Quantum Phenomena Flashcards

(61 cards)

1
Q

Define 1 electronvolt (1 eV).

A

The energy gained by an electron when it moves through a potential difference of 1 volt.

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2
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5
Q

What is 1 eV in joules?

A

1 eV = 1.60 × 10⁻¹⁹ J

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5
Q

How do you convert from eV to J?

A

Multiply by 1.6 × 10⁻¹⁹

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6
Q

How do you convert from J to eV?

A

Divide by 1.6 × 10⁻¹⁹

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7
Q

What equation relates energy, charge, and potential difference?

A

V = E / Q
(Where V = potential difference, E = energy, Q = charge)

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8
Q

What happens when a charged particle is accelerated through a potential difference?

A

It gains kinetic energy equal to the energy transferred (in eV).

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9
Q

What is the kinetic energy gained by an electron in terms of eV?

A

eV = ½mv²

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10
Q

What is the photoelectric effect?

A

The emission of electrons (photoelectrons) from the surface of a metal when electromagnetic radiation is absorbed.

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11
Q

What does the photoelectric effect demonstrate about light?

A

That light behaves as a particle, with energy carried in discrete packets (photons)

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12
Q

Why must a photon have a minimum frequency to emit an electron?

A

Because an electron can only absorb one photon, and it must have enough energy to overcome the work function.

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13
Q

Define threshold frequency (f₀).

A

The minimum frequency of electromagnetic radiation required to release a photoelectron from a metal surface.

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14
Q

Define threshold wavelength (λ₀).

A

The maximum wavelength of radiation that will emit a photoelectron.

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15
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16
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17
Q

Relationship between frequency and wavelength?

A

c = fλ
Where c is the speed of light, f is frequency, λ is wavelength.

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17
Q

Define the work function (Φ).

A

The minimum energy required to release an electron from the surface of a metal.

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18
Q

What happens if a photon’s energy is less than Φ?

A

No photoelectron is emitted.

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19
Q

What happens to excess photon energy after overcoming Φ?

A

It becomes the kinetic energy of the emitted photoelectron.

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20
Q

Equation linking energy, work function, and kinetic energy?

A

hf = Φ + Ek(max)

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21
Q

Why do alkali metals have lower work functions?

A

Their surface electrons are less tightly bound due to weaker attraction.

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22
Q

Define stopping potential (Vₛ).

A

The minimum potential difference required to stop all photoelectrons from reaching the collector plate.

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23
Equation linking stopping potential and kinetic energy?
Ek(max) = eVₛ Where e = electron charge
24
What does stopping potential measure?
the maximum kinetic energy of emitted photoelectrons.
25
Does increasing light intensity affect Vₛ?
No – intensity affects photoelectric current, not kinetic energy or Vₛ.
26
What does increasing intensity do?
Increases number of photons, hence more photoelectrons, but not their energy.
27
What happens if you increase frequency while keeping intensity constant?
- Photon energy ↑ - Photon number ↓ - Photoelectric current ↓ - Kinetic energy ↑
28
What are energy levels in an atom?
Discrete energy states that electrons can occupy.
29
Which energy level do electrons occupy by default?
The lowest possible energy level (ground state), which is the most stable.
30
What is excitation?
When an electron absorbs energy and moves to a higher energy level.
31
How does an electron become excited?
By absorbing a photon with exactly the right amount of energy.
32
What is de-excitation?
When an electron falls to a lower energy level, emitting a photon.
33
What happens to the energy of the emitted photon during de-excitation?
It equals the difference in energy between the two levels.
34
What is ionisation?
The removal of an electron from an atom, causing it to become charged.
35
What is ionisation energy?
The minimum energy required to remove an electron from the ground state.
36
Can an electron be removed from any energy level?
Yes, but the ionisation energy is defined from the ground state.
37
What is a fluorescent tube?
A low-pressure mercury vapor tube with a phosphor coating that emits visible light.
38
What is the role of mercury atoms in a fluorescent tube?
They get excited by colliding electrons and emit UV photons upon de-excitation.
39
What does the phosphor coating do in a fluorescent tube?
It absorbs UV photons and re-emits visible light photons during de-excitation
40
How is excitation achieved in a fluorescent tube?
By electron collisions with mercury atoms, not just photon absorption.
41
What causes the visible light in a fluorescent tube?
The de-excitation of phosphor electrons, not mercury directly.
42
What causes emission spectra?
Electrons de-exciting to lower energy levels, emitting photons.
43
What does an emission spectrum look like?
Coloured lines on a black background.
44
What does each line in an emission spectrum represent?
A specific photon energy from a particular electronic transition.
45
What causes absorption spectra?
Electrons absorbing photons and jumping to higher energy levels.
46
What does an absorption spectrum look like?
A continuous spectrum with dark lines (missing wavelengths).
47
Why are specific wavelengths missing in absorption spectra?
Those photons were absorbed by electrons for excitation.
48
How are emission and absorption spectra related?
The same wavelengths appear in both — emitted in one, absorbed in the other.
49
What evidence do line spectra provide about atoms?
Electrons can only occupy discrete energy levels.
50
Why does each element have a unique line spectrum?
Each element has a unique arrangement of energy levels.
51
What happens to absorbed photons in an absorption spectrum?
Re-emitted in random directions, so some wavelengths are missing from original beam.
52
What is wave-particle duality?
The concept that light and matter exhibit both wave and particle properties.
53
What experiment supports the wave nature of light?
Young’s Double-Slit Experiment (shows diffraction and interference).
54
What phenomenon supports the particle nature of light?
The Photoelectric Effect (light behaves as photons).
55
Why is graphite film used in electron diffraction experiments?
Its atomic lattice provides gaps acting like slits for electron waves.
56
What is the de Broglie wavelength?
It is the wavelength associated with a moving particle, showing wave-particle duality.
57
What happens when electrons pass through a slit similar in size to their de Broglie wavelengthThey exhibit diffraction,
They exhibit diffraction, forming a pattern
58
How does increasing the kinetic energy of electrons affect their de Broglie wavelength?
Increasing kinetic energy increases momentum, which decreases the de Broglie wavelength.
59
What is the relationship between electron momentum and the size of the diffraction pattern?
Smaller momentum → longer wavelength → larger diffraction pattern radius Larger momentum → shorter wavelength → smaller radius.