Quiz 3 Flashcards
(46 cards)
atoms tend to migrate from regions of…
high concentration to low concentration
Vavancy diffusion
atoms and vacancies exchange positions
-occur above 0 K
-applies to host and substitutional impurity atoms
-diffusion rate depends on 1. number of vacancies and 2. activation energy to exchange
self diffusion
migration of host atoms in pure metals
interstitial diffusion
small interstitials move from one interstitial position to another
-more rapid than vacancy diffusion b/c space already available
doping
diffusion of very small concentrations of atoms of an impurity (e.g. P) into semiconductor silicon
steady state diffusion
-rate of diffusion (flux) indep. of time
-Flux (J) proportional to concentration gradient
-Fick’s first law
non-steady state diffusion
-concentration is a function of time and position (depends on time and position)
-Fick’s second Law
Diffusion coefficient D is dependent on..
temperature
-D has exponential dependence on T
elastic deformation
nonpermanent, reversible (material will bounce back)
-generally valid at small deformations
-linear stress strain curve
-young’s modulus/modulus of elasticity, E
-hooke’s law
Plastic deformation
permanent and nonrecoverable
-stress strain curve is nonlinear
yield strength
stress at which noticeable plastic deformation has occured
tensile strength (TS)
max stress on engineering stress-strain curve (highest stress value)
ductility
amount of plastic deformation at failure
resilience
ability of a material to absorb energy during elastic deformation
-modulus of resilience, U_r
-U_r is area under stress strain curve until yielding
toughness
-amount of energy absorbed before fracture
- total area under stress strain curve
hardness
measure of resistance to surface plastic deformation, dents, or scratches
-large hardness means high resistance to compressive deformation, better wear properties
-small indents mean large hardness
stiffness
material’s resistance to elastic deformation
strength
a material’s resistance to plastic deformation
-yield and tensile strengths
slip
plastic deformation by dislocation motion (edge, screw, mixed)
-atomic bonds broken and reformed along slip plane as dislocation moves
-caterpillar analogy
edge dislocation motion
moves in direction of shear stress tau/parallel
screw dislocation motion
moves perpendicular to shear stress tau
dislocation characteristics for metals
-dislocation motion relatively easy due to non-directional metallic bonding
-occurs on close packed planes in packing direction
dislocation characteristics for ceramics (covalently bonded)
-relatively difficult dislocation motion due to strong covalent bonding directions
-ex. silicon, diamond
dislocation characteristics for ceramics (ionic bonding)
-relatively difficult dislocation motion
-few slip systems because motion of nearby ions of like charge (+, -) restricted by electrostatic repulsive forces
-ex. NaCl, MgO