Quantum Flashcards

(38 cards)

0
Q

Wavelength and frequency are _______ related.

A

inversely

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1
Q

All __________ waves, including visible light, travel at the speed of light, or ____________ m/s.

A

electromagnetic, 3.00 * 10^8 m/s

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2
Q

Atomic emission spectrum of an element

A

The set of frequencies of the electromagnetic waves emitted by atoms of the element

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3
Q

The distinct wavelengths that appear on hydrogen’s emission spectra are explained by ________

A

the different energy levels of hydrogen’s electrons

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4
Q

Describe the 4 quantum numbers.

A

PQN, SQN, m(sub)l, m(sub)s

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5
Q

Aufbau principle

A

Electrons are added to the orbitals of lowest energy first

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6
Q

Puali’s exclusion principle

A

Each orbital within a subshell can accommodate no more than two electrons and these electrons must have opposite spins

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7
Q

Hund’s principle

A

When electrons occupy orbitals of equal energy, one electron enters each orbital until all the orbitals contain one electron with parallel spins

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8
Q

Heisenberg’s uncertainty principle

A

You can never know the position and momentum of a particle at a given time

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9
Q

Total number of electrons within a given energy level is ____

A

2n^2

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10
Q

_____ notation and _____ notation follow the aufbau sequence, while ____ notation does not

A

Box, noble gas, spectroscopic

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11
Q

In 1900, Planck stated that there is a concept called a quantum, which is _______

A

a minimum quantity of energy that can be emitted at any time and it exists in small, measurable packets

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12
Q

After hearing Planck’s Quantum Theory, Bohr proposed that electrons maintain a __________ when they move around the nucleus.

A

energy level

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13
Q

de Broglie suggested that ________

A

If electromagnetic waves can behave as particles, then moving particles can have wave properties

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14
Q

Shape of s orbital

A

spherical

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15
Q

Shape of p orbital

A

dumbbell shape

16
Q

Shape of d orbital

17
Q

Shape of f orbital

A

doughnut shape

18
Q

The photoelectric effect was coined by ____

19
Q

Photoelectric effect

A

When light shines on a metal, the photons collide with the electrons from the metal, ejecting these electrons

20
Q

Lyman series

A

Anything to 1 (ultraviolet)

21
Q

Balmer series

A

Anything to 2 (visible light)

22
Q

Paschen series

A

(anything to 3) high IR

23
Q

Brackett series

A

anything to 4 (mid-IR region)

24
Pfund series
Anything to 5 (low IR region)
25
Weakness of the Rydberg equation?
It only works for hydrogen
26
List the series of spectral lines in order.
Balmer, Lyman, Paschen, Brackett, Pfund
27
Planck's constant
6.63 * 10^-34
28
Avogadro's number
6.022 * 10^23
29
JW Dobereiner
Observed the existence of triads of similarly behaving elements
30
Newlands
Observed that when elements were arranged according to increasing atomic mass, every eighth element had similar properties (law of octaves)
31
Henry Moseley
Proposed Periodic Law, that properties of elements are based on atomic numbers, not atomic mass
32
Azimuthal Arrangement
s & p blocks are group A (representative elements), d block group B (transition elements), f block (inner transition elements)
35
as you move from left to right, what decreases?
ionic size of cations and ionic size of anions, atomic radii,
36
As you move from left to right, what increases?
electronegativity, electron affinity, ionization energy
37
What is constant as you move left and right?
shielding effect
69
As you move down the columns of the periodic table, what decreases?
ionization energy, electron affinity, electronegativity
70
As you move down the columns, what increases?
shielding effect, atomic radii, nuclear charge, ionic size