Qualitative Analysis of Anions (Experiment 3) Flashcards
(16 cards)
In qualitative analysis of an unknown solution, it is important to answer the question,
What is present?
The previous experiment deals with the ______ and compared to this, the __________ in a solution is quite _______.
Analysis of Cation
Analysis of Anion
Indirect
It involves 1 to 2 stages of ______ then _______ test to check the ________
Separation,
Confirmatory
Anion’s Identity
What Group? and There is a visible change( such as gas evolution and formation of precipitate) with dilute ________________________
Group 1:
Group 1
Group 1 Co3(2-), SiO3(2), S2-, SO3(2-), S2O3(2-)
Group 2
SO4(2-), PO4(3-), F-, BO3(3-)
What Group?
Form precipitates with __________ in neutral solutions
Group 2
Barium Ions acidic
Group 3
Group 3Cl-, Br-, I-, SCN-
Form precipitates inwith ______________________ environment
silver ions acidic
Group 4
NO2-, NO3-, CO3 2-, ClO3-
Do not react with any ________________ and/or _____ mentioned above.
Reagents; Ions
Experiment 3:
Test Solutions:
0.05M Sodium Chloride, NaCl
0.05M Sodium Carbonate, Na2CO3
0.05M Sodium Sulphate, Na2SO4
0.05M Sodium Nitrate, NaNO3
Reagents:
0.1M Silver Nitrate, AgNO3
6M Acetic Acid, CH3COOH
6M Hydrochloric Acid, HCl
0.1M Barium Chloride, BaCl2
Sat. Barium Hydroxide, Ba(OH)2
6M Ammonia, NH3
6M Sodium Hydroxide, NaOH
Unknown Solution
Others:
Litmus Paper
Instrument:
Centrifuge and Water Bath
PROCEDURE:
- Separation and Confirmation of Chloride (Cl-)
- Confirmation of Carbonate (CO3(2-)
- Confirmation of Sulfate (SO4(2-)
- Confirmation of Nitrate (NO3-)