random P2 Flashcards

(63 cards)

1
Q
  1. What is an Alkane
  2. What is an Alkene

BOTH INCLUDING THEIR GENERAL FORMULA

A
  1. A saturated hydrocarbon (meaning it only has single bonds), general formula CnH2n+2
  2. An unsaturated hydrocarbon (meaning it has double bonds), general formula CnH2n
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2
Q

Give the first 4 alkanes and alkenes with their general formulas

A

ALKANES
• Methane, CH4
• Ethane, C2H6
• Propane, C3H8
• Butane, C4H10

ALKENES
• Ethene, C2H4
• Propene, C3H6
• But-1-ene, C4H8
• But-2-ene, C4H8

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3
Q

Are Alkanes or Alkenes more reactive? Explain why

A

•Alkenes are more reactive
•Because they have a double bond (unsaturated), and this bond can open up to react with other molecules.
• Alkenes only have single bonds (saturated), therefore they are not as reactive.

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4
Q

Describe the test for identifying Alkanes/Alkenes

A

• If you shake the hydrocarbon with bromine water;
-> An alkene would decolourise/react with the bromine water, due to its double bonds (orange to colourless)
-> Alkanes will not react with bromine water as they only have single bonds (brown colour stays the same)

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5
Q

Alkanes and Alkenes burn in oxygen during complete combustion.
What are the products of this reaction?

A

• Carbon Dioxide
• Water

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6
Q

What is the reaction called between Alkenes and Bromine Water?

A

An Addition Reaction

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7
Q

Give 3 ways to measure the ROR

A

• Precipitation
• Change in Mass
• The Volume of Gas given off

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8
Q

A scientist wants to measure the ROR of two see-through solutions that together produce a precipitate. What experiment should they do?

A

• Precipitation
1. Put a conical flask on a piece of paper that has a cross on it.
2. Mix the two reactant solutions together in the flask
3. Observe/Time how long it takes for the mark to disappear - the faster the time, the faster the ROR.

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9
Q

What’s a Disadvantage of Precipitation Experiments (to measure the ROR)?

A

The result is subjective, people might not agree when the mark is exactly obscured.

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10
Q

A scientist wants to measure the ROR in an experiment, but the reaction produces a Gas. What Experiment should they use?

A

• Change in Mass Experiment
• When gas evaporates, the reaction loses mass, which can be recorded in a mass balance. You know when the reaction has finished when the balance stops changing

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11
Q

Give a Disadvantge of a Change in Mass Experiment (one that produces gas)

A

Gas is directly released into the open air, which can be dangerous if it’s toxic - therefore this experiment will need a fume cupboard.

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12
Q

How can a Scientist measure the volume of gas given off in an experiment?

A

• Measure the Volume of gas given off by:
1. Put the reactant in a conical flask, then quickly attach a bung to the flask that’s connect to a gas syringe.
2. The gas evaporated in the reaction will enter the gas syringe and cause it to move; therefore measuring the volume of the gas produced.
3. The reaction will have finished when the gas syringe has stopped moving.

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13
Q

Give four things that can effect the ROR

A

• Surface Area
• Temperature
• Concentration
• Pressure

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14
Q

How does Surface Area affect the ROR?
Use Marble Chips as an example

A

The bigger the SA, the faster the ROR. E.g. if you compared the ROR of marble large marble chips vs small marble chips (both at the same mass) then the smaller marble chips will have a faster ROR, as there is more physical surface for the reactants to react with

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15
Q

How does Temperature affect the ROR?

A

The hotter a reaction, the more energy the particles have. Therefore, the particles collide more as they are moving faster, so reaction happen quicker and therefore the ROR increases.

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16
Q

How does Concentration affect the ROR?

A

The more concentrated a solution is, the more particles there are. This means that the ROR will increase, as there will be more particles to react with, with also more limited space.

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17
Q

How does Pressure affect the ROR?

A

When pressure is increased, the amount of space becomes more limited, therefore there is not a lot of space for the particles and so collisions are more frequent, which increases the ROR.

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18
Q

What is Bond Energy?

A

The energy needed to break a bond or the energy released when a bond forms (energy transfer)

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19
Q

What process are bond breaking and bond making and why?

A

BOND BREAKING is an endothermic process, because energy needs to be supplied.
BOND MAKING is an exothermic process because energy is released when bonds are formed.

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20
Q

Explain how the Atmosphere was formed

A

PHASE 1 - Originally, the planet was molten and rocky (like mars) - there was a lot of volcanic activity that released gases like Carbon Dioxide, methane, nitrogen and water vapour into the atmosphere. There was little oxygen, so there was no living organisms.

PHASE 2 - the Earth began to cool, which made the water vapour condense, causing precipitation and forming the oceans. Carbon dioxide dissolved in the oceans. Then plants like algae started to grow from the water, which removed more Carbon dioxide and produced Oxygen. Carbon dioxide got locked up in fossil fuels and sedimentary rocks.
PHASE 3 - The amount of oxygen allowed the evolution of complex organisms.

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21
Q

What is the Atmosphere?

A

A layer of gases that surround the Earths surface

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22
Q

What’s the Ozone Layer?

A

When oxygen created a layer in the atmosphere that blocked harmful rays from the sun, this allowed complex evolution to happen.

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23
Q

Why did the amount of Nitrogen in the atmosphere increase?

A

Ammonia in the atmosphere formed nitrogen when reacting with oxygen and was also released by denitrifying bacteria.
However, nitrogen is not very reactive, it was being made but not broken down/being reacted with. So the levels of Nitrogen increased

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24
Q

What is a greenhouse gas?

A

A gas in the atmosphere that can absorb and reflect heat radiation

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25
Explain how the Greenhouse effect works
1. The sun emits short wavelength radiations which passes through the earths atmosphere 2. The short wavelength radiation reaches the earths surface and is absorbed, then in re-emitted as long wavelength radiation. 3. This radiation is absorbed by greenhouse gases 4. The greenhouse gases re-radiate it in all directions, including back towards Earth 5. The radiation is thermal radiation, so it warms the surface of the earth.
26
What’s the problem with the Greenhouse effect?
The greenhouse effect is not always bad, as we need heat to survive and it acts as an insulting layer, however, because of human activity such as the combustion of fossils fuels, more greenhouse gases are being added to the atmosphere (higher concentration) therefore, more of this effect is happening. So the world is gradually becoming hotter and hotter. This causes Climate Change
27
Give two of the main causes of Climate Change
• Combustion/Burning of fossils fuels fuels (releases carbon dioxide) • Deforestation (reduces photosynthesis so the carbon dioxide isn’t been used up)
28
How is livestock farming affecting climate change?
The more livestock that we farm, the more methane it produces, which is a problem because methane is an effective greenhouse gas.
29
What is Global Warming?
A type of climate change that causes other types of climate changes, such as changes in rainfall patterns (which could cause flooding)
30
How can we estimate past global temperatures
Through studying fossils, tree rings and gas bubble trapped in ice sheet
31
What is the general formula for Alcohol?
CnH2n+1OH
32
You can make alkenes by…what?
Dehydrating Alcohols If you heat a mixture of an alcohol and an acid catalyst, you get an alkene and water
33
How can you make ethanol?
In fermentation, using yeast and a type of carbohydrate
34
What are the products of a fermentation reaction?
Ethanol and carbon dioxide
35
Describe the process of Fermentation
1. Mix yeast and a solution of glucose in a clean container. Seal and leave in a warm place (30C-40C). If too cold, the reaction slows and if too hot, the enzymes in the yeast denature. 2. Keep the mixture in anaerobic conditions, as oxygen can covert the ethanol to ethanoic acid (vinegar). 3. When the concentration of alcohol reaches 10%-20%, the fermentation stops because the yeast gets killed of by the alcohol. 4. The yeast will fall to the bottom of the container, and you can collect the ethanol solution from the top.
36
What method can you use to make a more concentrated alcohol.
Fractional Distillation
37
What method can you use to make a more concentrated alcohol.
Fractional Distillation
38
Describe the process of using Fractional Distillation to make a more concentrated alcohol
1. Add a dilute solution of ethanol to a beaker, add a bung, fractionating column, condenser and another beaker. 2. Heat the dilute ethanol solution; ethanol has a lower boiling point than water, so it will evaporate and rise up the factoring column while the water stays liquid. 3. The condenser then condenses the ethanol Vapor, then you are left with a more concentrated version of ethanol
39
Ethanol has a lower boiling point than what?
Water
40
What is the average concentration of ethanol
20%
41
Why are alcohols used as fuels?
Because when their burnt they release energy
42
When doing an experiment, what does less alcohol being burnt mean?
It’s a better fuel
43
Explain how to do the Alcohol spirit-burner experiment
1. Put some of the alcohol into a spirit burner (with a lid) measure its mass using a mass balance 2. Measure 100cm3 of distilled water into a copper calorimeter 3. Measure and record its temperature. 4. Place the spirit burner underneath the calorimeter and remove the lid and light the wick. 5. Stir the water carefully with the thermometer, until it has increased by about 20C, put the lid back on and put the flame out. 6. Measure and record the mass of the spirit burner and the temperature of the water. 7. Repeat with different alcohols, using fresh water each time.
44
Give a conclusion to the alcohol spirit-burner experiment
The change in mass is equal to the mass of fuel burned. Less alcohol burned means a better fuel.
45
What is a Polymer
A long chain molecule that is formed by joining lots of smaller molecules called monomers together.
46
What bonding do Polymers use?
Covalent Bonds
47
Polymers contain Covalent bonds, which have high melting and boiling points. Polymers have high melting or boiling points, however this is not due to the bonding. Why?
When we want to melt/boil polymers, we break the intermolecular forces between the separate molecules instead of the actual bonding, and these forces are weaker than covalent bonding. However, because polymers are so long, they have a high surface area, and therefore they still need quite a lot of energy to overcome.
48
What is Addition Polymerisation?
The process of small molecules called monomers joining together into a long chain, called a polymer
49
What two conditions are necessary for Addition Polymerisation?
• Pressure • Catalyst
50
What makes Polyesters different to polymers
Polyester are usually made of two different monomers
51
Name the two monomers that Polyester is made out of
• Dicarboxylic Acid Monomer (contains two carboxlyic acid groups) • Diol Monomer (contains two alcohol groups)
52
What does a Carboxylic Acid Group and a Diol Monomer Group look like?
Carboxylic Acid: O = C - HO Diol Monomer: HO/OH
53
How does Condensation Polymerisation work?
A Dicarboxylic Acid and a Diol Monomer bond, the Dicarboxylic Acid give up a OH group and the diol monomer gives up a H; these atoms form a water molecule. This causes the carbon and oxygen to bond, which causes an Ester Link
54
What’s a Dimer?
Only two monomers combined
55
What are the conditions required for Condenstation Polymerisation
• each of the monomers have to have at least two functional groups • Needs to be at least two different functional groups overall • a small molecules needs to be given off at the end of - normally a water molecule
56
Polyesters are… what? And why?
Bio-degradable Because microorganisms can break down the ester link
57
58
59
Describe the Endothermic Reaction
React an acid with an alkali, and measure the max temperature reached. Repeat with increasing volumes of alkali. The max temp will eventually decrease as the alkali is in excess (same energy released but larger volume).
60
Smaller Hydrocarbons make better fuels than large hydrocarbons; why?
Smaller hydrocarbons flow more readily and are easier to ignite.
61
Give the two types of cracking
• Catalytic Cracking • Steam Cracking
62
Give the two types of cracking
• Catalytic Cracking • Steam Cracking
63
What is Cracking?
Cracking is splitting up long-chain hydrocarbons; Turing long alkane molecules into smaller alkene molecules (which can be used to make polymers).