QM Models Flashcards

1
Q

Harmonic oscillator separation between energy levels

A

Hbar ω

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2
Q

Zero-point vibrational energy

A

E = 1/2 hbar ω

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3
Q

Quantisation

A

Result of boundary conditions on the Schrödinger equation

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4
Q

Labelling moments of inertia

A

Ic > Ib > Ia

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5
Q

Linear rotors

A

Ib = Ic, Ia = 0

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6
Q

Spherical rotors

A

Ia = Ib = Ic

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7
Q

Symmetric rotors

A

Two equal moments of inertia

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8
Q

Asymmetric rotors

A

3 different moments of inertia

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9
Q

Born-Oppenheimer approximation

A

Separation of motion of electrons and nuclei

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