Qualitative Analysis of Carbohydrates Flashcards

(51 cards)

1
Q

most abundant organic compounds found in living organisms and are composed of carbon, hydrogen, and oxygen.

A

Carbohydrates

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2
Q

act as the primary source to provide energy for functioning of living organisms

A

Carbohydrates

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3
Q

considered as hydrates of carbon

A

carbohydrates

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4
Q

general formula of Carbohydrates

A

Cx(H2O)y

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5
Q

defined as polyhydroxy aldehydes or polyhydroxy ketones or the compounds which produces such products on hydrolysis

A

carbohydrates

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6
Q

carbohydrates are defined as _________________________or the compounds which produces such products on hydrolysis

A

polyhydroxy aldehydes
polyhydroxy ketones

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7
Q

Based on reactivity with Tollen’s, Benedict’s or Fehling’s reagent carbohydrates are classified as:

A

reducing sugars
non-reducing sugars

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8
Q

carbohydrates that can reduce Tollen’s, Benedict’s or Fehling’s reagent are called _____________

A

reducing sugars

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9
Q

sugar with free aldehyde or ketone group

A

reducing sugars

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10
Q

true or false: all monosaccharides and most of the disaccharides are reducing sugars

A

true

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11
Q

Carbohydrates that cannot reduce Tollen’s, Benedict’s or Fehling’s reagents are called

A

non-reducing sugars

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12
Q

True or False: Maltose and Lactose are non-reducing sugars

A

False; reducing

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13
Q

True or False: Sucrose is a reducing sugar

A

False; non-reducing

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14
Q

What are the different tests for the detection of carbohydrates?

A

Molisch’s test
Fehling’s test
Benedict’s test
Tollen’s test
Iodine test

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15
Q

10% alcoholic solution of α-naphthol

A

Molisch’s reagent

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16
Q

What is used in Molisch’s test?

A

concentrated sulfuric acid

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17
Q

carbohydrates undergo dehydration by sulfuring acid to form _______ that reacts with α-naphthol

A

furfural (furfuraldehyde)

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18
Q

carbohydrates undergo dehydration by sulfuring acid to form furfural that reacts with α-naphthol to form a _______ colored product

A

violet

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19
Q

carbohydrates undergo dehydration by sulfuring acid to form furfural that reacts with α-naphthol to form a violet colored product

A

molisch’s test

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20
Q

Fehling’s A is a _____________ while Fehling’s B solution is potassium sodium tartrate

A

copper sulphate

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21
Q

Fehling’s B solution is ___________ while Fehling’s A is copper sulphate

A

potassium sodium tartrate

22
Q

On heating, carbohydrate reduces deep blue solution of __________ to red precipitate of insoluble copper oxide

A

copper II ions

23
Q

On heating, carbohydrate reduces deep blue solution of copper II ions to red precipitate of insoluble ____________

24
Q

The copper ions present in Fehling’s solution in +3 state is reduced to _________________

A

+2 oxidation state

25
In alkaline medium, copper ions present in Fehling's solution is precipitated as _____________
red cuprous oxide
26
distinguishes reducing sugar from non-reducing sugar
Benedict's test
27
Benedict's reagent contains
Blue copper (II) ions (Cu2 cupric ions)
28
Benedict's reagent contains Blue copper (II) ions (Cu2 cupric ions) that are reduced to
copper (I) ions (Cu2+ cupric ions)
29
In alkaline medium, __________ converts glucose to enediol which reduce cupric to cuprous forming cuprous hydroxide
sodium carbonate
30
In alkaline medium, sodium carbonate converts __________ to enediol which reduce cupric to cuprous forming cuprous hydroxide
glucose
31
In alkaline medium, sodium carbonate converts glucose to ________ which reduce cupric to cuprous forming cuprous hydroxide
enediol
32
reduce cupric to cuprous forming cuprous hydroxide
enediol
33
Where is the Benedict's solution kept?
sodium citrate
34
upon boiling, Benedict's reagent forms
cuprous oxide
35
ammoniacal silver nitrate solution
Tollen's reagent
36
Carbohydrates reacts with Tollens reagent forms a ________ mirror on the inner walls of the test tibe
silver
37
used to detect presence of starch
Iodine test
38
True or False: Iodine is not much soluble in water
true
39
Where is iodine solution prepared?
dissolving iodine in water in the presence of potassium iodide
40
Iodine dissolved in an aqueous solution of potassium iodide reacts with starch to form a ____________ which gives characteristics blue black color
starch/iodine complex
41
True or False: In iodine test, when heating the blue color disappears and on cooling the blue color reappears
True
42
positive in molisch's test
maltose lactose sucrose
43
negative on molisch's test
starch
44
Fehling's test positive
maltose lactose sucrose
45
Fehling's test negative
starch
46
Benedict's test positive
maltose lactose sucrose
47
Benedict's test negative
starch
48
Tollen's test positive
maltose lactose
49
Tollen's test negative
sucrose starch
50
Iodine test positive
starch
51
iodine test negative
maltose lactose sucrose