrogen ratio (losing an H or gaining an O)

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14
Q

Describe the oxidising agent hot copper (II) oxide

A

> its weak
changes from black to brown
1• alcohol ~> aldehyde
2• alcohol ~> ketone

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15
Q

Describe the oxidising agent Acidified Dichromate (VI) solutions (K2Cr2O7)

A

> its strong
changes from orange to green
1• alcohol ~> aldehyde ~> carboxylic acid
2• alcohol ~> ketone

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16
Q

Describe the oxidising agent Tollens Reagent

A

> its strong
Colourless solution to silver mirror
1• alcohol ~> aldehyde ~> carboxylic acid

17
Q

Describe the oxidising agent Fehlings solution

A

> its strong
Blue solution to brick red precipitate
1• alcohol ~> aldehyde ~> carboxylic acid

18
Q

Why do foods spoil

A

They contain edible oils which can spoil after being exposed to air
(O2 from air causes food to oxidise - increasing O:H ratio

19
Q

Give an example of what happens when a food spoils

A

When butter spoils its due to the formation of butanoic acid as the butter is hydrolysed - its said to be rancid

20
Q

What do antioxidants do

A

They prevent foods from spoiling too quickly by stopping oxidation reactions from taking place

21
Q

How do antioxidants do their job

A

They are reducing agents and cause other substances to be reduced whilst being oxidised themselves

22
Q

What are essential oils

A

Hydrophobic liquids containing mixtures of volatile aroma compounds that evaporate easily giving distint fragrances

23
Q

How are essential oils extracted

A

From plants via steam distillation
(Look at diagram in booklet)

24
Q

What difficulty is faced when extracting essential oils

A

Obtaining the liquid before it evaporates

25
How do you identify terpenes
They are unsaturated compounds thay form by joining isoprene units (therefore contain 5 carbon atoms per unit = isoprenes)
26
What is ultraviolet radiation
A high energy form of light present in sunlight
27
What are free radicals
Free radicals are atoms and molecules that are highly reactive due to the presence of an unpaired electron
28
How do free radicals form
When strong covalent bonds are broken by UV light
29
What three steps are in a free radical chain reaction
Initiation Propagation Termination
30
What is initiation
UV light provides energy for the splitting of diatomic halogen molecule into reactive halogen atoms or free radicals ( Cl2(g) ~> Cl•(g) + •Cl(g) )
31
What is propagation
Free radicals collide with other species but the number of free radicals is maintained ( H2(g) + •Cl ~> H•(g) +HCl (g) ) ( H•(g) + Cl2(g) ~> HCl(g) + Cl•(g) )
32
What is termination
Free radicals are used uo by collision with each other ( H•(g) + •Cl(g) ~> HCl(g) ( H•(g) + •H(g)