Rate and extent of chemical change Flashcards

1
Q

What are the two equations for rate of reaction?

A

Quantity of reactant used / time taken

Or

Quantity of product formed / time taken

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2
Q

How does measuring change in mass help us find rate of reaction?

A

Using a flask with your object and solution.

Putting it on a scale.

Gas escapes so the mass decreases.

Use a timer and see how the mass has changed between that time.

Use the equation for rate of reaction (Quant of mass used / time taken)

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3
Q

What is the unit used for measuring change in mass / time.

A

Grams per second

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4
Q

To measure the volume of a gas formed in a reaction, when might you choose to use a gas syringe rather than a measuring cylinder?

A

To measure a soluble gas

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5
Q

How do you find rate of reaction using the volume of the gas produced practical?

A

Using a flask and a upside down cylindrical flask filled with water,

Putting a tube from the flask and the the cylindrical flask.

The reaction is happening in the flask releasing gases.

The gases displace the water and pushes the water down and then you measure the volume of the gas that has displaced the water.

Do this with a timer and use the formula for rate of reaction.

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6
Q

How do you find the rate of reaction using colour change?

A

Using a flask with a cross at the base and your solid and solution.

Using a precipitate (solid formed), putting it in your solution and time how long it takes for the cross to not able to be seen

Use the formula 1 / time.

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7
Q

What does it mean when the line is flat on a rate graph?

A

Reaction has stopped

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8
Q

What does having a steeper gradient show in a rate graph?

A

It has a higher rate of reaction.

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9
Q

How do you calculate rate of reaction at a specific time?

A

Draw a tangent and calculate the gradient

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10
Q

On a rate graph showing product formed over time, what causes the gradient to eventually flatten out?

A

The reactant has been used up

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11
Q

Use your knowledge of particles to explain why the rate of the reaction decreased.

A

Less particles in a given volume (1)

Particles less likely to collide (1)

With enough energy or less successful collisions (1)

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12
Q

What is pressure?

A

Pressure is a measurement of the number of particles in a given volume of gas.

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13
Q

How does temperature affect rate of reaction?

A

Higher temperature = Higher rate of reaction

More energy towards the particles meaning more collisions.

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14
Q

How does pressure / concentration affect rate of reaction?

A

Higher pressure / concentration = higher rate of reaction

As more particles, more collisions.

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15
Q

Why does having a larger surface area increase rate of reaction?

A

This is because there are more particles exposed to the other reactant.

Greater chance of particles colliding.

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16
Q

What is a catalyst?

A

A substance that speeds up a chemical reaction without being used up.

17
Q

How does a catalyst work?

A

It reduces the activation energy of the reaction.

18
Q

Are catalysts chemically changed by a reaction?

A

No they are chemically unchanged by a reaction.

19
Q

Why are catalysts useful for producing chemicals in industry?

A

Catalysts are used in industry because they lower the activation energy required, thereby making reactions more efficient and cost effective.

20
Q

What is the collision theory?

A

Collision theory states that chemical reactions can only occur when reacting particles collide and have sufficient energy.

21
Q

What is activation energy?

A

The minimum amount of energy that particles must have to react is called activation energy.

22
Q

What is a reversible reaction?

A

A reversible reaction is one in which the products of the reaction can react to produce the original reactants again.

23
Q

If you heat up NH4Cl to make NH3 + HCl how do reverse the reaction?

A

By cooling it down. (ENDOTHERMIC)

24
Q

If you heat up hydrated copper sulphate it turns into anhydrous copper sulphate. How do you reverse the reaction?

A

Adding water

25
Q

What is a equilibrium?

A

It is when the forward and reverse reactions occur at exactly the same rate.

26
Q

Why is equilibrium only occur in a closed system?

A

No reactant can be released or added so the reactions can happen at the same time.

27
Q

When a reversible reaction reaches equilibrium are the concentrations of all reactants equal?

A

No as there may be more reactants products than reactants.

28
Q

What is name of the type of reaction that takes in heat energy?

A

Endothermic.

29
Q

Describe the energy change when an excess of water is added to the anhydrous white copper sulfate.

A

Energy is transferred to the surroundings or energy is transferred from
the anhydrous copper sulphate to the surroundings or heat energy/heat is given off. [1]
The reaction is exothermic. [1]

30
Q

What is Le Chatelier’s principle?

A

If a change is made to an equilibrium. The equilibrium will act to oppose the change.

Example: If temperature increases, the endothermic reaction will happen more and cools down the system.

31
Q

In the reaction A + B ⇌ C + D, what happens to the amounts of the reactants and products if the concentration of D is increased in equilibrium?

A

A and B increase; C and D decrease